Patents Represented by Attorney Willard R. Sprowls
  • Patent number: 4105601
    Abstract: Novel blowing agents are disclosed comprising 3,3'-carbonylbis(organo carbazates). The organo group may be alkyl, cycloalkyl, aryl or aralkyl moieties. In the preferred embodiment the organo group is an alkyl group selected from the group consisting of methyl, isopropyl, secondary butyl or tertiary butyl. The blowing agents find utility in the preparation of expanded organoplastic materials such as rubbers, thermosetting resins and thermoplastic resins.
    Type: Grant
    Filed: March 30, 1977
    Date of Patent: August 8, 1978
    Assignee: Uniroyal, Inc.
    Inventors: Byron A. Hunter, Franklin H. Barrows
  • Patent number: 4010028
    Abstract: A bonded calcium carbide article that is solid and self-supporting is obtained by mixing granular calcium carbide with a suitable bonding agent. The resultant bonded calcium carbide article, which is easy and safe to handle, can be effectively and efficiently used as a sulfur scavenger in the refining of metals and metal alloys.
    Type: Grant
    Filed: July 29, 1974
    Date of Patent: March 1, 1977
    Assignee: Uniroyal Inc.
    Inventors: Donald A. Irwin, Sr., Gordon H. Madge, Charles F. Kloss, Allen L. Stone
  • Patent number: 4003940
    Abstract: New sulfites derived from alkynols and glycol ethers of phenylphenols are provided which are useful as insecticides and acaricides and which exhibit substantially reduced phytotoxicity than similarly used compounds. This invention also deals with the use of the novel sulfites in treating plants.
    Type: Grant
    Filed: July 23, 1975
    Date of Patent: January 18, 1977
    Assignee: Uniroyal Inc.
    Inventors: Rupert A. Covey, Robert E. Grahame, Jr.
  • Patent number: 3998783
    Abstract: Polymers are flame-retarded by novel combinations of additives comprising:A. a specified compound of iron, cobalt, nickel, tin or antimony,B. an alkali metal chloride, bromide or iodide, andC. an organic acid or inorganic acid salt. Alternatively, additive (c) may be an integral part of the polymer in whole or in part.
    Type: Grant
    Filed: December 11, 1975
    Date of Patent: December 21, 1976
    Assignee: Uniroyal Inc.
    Inventor: William Paul Whelan, Jr.
  • Patent number: 3996194
    Abstract: This invention is directed to 1,5-bis(3',5'-dihydrocarbyl-4'-hydroxyphenyl)pentyl derivatives, including the 3-pentyl ester, amine and amide compounds. It also deals with the stabilization of organic materials by incorporating such compounds therein, either alone or in combination with a dialkyl 3,3'-thiodipropionate or a tri(alkaryl)phosphite.
    Type: Grant
    Filed: February 26, 1975
    Date of Patent: December 7, 1976
    Assignee: Uniroyal Inc.
    Inventors: Richard A. Gencarelli, Edward L. Wheeler
  • Patent number: 3991036
    Abstract: Disclosed are new chemical compounds namely 1,4-dialkanols of octahydrothieno[3,4-b]pyrazine 6,6-dioxides, and 4-alkanols of octahydrothieno[3,4-b]pyrazine 6,6-dioxides, the use of such compounds in the production of polyurethanes, and methods of making such compounds.
    Type: Grant
    Filed: December 15, 1975
    Date of Patent: November 9, 1976
    Assignee: Uniroyal Inc.
    Inventors: Walter Nudenberg, Edward L. Hagen, Julian R. Little, Chung-Ling Mao
  • Patent number: 3976664
    Abstract: There are disclosed novel, dodecahalo-9,10-oxadecahydro-1,4:5,8-dimethanoanthracenes which are useful as flame retardant additives for acrylonitrile-butadiene-styrene (ABS) gum plastics and other polymeric materials, and a method for preparing these novel anthracenes.
    Type: Grant
    Filed: July 29, 1974
    Date of Patent: August 24, 1976
    Assignee: Uniroyal Inc.
    Inventors: Yong S. Rim, Walter Nudenberg
  • Patent number: 3976672
    Abstract: Novel (hydrocarbylphenylsulfonyl)alkyltrimethyl stannanes and a process for preparing same are disclosed. These stannane compounds correspond to the following formula: ##SPC1##Wherein R' is the same or different and is selected from the group consisting of linear and branched alkyl having 1 to 20 carbon atoms, cycloaliphatic having 4 to 6 carbon atoms and linear and branched alkenyl having 2 to 20 carbon atoms, m is an integer from 1 to 3 and n is an integer from 2 to 11.The stannane compounds of this invention exhibit insecticidal properties when employed in insecticidal formulations.
    Type: Grant
    Filed: December 15, 1975
    Date of Patent: August 24, 1976
    Assignee: Uniroyal Inc.
    Inventors: Richard J. Strunk, Winchester Loomis Hubbard
  • Patent number: 3962482
    Abstract: Clear, elastic, water gels and gel-forming compositions are based on potassium-sensitive carrageenan in the form of an alkali metal or an ammonium salt and a water-soluble potassium salt. Addition to the composition of calcium-sensitive carrageenan, also in the form of an alkali metal or an ammonium salt, imparts freedom from syneresis. The water gels and the gel-forming compositions are characterized by essentially complete freedom from polyvalent metal cations.
    Type: Grant
    Filed: June 2, 1975
    Date of Patent: June 8, 1976
    Assignee: Uniroyal, Ltd.
