Patents Represented by Attorney W. G. Montgomery
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Patent number: 4931596Abstract: Hydroxylated primary amines corresponding to the formula:R--X--CH.sub.2 --CH(OH)--CH.sub.2 NH.sub.2 (I)in which R is a saturated or unsaturated straight chain C.sub.5 -C.sub.18 aliphatic radical and X represents --O--, --S--, --NH-- or --CH.sub.2 -- are prepared by reacting an epoxide of the formula: ##STR1## in which R and X are as defined previously and R.sub.1 and R.sub.2 together represent an epoxy radical with ammonium carbamate to form the corresponding substituted ammonium carbamate of the formula: ##STR2## in which R and X are as defined previously and thereafter heating the substituted ammonium carbamate thus formed at a temperature and for a length of time sufficient to form the corresponding hydroxylated primary amine of formula (I).The hydroxylated primary amines of formula (I) and the salts of these compounds, particularly the hydrohalide, acetate and quaternary alkyl ammonium salts thereof are useful as medicaments, anticeptics, sterilizing agents and preservatives.Type: GrantFiled: January 3, 1989Date of Patent: June 5, 1990Assignee: Ethyl CorporationInventor: Kathleen S. Laurenzo
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Patent number: 4910324Abstract: Phosphorus compounds having at least one chlorine, bromine or iodine bonded directly to phosphorus are transhalogenated with fluorine by reaction with a fluoride salt, e.g., KF, or ammonium fluoride in an inert solvent in the presence of a catalytic amount of a carboxylic acid.Type: GrantFiled: August 29, 1988Date of Patent: March 20, 1990Assignee: Ethyl CorporationInventors: Lester P. J. Burton, Vincent J. Gatto
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Patent number: 4894481Abstract: Cyclic chlorophosphites of ortho-bridged phenols are made by reaction of an ortho-bridged bisphenol with PCl.sub.3 in an inert solvent using a catalytic amount of a polymeric compound having a pyridine skeletal structure and a cross-linked structure to promote the reaction.Type: GrantFiled: July 5, 1988Date of Patent: January 16, 1990Assignee: Ethyl CorporationInventor: Edward A. Burt
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Patent number: 4888138Abstract: Compounds corresponding to the formula: ##STR1## in which R is a saturated or unsaturated straight chain C.sub.5 -C.sub.18 aliphatic radical and X represents --O--, --S--, --NH-- or --CH.sub.2 -- are provided by reacting compounds corresponding to the formula: ##STR2## in which R and X are as defined above and R.sub.1 and R.sub.2 together represent an epoxy radical with ammonium carbamate.These compounds may be used as intermediates in the preparation of the hydrohalide salts, particularly the hydrochloride and hydrobromide salts, and acetates of hydroxylated primary amines corresponding to the formula:R--X--CH.sub.2 --CH(OH)--CH.sub.2 NH.sub.2 (III)in which R and X are as defined above which are useful as medicaments, antiseptics, sterilizing agents and preservatives.Type: GrantFiled: November 10, 1988Date of Patent: December 19, 1989Assignee: Ethyl CorporationInventor: Kathleen S. Laurenzo
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Patent number: 4827013Abstract: (S) .alpha.-cyano-3-phenoxy-benzyl acetate having the formula: ##STR1## and a novel process for its preparation.Type: GrantFiled: December 31, 1985Date of Patent: May 2, 1989Assignee: Ethyl CorporationInventors: Frank J. Smith, Jerry M. Roper
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Patent number: 4816532Abstract: Polyorganophosphazenes having at least some N-(acryloxyhydrocarbyl)carbamyloxyhydrocarbyloxy groups:H.sub.2 C.dbd.CHR--C(O)O--R--NH--C(O)O--R--O--bonded to phosphorus can be cross-linked by exposure to ultraviolet radiation.Type: GrantFiled: March 21, 1988Date of Patent: March 28, 1989Assignee: Ethyl CorporationInventor: Suae-Chen Chang
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Patent number: 4800230Abstract: Alpha-cyano-phenoxybenzyl esters are prepared by reacting an acid halide with an ester of an alpha-cyano-phenoxybenzyl alcohol in the presence of an inert polar aprotic solvent and a transition metal alkoxide catalyst.Type: GrantFiled: June 30, 1986Date of Patent: January 24, 1989Assignee: Ethyl CorporationInventor: Jerry M. Roper
