Patents Represented by Law Firm Wells & Wells
  • Patent number: 4345066
    Abstract: Transparent, high molecular-weight copolyamides having high glass transition temperatures, based on:(1) lactams or omega-aminocarboxylic acids;(2) terephthalic acid, isophthalic acid, esters thereof, ester forming derivatives thereof, or mixtures thereof; and(3) mixtures of diamines; the copolyamide consisting of:(A) about 25 to 60 mole % of at least one omega-aminocarboxylic acid having at least 11 C atoms or its lactams;(B) about 40 to 75 mole % of an equivalent mixture of terephthalic acid, isophthalic acid or a mixture thereof, and a diamine mixture of about 80 to 50 mole % referred to the total diamines, of isophorone diamine and correspondingly about 20 to 50 mole % of diamines of the general formula ##STR1## where R.sub.1 and R.sub.2 are hydrogen atoms or alkyl groups having 1 to 4 C atoms and the sum of A+B amounts to 100 mole %.The copolyamides have utility as transparent, impact resistant molded articles.
    Type: Grant
    Filed: August 26, 1980
    Date of Patent: August 17, 1982
    Assignee: Chemische Werke Huls AG
    Inventor: Jorn Ruter
  • Patent number: 4345052
    Abstract: Method for manufacturing polyether ester amides by polycondensing at ordinary or reduced pressure, optionally in the presence of catalysts. A hot melt of:(a) polyamides having carboxyl end groups with polyethers having hydroxyl end groups and amino end groups;(b) polyamides having carboxyl end groups and polyethers having hydroxyl end groups;(c) polyamides having carboxyl end groups with polyethers having amino end groups; or(d) polyamides having amino end groups with polyethers having carboxyl end groups;is treated at temperatures from about 200.degree. to 300.degree. C. and at a water vapor pressure of about 5 to 25 bars with mechanical agitation and after water is removed by decompression the polycondensation of the polyether ester amide is carried out.
    Type: Grant
    Filed: July 10, 1980
    Date of Patent: August 17, 1982
    Assignee: Chemische Werke Huls AG
    Inventors: Salih Mumcu, Hans J. Panoch
  • Patent number: 4341831
    Abstract: A primer is provided as a bonding base in an extruded hollow aluminum shape ensheathed by a polyurethane foam. Due to the different coefficients of expansion between the plastic and the aluminum, changes in length take place, which cannot be adequately prevented using the known primers.The invention therefore solves the problem to widely prevent the shrinkage of the plastic sheath and simultaneously to provide a way of depositing the primer in a simple manner.This problem is solved by the invention in that the primer is a compound of resin, pigment and acid. The purpose of the acid is to cause the bonding reaction with the metal substrate, whereas the pigments on one hand cause the bonding reaction with the plastic sheath and on the other hand are used to ascertain the apparent film thickness.An improvement in adhesion of 1,000% is surprisingly achieved when using such a primer.
    Type: Grant
    Filed: May 4, 1981
    Date of Patent: July 27, 1982
    Assignee: Fulgeritwerke Seelze und Eichriede in Luthe bei Hannover Adolf Oesterheld GmbH & Co. Kommanditgesellschaft
    Inventor: Joachim Kleiss
  • Patent number: 4340752
    Abstract: A process for the purification of terephthalic acid in which a dispersion of the terephthalic acid in a liquid dispersant such as acetic acid is continuously pumped repeatedly through a cycle. Fresh dispersion is fed continuously into the cycle while simultaneously a corresponding amount of treated dispersion is removed. The cycle comprises a heater and a cooler and the cooler serves as a crystallizer. The dispersion prior to entering the heater is subjected to a highly effective particle comminution and is exposed upstream of or in the heater to an oxygen containing gas such as air. The acetic acid dispersant is removed from the treated dispersion and recycled to the cycle.
    Type: Grant
    Filed: March 21, 1978
    Date of Patent: July 20, 1982
    Assignee: Chemische Werke Huls AG
    Inventors: Ferdinand List, Friedrich-August Orlowski
  • Patent number: 4337319
    Abstract: Self-extinguishing, fine particulate, expandable styrene polymers for the manufacture of molded articles, containing bromine compounds and one synergist. The synergist, referred to the styrene polymer, is at least one hydrocarbon present in amounts from about 0.1 to 3% by weight and forms stable radicals at temperatures above 300.degree. C.