    Inventors: Frederick W. Comer, Clifford H. G. Strong
  • Patent number: 3955994
    Abstract: Cementitious structures characterized by improved durability and weather resistance are obtained by: Incorporating alkyl and alkenyl succinic acids, their anhydrides, acid esters, acid amides, halogenated compounds and salts, into cementitious mixtures prior to setting; applying said succinic compounds onto concrete subsequent to setting; or by a combination of the forgoing steps; said alkyl and alkenyl substituents containing from 8 to 40 carbon atoms.
    Type: Grant
    Filed: December 16, 1974
    Date of Patent: May 11, 1976
    Assignee: Uniroyal Inc.
    Inventors: Byron A. Hunter, John W. Zukel
  • Patent number: 3956139
    Abstract: Polymers are flame-retarded by novel combinations of additives comprising:A. a specified compound of iron, cobalt, nickel, tin or antimony,B. an alkali metal chloride, bromide or iodide, andC. an organic acid or inorganic acid salt.Alternatively, additive (c) may be an integral part of the polymer in whole or in part.
    Type: Grant
    Filed: September 12, 1973
    Date of Patent: May 11, 1976
    Assignee: Uniroyal Inc.
    Inventor: William Paul Whelan, Jr.
  • Patent number: 3951894
    Abstract: New flame-retarded rubber and plastic compositions are disclosed which are economical to produce and which exhibit increased flame-retardance and reduced toxicity. Generally, these new compositions comprise a copolymer of acrylonitrile-butadiene rubber or a terpolymer of acrylonitrile, butadiene and styrene, a bromine- or chlorine-containing organic fire-retardant additive, and an iron compound selected from a specified group.
    Type: Grant
    Filed: October 17, 1974
    Date of Patent: April 20, 1976
    Assignee: Uniroyal Inc.
    Inventor: William Paul Whelan, Jr.
  • Patent number: 3944528
    Abstract: This invention relates to a solution process for preparing copolymers of a conjugated diene hydrocarbon and a vinyl-substituted aromatic hydrocarbon using a potassium-modified organolithium catalyst. The Li/K molar ratio is varied depending upon whether a random or pseudorandom copolymer is desired and depending on whether an aliphatic hydrocarbon or aromatic hydrocarbon solvent or a mixture of such solvents is used. The invention includes the pseudorandom copolymers formed by the process of the invention, such copolymers being characterized, in part, by having blocks with two to four units of the vinyl-substituted aromatic hydrocarbon interspersed throughout the copolymer chain.
    Type: Grant
    Filed: February 12, 1975
    Date of Patent: March 16, 1976
    Assignee: Uniroyal, Inc.
    Inventor: Frederick C. Loveless
  • Patent number: 3940146
    Abstract: This invention relates to an improved golf ball cover comprised of an ionomer based upon the copolymers of, e.g., ethylene and acrylic or methacrylic acid and a chlorosulfonated polyethylene. Covers made in accordance with this invention exhibit high durability features.
    Type: Grant
    Filed: August 21, 1972
    Date of Patent: February 24, 1976
    Assignee: Uniroyal Inc.
    Inventor: James F. Little
  • Patent number: 3940396
    Abstract: Disclosed are new chemical compounds namely 1,4-dialkanols of octahydrothieno[3,4-b]pyrazine 6,6-dioxides and 4-alkanols of octahydrothieno[3,4-b]pyrazine 6,6-dioxides, the use of such compounds in the production of polyurethanes, and methods of making such compounds.
    Type: Grant
    Filed: February 28, 1973
    Date of Patent: February 24, 1976
    Assignee: Uniroyal Inc.
    Inventors: Walter Nudenberg, Edward L. Hagen, Julian R. Little, Chung-Ling Mao
  • Patent number: 3939119
    Abstract: Thermoplastic copolymers are formed by the interaction of a 4-mercaptophenol and a dihalo-substituted aromatic sulfone of the structureX--phenylene-SO.sub.2 2-phenylene) .sub.y X, wherein y is 1 or 2. The latter are typified by 4,4'-dichlorodiphenyl sulfone and 4,4'-bis(4-chlorophenylsulfonyl)biphenyl. The mercoptophenol may have one or two lower alkyl groups ortho to the hydroxyl.The polymers are characterized by high glass transition temperatures and high impact strength.
    Type: Grant
    Filed: May 27, 1971
    Date of Patent: February 17, 1976
    Assignee: Uniroyal, Inc.
    Inventor: Francis X. O'Shea
  • Patent number: 3933714
    Abstract: Adhesive-coated tire cord fabric and similar fabric and single end cords for other end uses can be protected from the adverse effects of atmospheric pollutants, prior to the adhesion of such fabrics to rubber, by incorporating N,N'-ethylene bis-stearamide in the adhesive formulation.
    Type: Grant
    Filed: October 21, 1974
    Date of Patent: January 20, 1976
    Assignee: Uniroyal Inc.
    Inventor: Hansford Tyson Adams
  • Patent number: 3932565
    Abstract: Polymeric bromine-containing phosphoramidate polyols are obtained by reacting bromine with spirocyclic phosphoramidites and thereafter reacting the brominated products with a polyol, in the presence of an acid acceptor. The novel viscous polymers thus produced react with polyisocyanates to produce polyurethanes. Polyurethanes so made are characterized by improved flame-retardant properties compared with conventional polyurethanes.
    Type: Grant
    Filed: December 26, 1973
    Date of Patent: January 13, 1976
    Assignee: Uniroyal Inc.
    Inventor: Wadim Batorewicz
  • Patent number: 3932633
    Abstract: Certain o-triazenobenzamides are useful as anti-aggression agents. Certain methods of perparation are novel.
    Type: Grant
    Filed: March 4, 1974
    Date of Patent: January 13, 1976
    Assignee: Uniroyal Inc.
    Inventors: John Terence O'Brien, Zaven S. Ariyan