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Patent number: 4745189Abstract: A method of preparing N-halogenated organic heterocyclic compounds by reacting in an aqueous mixture under alkaline conditions (e.g. NaOH) and in the presence of a halogenated organic compound (e.g. methylene chloride), a N-hydrogen organic heterocyclic compound containing at least one NH group (e.g. 5,5-dimethylhydantoin) and a halogen-producing chemical (e.g. Br.sub.2).Type: GrantFiled: June 23, 1986Date of Patent: May 17, 1988Assignee: Ethyl CorporationInventors: John Y. Lee, Mark A. Templeton
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Patent number: 4728463Abstract: Brominated styrene-maleate copolymer containing at least 50 weight percent bromine and its use as a fire retardant.Type: GrantFiled: August 18, 1986Date of Patent: March 1, 1988Assignee: Ethyl CorporationInventors: Burton J. Sutker, Gen-Shing Ti, Mo A. Khuddus
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Patent number: 4716251Abstract: Diaryloxyalkanes such as diphenoxyethane are brominated to give a product containing an average of about 5-7 bromine atoms per molecule by commingling a solution of the diaryloxyalkane in a haloalkane solvent with an excess of liquid bromine in the absence of a bromination catalyst.Type: GrantFiled: February 7, 1986Date of Patent: December 29, 1987Assignee: Ethyl CorporationInventors: Gerald L. Scymanski, Amgad S. Mossaad, Saadat Hussain
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Patent number: 4710306Abstract: A process for decolorizing iron-caused yellow color in brine solutions comprising adding a small amount of a soluble metal salt such as alugenite to the brine solution, neutralizing the solution and then filtering the solution to obtain a solution of a desired degree of clarity.Type: GrantFiled: January 22, 1985Date of Patent: December 1, 1987Assignee: Ethyl CorporationInventor: Warren B. Kirsch
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Patent number: 4701568Abstract: Tetrabromobisphenol-A is made in high purity by contacting a solution of bisphenol-A dissolved in a C.sub.1 -C.sub.4 alkanol with gaseous bromine.Type: GrantFiled: June 30, 1986Date of Patent: October 20, 1987Assignee: Ethyl CorporationInventors: Bonnie G. McKinnie, Olan W. Mitchell
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Patent number: 4652272Abstract: Coking in and around the injector nozzles of indirect injection compression ignition engines is reduced by means of distillate fuel with which has been blended suitable concentrations of (i) organic nitrate ignition accelerator, and (ii) a carboxylic acid ester.Also described are additive mixtures of (i) and (ii) for use in distillate fuels in amounts sufficient to reduce the coking tendencies of such fuels when used in the operation of indirect injection compression ignition engines.Type: GrantFiled: November 14, 1985Date of Patent: March 24, 1987Assignee: Ethyl CorporationInventors: Edward F. Zaweski, Leonard M. Niebylski
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Patent number: 4645538Abstract: An asphaltic composition of enhanced utility for vehicular pavement is described. It comprises a road paving grade of asphalt in admixture with a small amount of an alkylene dithiocarbamate such as methylene bis(dibutyldithiocarbamate) characterized by having a reduced increase in absolute viscosity to original absolute viscosity after thin film aging as measured by ASTM Test D 1754 at 140.degree. F. Such compositions exhibit enhanced resistance to oxidative degradation of the type normally experienced by road paving grades of asphalt.Type: GrantFiled: May 31, 1985Date of Patent: February 24, 1987Assignee: Ethyl CorporationInventors: William E. Wright, Edward F. Zaweski