    Type: Grant
    Filed: November 12, 1980
    Date of Patent: June 29, 1982
    Assignee: Chemische Werke Huls AG
    Inventors: Josef K. Rigler, Hans-Josef Ratajczak, Horst Leithauser, Karl Trukenbrod
  • Patent number: 4337234
    Abstract: A process for preparing sodium bicarbonate and hydrogen chloride by reacting an aqueous sodium chloride solution with carbon dioxide under pressure in the presence of an amine and of an organic solvent.1. Carbon dioxide is introduced under a pressure of5-80 bars into a mixture essentially containing1.1 an aqueous sodium chloride solution,1.2 a tertiary amine,1.3 a non-polar, organic solvent, and1.4 a polar, organic solvent having a boiling point above 140.degree. C.,2. the aqueous and organic phases obtained are separated under the same pressure as step 1,3. the aqueous phase is rid of the precipitated sodium bicarbonate and following reconcentration with sodium chloride is fed back into process stage 1 (carbonization),4. the organic phase(s) containing the polar and non-polar organic solvents is (are) heated and the hydrogen chloride released is evacuated, and5. the tertiary amine, polar and non-polar organic solvents from step 4 are recirculated to step 1.
    Type: Grant
    Filed: October 3, 1980
    Date of Patent: June 29, 1982
    Assignee: Chemische Werke Huls AG
    Inventors: Bernhard Hentschel, Jurgen Ziebarth, Alfred Coenen, Kurt Kosswig, Ferdinand von Praun
  • Patent number: 4335826
    Abstract: A container 10 has a release device which comprises a flexible plate 14 and a line 17 attached to the contents 11 of the container; when a force is applied to line 17 it is communicated to plate 14 which flexes and is pulled clear of a retaining flange 13 to release contents 11. As shown, the force is applied to the plate 14 via washers 18,19 and 20. Plate 14 preferably has radially directed fingers. The container may constitute part of a rocket-launched projectile and may be used to release a parachute at a desired height, the other end of line 17 being fixed.
    Type: Grant
    Filed: August 26, 1980
    Date of Patent: June 22, 1982
    Inventors: Henry M. Prain, Andrew M. Scott
  • Patent number: 4334056
    Abstract: Polyamide powder coating compositions for the coating of metals at high temperatures are obtained by the precipitation method from polyamides having at least 10 aliphatically bound carbon atoms per carbonamide group, copolyamides having at least 70% of these polyamides and mixtures of homopolyamides and copolyamides having at least 70% of these polyamides.A. For the preparation of powder coating compositions useful in the fluidized bed coating method the polyamides with 10 or more carbon atoms and having a relative viscosity between 1.4 and 1.8 are added to at least twice the amount by weight of ethanol and while the mixture is being mechanically mixed in a closed vessel is converted into a solution at temperatures between 130.degree. and 150.degree. C. This solution is adjusted to a precipitation temperature of between 100.degree. and 125.degree. C. while avoiding the formation of local sub-cooling and is agitated under an inert gas atmosphere to suppress boiling.
    Type: Grant
    Filed: February 20, 1980
    Date of Patent: June 8, 1982
    Assignee: Chemische Werke Huls AG
    Inventors: Klaus-Rudolf Meyer, Karl-Heinz Hornung, Rainer Feldmann, Hans-Jurgen Smigerski
  • Patent number: 4329014
    Abstract: An incident light illumination apparatus for generating light and dark field illumination along an optical axis. The illumination apparatus is coupled to a stage arm of a microscope and a microscope tube is coupled to the illumination apparatus.An illumination stub (7) is located in the illumination apparatus along the optical axis between a light source (8) and an optical deflecting element (11). An aperture (13) passes through the stub from side-to-side for the interchangeable insertion of an insertion module (14,15). This insertion module contains at least two functional groups (I,II; III,II) which can be sequentially placed into the optical axis (9) and the functional groups consist of light attenuating (25) and/or light bounding (19,20,23,24,27) optical components, and additional means (28,29) for pivoting a center stop (30) into the optical axis (9).
    Type: Grant
    Filed: June 13, 1980
    Date of Patent: May 11, 1982
    Assignee: Ernst Leitz Wetzlar GmbH
    Inventors: Gunter Reinheimer, Norbert Gaul
  • Patent number: 4321247
    Abstract: A process for producing sodium bicarbonate and hydrogen chloride by reacting an aqueous sodium chloride solution with carbon dioxide in the presence of an amine and an organic solvent. The steps of the process are carried out, wherein:(1) carbon dioxide is introduced into a mixture containing essentially(1.1) an aqueous sodium chloride solution,(1.2) a tertiary amine, and(1.3) a polar, organic solvent;(2) the aqueous and organic phases so obtained are separated;(3) the aqueous phase freed from the separated sodium bicarbonate following reconcentration with sodium chloride is fed back into process stage 1 (carbonization stage);(4) the organic phase (s) (is) are separated from the polar organic solvent and possibly of water to the widest possible extent and/or required; and(5) the residue containing a non-polar solvent is heated and the hydrogen chloride is removed.
