Patents Represented by Attorney W. T. Clarke
  • Patent number: 4442062
    Abstract: A process and apparatus are provided for the production of a non-woven fabric by melt-blowing wherein one or more yarns, e.g. monofilaments, are added or charged into the fabric stream between the extruder and collector by means of a supporting and drawing pressure gas stream. In one embodiment means are provided to regulate flow of the gas stream. In another embodiment means are provided to reciprocate or to rotate through a small arc the one or more charging means.
    Type: Grant
    Filed: October 2, 1980
    Date of Patent: April 10, 1984
    Assignee: Toa Nenryo Kogyo Kabushiki Kaisha
    Inventors: Shigeo Fujii, Tokuzo Ikeda, Takashi Mikami, Shuji Okano
  • Patent number: 4434205
    Abstract: An artificial leather is made by impregnating a special nonwoven web substrate with an elastic polymer material. In another embodiment the substrate comprises a nonwoven fabric laminated to a woven or nonwoven fabric.
    Type: Grant
    Filed: July 22, 1982
    Date of Patent: February 28, 1984
    Assignee: Toa Nenryo Kogyo Kabushiki Kaisha
    Inventors: Shigeo Fujii, Tokuzo Ikeda, Takashi Mikami, Shuji Okano
  • Patent number: 4375446
    Abstract: A process for producing a thermoplastic nonwoven fabric having a uniform thickness and optionally napped fibers according to a melt blowing method, which comprises blowing a fiber stream consisting of melt blown fibers and a gas at a high speed onto a plate within a valley-like fiber-collecting zone formed by two plates having a large number of pores, to form a uniform nonwoven fabric without scattering fibers.
    Type: Grant
    Filed: December 21, 1979
    Date of Patent: March 1, 1983
    Assignee: Toa Nenryo Kogyo Kabushiki Kaisha
    Inventors: Shigeo Fujii, Tokuzo Ikeda, Takashi Mikami, Shuji Okano
  • Patent number: 4295809
    Abstract: In an improved die-nose assembly for a melt-blowing process wherein molten resin is extruded from a series of die-holes while heated gas is blown out through slots on either side of the die nose associated therewith, spacers which are movable widthwise of the die assembly are provided in the gas slots to provide effective uniformity in the gas streams across the width of the die.
    Type: Grant
    Filed: September 14, 1979
    Date of Patent: October 20, 1981
    Assignee: Toa Nenryo Kogyo Kabushiki Kaisha
    Inventors: Takashi Mikami, Shigeo Fujii, Shuji Okano, Tokuzo Ikeda
  • Patent number: 4285655
    Abstract: An improved coat hanger die is provided wherein the manifold is curved and wherein the manifold radius, coat hanger slit part thickness and the form of the coat hanger die are determined by a formula which is disclosed all in relation to the radius of the manifold at its inlet. The radius of the manifold at its inlet is selected in consideration of the flow characteristics of the resin melt to provide a low melt velocity at the inlet.
    Type: Grant
    Filed: November 7, 1979
    Date of Patent: August 25, 1981
    Assignee: Toa Nenryo Kogyo Kabushiki Kaisha
    Inventor: Yutaka Matsubara
  • Patent number: 4238175
    Abstract: A process and apparatus are provided for the production of a non-woven fabric by melt-blowing wherein one or more yarns, e.g. monofilaments, are added or charged into the fabric stream between the extruder and collector by means of a supporting and drawing pressure gas stream. In one embodiment means are provided to regulate flow of the gas stream in another embodiment means are provided to reciprocate or to rotate through a small arc the one or more charging means.
    Type: Grant
    Filed: March 2, 1978
    Date of Patent: December 9, 1980
    Assignee: Toa Nenryo Kogyo Kabushiki Kaisha
    Inventors: Shigeo Fujii, Tokuzo Ikeda, Takashi Mikami, Shuji Okano
  • Patent number: 4146529
    Abstract: A process for the production of modified polyolefins by combining a polyolefin with one or more carboxylic acids or their anhydrides in the presence of a radical producing agent in an extruder and in the presence of an organosilane. If desired glass fibers can also be incorporated at the same time.