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Patent number: 4639324Abstract: Lubricating oils having improved antioxidant and anti-wear properties are obtained by adding a minor amount of a reaction product made by reacting at least one aliphatic olefinically unsaturated hydrocarbon containing from about 8 to 36 carbon atoms (preferably an .alpha.-olefin) concurrently with sulfur and at least one fatty acid ester (preferably an oil such as cottonseed oil) to obtain a reaction intermediate and reacting this intermediate with additional sulfur and a dimer of cyclopentadiene or lower C.sub.1-4 alkyl substituted cyclopentadiene dimers, such as methylcyclopentadiene dimer.Type: GrantFiled: July 8, 1985Date of Patent: January 27, 1987Assignee: Ethyl Petroleum Additives, Inc.Inventor: William Y. Lam
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Patent number: 4626259Abstract: Coking in and around the injector nozzles of indirect injection compression ignition engines is reduced by means of distillate fuel with which has been blended suitable concentrations of (i) organic nitrate ignition accelerator, and (ii) a sterically hindered 4,4'-thiobis phenol.Also described are additive mixtures of (i) and (ii) for use in distillate fuels in amounts sufficient to reduce the coking tendencies of such fuels when used in the operation of indirect injection compression ignition engines.Type: GrantFiled: October 31, 1985Date of Patent: December 2, 1986Assignee: Ethyl CorporationInventors: Edward F. Zaweski, Leonard M. Niebylski
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Patent number: 4623363Abstract: Coking in and around the injector nozzles of indirect injection compression ignition engines is reduced by means of distillate fuel with which has been blended suitable concentrations of (i) organic nitrate ignition accelerator and (ii) a P.sub.2 S.sub.5 -terpene reaction product.Also described are additive mixtures of (i) and (ii) for use in distillate fuels in amounts sufficient to reduce the coking tendencies of such fuels when used in the operation of indirect injection compression ignition engines.Type: GrantFiled: November 27, 1985Date of Patent: November 18, 1986Assignee: Ethyl CorporationInventors: Edward F. Zaweski, Leonard M. Niebylski
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Patent number: 4623362Abstract: Coking in and around the injector nozzles of indirect injection compression ignition engines is reduced by means of distillate fuel with which has been blended suitable concentrations of (i) organic nitrate ignition accelerator, and (ii) an alkoxyalkanol.Also described are additive mixtures of (i) and (ii) for use in distillate fuels in amounts sufficient to reduce the coking tendencies of such fuels when used in the operation of indirect injection compression ignition engines.Type: GrantFiled: November 14, 1985Date of Patent: November 18, 1986Assignee: Ethyl CorporationInventors: Edward F. Zaweski, Leonard M. Niebylski
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Patent number: 4623360Abstract: Coking in and around the injector nozzles of indirect injection compression ignition engines is reduced by means of distillate fuel with which has been blended suitable concentrations of (i) organic nitrate ignition accelerator, and (ii) a boronated phenolic compound.Also described are additive mixtures of (i) and (ii) for use in distillate fuels in amounts sufficient to reduce the coking tendencies of such fuels when used in the operation of indirect injection compression ignition engines.Type: GrantFiled: October 31, 1985Date of Patent: November 18, 1986Assignee: Ethyl CorporationInventors: Edward F. Zaweski, Leonard M. Niebylski
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Patent number: 4623361Abstract: Coking in and around the injector nozzles of indirect injection compression ingition engines is reduced by means of distillate fuel with which has been blended suitable concentrations of (i) organic nitrate ignition accelerator, and (ii) organic phosphate.Also described are additive mixtures of (i) and (ii) for use in distillate fuels in amounts sufficient to reduce the coking tendencies of such fuels when used in the operation of indirect injection compression ignition engines.Type: GrantFiled: October 31, 1985Date of Patent: November 18, 1986Assignee: Ethyl CorporationInventors: Edward F. Zaweski, Leonard M. Niebylski