    Type: Grant
    Filed: October 3, 1980
    Date of Patent: March 23, 1982
    Assignee: Chemische Werke Huls AG
    Inventors: Alfred Coenen, Kurt Kosswig, Ferdinand v. Praun, Hans Regner
  • Patent number: 4320106
    Abstract: A process for preparing sodium bicarbonate and hydrogen chloride by reacting an aqueous sodium chloride solution with carbon dioxide under pressure in the presence of an amine and of an organic solvent.1. Carbon dioxide is introduced under a pressure of8-80 bars into a mixture essentially containing1.1 an aqueous sodium chloride solution,1.2 a tertiary amine,1.3 a non-polar organic solvent, and1.4 a polar, organic solvent having a boiling point above 140.degree. C.,2. the aqueous and organic phases obtained are separated under the same pressure as step 1,3. the aqueous phase is rid of the precipitated sodium bicarbonate and following reconcentration with sodium chloride is fed back into process stage 1 (carbonization),4. the organic phase(s) containing the polar and non-polar organic solvents is (are) heated and the hydrogen chloride released is evacuated, and5. the tertiary amine, polar and non-polar organic solvents from step 4 are recirculated in step 1.
    Type: Grant
    Filed: October 23, 1980
    Date of Patent: March 16, 1982
    Assignee: Chemische Werke Huls AG
    Inventors: Bernhard Hentschel, Jurgen Ziebarth, Alfred Coenen, Kurt Kosswig, Ferdinand V. Praun
  • Patent number: 4320237
    Abstract: Method for the hydroformylation of olefins with carbon monoxide and hydrogen in the presence of soluble cobalt compounds as the catalyst at an elevated temperature and under increased pressure, and optionally in the presence of paraffins and/or other inert diluents. The hydroformylation is conducted, in a first stage, up to a conversion of about 40-75 percent with remixing of the reaction mixture, and then, in a second stage, up to a conversion of at least 95 percent, preferably 95-98 percent, without remixing.
    Type: Grant
    Filed: April 7, 1978
    Date of Patent: March 16, 1982
    Assignee: Chemische Werke Huls AG
    Inventors: Manfred Kaufhold, Johann Gaube
  • Patent number: 4315053
    Abstract: An article having a substrate and a multilayer coating composition adhered thereto. The multilayer coating has a pigmented base film and deposited on the base film is a transparent coating which has no intermixing and no intersolution between the base coating and the transparent coating. The transparent coating is a cross linking resin containing hydroxyl groups obtained by esterifying polycarboxylic acids with polyols.
    Type: Grant
    Filed: May 28, 1980
    Date of Patent: February 9, 1982
    Assignee: BASF Farben & Fasern AG
    Inventors: Ulrich Poth, Dieter Moller, Arnold Dobbelstein
  • Patent number: 4310473
    Abstract: The process for separating sulfuric acid from the sulfoxidation output obtained when paraffins are reacted with sulfuric acid, oxygen and water in the presence of ultraviolet light, using an alcohol containing at least 5 C atoms, is improved by treating the sulfoxidation output with a 0.25 to 2.5 fold amount by weight of a mixture of(a) 40 to 95% by weight of alcohol, and(b) 5 to 60% by weight of paraffins and the aqueous phase formed thereby is separated with the sulfuric acid.
    Type: Grant
    Filed: March 3, 1981
    Date of Patent: January 12, 1982
    Assignee: Chemische Werke Huls AG
    Inventors: Hermann Springmann, Karl Borchers
  • Patent number: 4310442
    Abstract: The activity and the service life of supported silver catalysts used in the preparation of ethylene oxide by the catalytic vapor phase oxidation of ethylene with molecular oxygen are extended by using mixtures of:(a) supported silver catalysts and promoter metal compounds;(b) supported silver catalysts and supported promoter metal compounds;(c) promoter metal compound treated supported silver catalysts and promoter metal compounds; or(d) promoter metal compound treated supported silver catalysts and supported promoter metal compounds.Promoter metal compounds containing about 0.001-0.05% by weight rubidium, about 0.01-0.20% by weight potassium, about 0.001-0.5% by weight cesium or about 0.01-0.25% by weight barium, based on the total weight of catalyst, are suitable.