    Type: Grant
    Filed: September 29, 1977
    Date of Patent: March 27, 1979
    Assignee: Toa Nenryo Kogyo Kabushiki Kaisha
    Inventors: Noboru Yamamoto, Masaaki Isoi, Maoto Yoda, Shozo Wada
  • Patent number: 4146590
    Abstract: Modified polyolefin having high adhesion strength and less irritating odor during processing is obtained by reacting unsaturated carboxylic acid or its anhydride grafted polyolefin with a bifunctional compound having alcohol groups or amine groups. Preferable unsaturated carboxylic acids are maleic acid, and endobicyclo-[2,2,1]-5-heptene-2,3-dicarboxylic acid. Preferable bifunctional compounds are ethylene glycol, 1,4-butanediol, 1,6-hexanediol, glycerine, ethylene diamine, 1,3-diaminopropane m-phenylene diamine, etc.
    Type: Grant
    Filed: June 2, 1975
    Date of Patent: March 27, 1979
    Assignee: Toa Nenryo Kogyo Kabushiki Kaisha
    Inventors: Noboru Yamamoto, Makoto Yoda, Shozo Wada
  • Patent number: 4136219
    Abstract: Polyurethane paint is applied with good adhesion to a vulcanized rubber surface composed of halogenated butyl rubber or blends thereof with natural rubber, SBR rubber, EPDM rubber, polybutadiene rubber, acrylonitrile butadiene rubber, polychlorophrene rubber, synthetic polyisoprene rubber, or chloro sulfonated polyethylene rubber, the blends containing at least 30 phr halogenated butyl rubber, the rubber having been cured using a metal oxide or halide and an alkyl phenol polysulfide accelerator.
    Type: Grant
    Filed: March 18, 1977
    Date of Patent: January 23, 1979
    Inventors: Norman E. Odam, Bernard Costemalle
  • Patent number: 4127504
    Abstract: A process for the production of a catalyst component for use in the polymerization of .alpha.-olefins, which comprises reducing titanium tetrachloride with an organo aluminum compound having the general formula Al Rn X.sub.3-n wherein R represents a hydrocarbon group having 1 to 18 carbon atoms, x represents a halogen atom and n represents a suitable numeral between o<n.ltoreq.3, to thus obtain a reduced solid, then removing aluminum compounds contained in said reduced solid and activating with a mixture or a complex of titanium tetrachloride and a dialkyl ether of the general formula R'OR" wherein R' and R" are (a) alkyl groups having 1-4 carbon atoms, (b) normal alkyl groups having five carbon atoms, or (c) alkyl groups having 6-20 carbon atoms.
    Type: Grant
    Filed: November 24, 1976
    Date of Patent: November 28, 1978
    Assignee: Toa Nenryo Kogyo Kabushiki Kaisha
    Inventors: Hiroshi Ueno, Naomi Inaba, Tokuo Makishima, Shozo Wada
  • Patent number: 4127505
    Abstract: The invention relates to a process for the production of a catalyst component for use in the polymerization of .alpha.-olefins, which comprises reacting titanium tetrachloride with a dialkylaluminum monohalide and monoalkylaluminum dihalide, said dialkylaluminum monohalide being in a proportion of at least equimolar to said titanium tetrachloride, to thus obtain a violet reduced solid, then removing aluminum compounds contained in said reduced solid and further activating with a mixture or complex of titanium tetrachloride and a dialkyl ether of the general formula ROR' wherein R and R' are the same or different and are (a) alkyl groups having 1-4 carbon atoms, (b) normal alkyl groups having 5 carbon atoms or (c) alkyl groups having 6-20 carbon atoms and to a catalyst component prepared by the process of the invention.
    Type: Grant
    Filed: November 23, 1976
    Date of Patent: November 28, 1978
    Assignee: Toa Nenryo Kogyo Kabushiki Kaisha
    Inventors: Hiroshi Ueno, Naomi Inaba, Tokyo Makishima, Shozo Wada