    Type: Grant
    Filed: June 24, 1980
    Date of Patent: January 12, 1982
    Assignee: Chemische Werke Huls AG
    Inventors: Erwin Vangermain, Claus-Dieter Mengler, Rainer Elm, Horst Ueberschaer, Wilhelm Brauckmann
  • Patent number: 4306889
    Abstract: An adsorber device for drying compressed gas comprises a first and a second chamber which operate alternately on drying and on regenerating the desiccant contained in the chambers. Regenerating is accomplished by branching-off a partial flow of dried gas at the outlet side of the chamber operating on drying and supplying the partial gas flow to the chamber working on regenerating. Means are provided for limiting the branched-off partial gas flow to the gas volume actually needed for regenerating. Embodiments are described wherein this gas limiting is accomplished with a constant partial gas flow prevailing between the two chambers and, further, embodiments are described wherein this partial gas flow is adjusted in accordance with the main gas flow through the chamber working on drying.
    Type: Grant
    Filed: July 28, 1980
    Date of Patent: December 22, 1981
    Assignees: Pintsch Bamag Gastechnik GmbH, Rudolf Schafer Ingenieurtechnik GmbH
    Inventors: Christoph Kruger, Rudolf Schafer
  • Patent number: 4305844
    Abstract: A process for preparing silver catalysts containing alkaline earth metals and alkali metals as promoters for the production of ethylene oxide by oxidizing ethylene with oxygen or oxygen-containing gases. The silver catalysts are prepared by:(a) depositing a suspension consisting of silver oxide and an aqueous solution of an organic silver salt on a porous substrate, the molar ratio of the silver in the silver oxide to the silver in the silver salt being from about 35 to 65%, and periodically increasing the pressure (decreasing the vacuum) being used during the absorption;(b) carrying out an interim drying as a thin moving bed in an inert gas atmosphere at temperatures between about 50.degree. and 150.degree. C.
    Type: Grant
    Filed: March 31, 1980
    Date of Patent: December 15, 1981
    Assignee: Chemische Werke Huls AG
    Inventors: Erwin Vangermain, Willi Brauckmann, Hans-Jurgen Erberich, Horst Ueberschaer
  • Patent number: 4305917
    Abstract: According to the present invention, ammonia and hydrogen chloride are prepared from ammonium chloride.The steps of the process include:1. heating a mixture consisting essentially of(a) ammonium chloride,(b) a water-insoluble amine, and(c) an organic solvent;2. evacuating the ammonia released thereby;3. removing the polar solvent and any water remaining in the sump to the extent possible and/or required; and4. heating the residue containing a non-polar and/or a weakly polar solvent and removing the hydrogen chloride.
    Type: Grant
    Filed: September 26, 1980
    Date of Patent: December 15, 1981
    Assignee: Chemische Werke Huls AG
    Inventors: Alfred Coenen, Kurt Kosswig, Dieter Balzer
  • Patent number: 4301654
    Abstract: The principle of the acid/soda fire extinguisher is applied to generating pressure in the expansible chamber of a power plant or engine.Pressure is generated in a first container by adding sulfuric acid to a bicarbonate of soda solution and the pressurized solution is applied alternatively to the two sides of a double acting piston. The unpressurized side of the piston is alternatively connected to a second container for the collection of used solution.When the solution in the first container is used up, the solution in the second container is activated by the addition of more sulfuric acid and the cycle is reversed.
    Type: Grant
    Filed: November 6, 1979
    Date of Patent: November 24, 1981
    Inventor: David W. Hayden
  • Patent number: 4287130
    Abstract: The process for reacting olefins with ozone in a carboxylic acid medium using pure oxygen or an oxygenated gas mixture for the ozone production, is improved by recycling the oxygen or the oxygenated gas mixture leaving the ozonizing stage.The oxygen containing gas leaving the ozonizing stage is:(a) washed with the carboxylic acid input of the ozonizing stage,(b) treated with an aqueous solution of an alkalinically reacting substance, and lastly,(c) dried and fed back to the ozonizer.
    Type: Grant
    Filed: September 26, 1980
    Date of Patent: September 1, 1981
    Assignee: Chemische Werke Huls A.G.
    Inventors: Klaus-Dieter Dohm, Peter Hofmann