Abstract: A golf ball comprising a core having a first density formed from a diene rubber composition including glass microspheres having an isotactic crush strength of about 5,000 psi or greater and having a true density of about 0.70 g/cm3 or less, the microspheres being present in an amount sufficient to lower the first density to about 1.05 g/cm3 or less; a cover; and an intermediate layer disposed between the core and the cover, the intermediate layer having a density of from about 1.3 g/cm3 to about 1.9 g/cm3 and including a composition formed from a compatibilized blend of a non-ionic fluoropolymer and an acrylate-based polymer; wherein a ratio of the core density to the intermediate layer density is between about 0.81 to about 0.5.
Type:
Grant
Filed:
June 14, 2004
Date of Patent:
March 7, 2006
Assignee:
Acushnet Company
Inventors:
Murali Rajagopalan, Douglas S. Goguen, Pamela V. Arnold
Abstract: A golf ball including a core including a halogenated thiophenol and having a diameter of from about 1.3 inches to about 1.4 inches, a compression of about 44 or less; and a coefficient of restitution of from about 0.770 to about 0.810; a cast polyurethane or polyurea cover; and an intermediate layer disposed between the core and the cover, the intermediate layer having a thickness of from about 0.11 inches to about 0.12 inches and being formed from a composition including at least two ionomers; wherein a combination of the core and the intermediate layer results in a compression of from about 70 to about 100, and the golf ball has a coefficient of restitution of from about 0.805 to about 0.820 at about 125 ft/s and a compression of from about 75 to about 105.
Abstract: An automated flash/overflow removal system for the manufacturing of golf balls, including a gripping assembly mounted on a motion system. The gripping assembly includes a plurality of gripping members capable of clamping and releasing the flash/overflow from a golf ball mold portion.
Abstract: A golf ball comprising a core comprised of a polymer containing an acid group fully-neutralized by an organic acid or a salt, a cation source, or a suitable base thereof, the core having a first Shore D hardness, a compression of no greater than about 90, and a diameter of between about 1.00 inches and about 1.64 inches; and a cover layer comprising ionomeric copolymers and terpolymers, ionomer precursors, thermoplastics, thermoplastic elastomers, polybutadiene rubber, balata, grafted metallocene-catalyzed polymers, non-grafted metallocene-catalyzed polymers, single-site polymers, high-crystalline acid polymers and their ionomers, or cationic ionomers.
Type:
Grant
Filed:
May 5, 2004
Date of Patent:
February 7, 2006
Assignee:
Acushnet Company
Inventors:
Murali Rajagopalan, Michael J. Sullivan
Abstract: A golf ball including a core; an intermediate layer formed from a polymer blend including a first material having a flexural modulus of between about 65,000 psi and about 120,000 psi and a second material including a grafted-metallocene polymer; and a cover layer formed from a castable reactive liquid material.
Type:
Grant
Filed:
September 22, 2003
Date of Patent:
January 31, 2006
Assignee:
Acushnet Company
Inventors:
Herbert C. Boehm, William E. Morgan, Jeffrey L. Dalton, Douglas E. Jones, Christopher Cavallaro, Murali Rajagopalan
Abstract: A golf ball including a core and a cover layer, where the cover layer includes a curing agent and a polyurethane/urea hybrid prepolymer formed from a polyisocyanate and a monodisperse heterotelechelic polymer having a polydispersity of from about 1.0 to about 1.
Abstract: A golf ball including a core and a cover layer including a curing agent and a polyurethane prepolymer formed from a polyisocyanate and a monodisperse telechelic polyol having a polydispersity of from about 1.0 to about 1.3, and having the formula: T-Zn-C-Y-C-Zn-T where Y is at least one molecule or mixtures of molecules having at least two independently polymerized vinyl groups, such as 1,3-divinylbenzene or 1,4-divinylbenzene; C is a hydrogenated or unsaturated block derived by anionic polymerization of at least one monomer selected from the group consisting of conjugated dienes, alkenyl-substituted aromatics, and mixtures thereof; Zn is a branched or straight chain hydrocarbon connecting group which contains n=1ā50 carbon atoms; and T is hydroxyl.
Abstract: A golf ball including a core and a cover layer including a curing agent and a polyurea prepolymer formed from a polyisocyanate and a monodisperse telechelic polyamine having a polydispersity of from about 1.0 to about 1.3, and having the formula: T-Zn-CāYāC-Zn-T where Y is at least one molecule or mixtures of molecules having at least two independently polymerized vinyl groups, such as 1,3-divinylbenzene or 1,4-divinylbenzene; C is a hydrogenated or unsaturated block derived by anionic polymerization of at least one monomer selected from the group consisting of conjugated dienes, alkenyl-substituted aromatics, and mixtures thereof; Zn is a branched or straight chain hydrocarbon connecting group which contains n=1ā50 carbon atoms; and T is primary or secondary amine.
Abstract: A golf ball comprising a core including a center having an outer diameter from about 0.375 inches to about 1.4 inches and deflection of greater than about 4.5 mm under a load of 100 Kg and an outer core layer having an outer diameter of from about 1.4 in to about 1.62 in, wherein at least one of the center or core layer includes polybutadiene rubber composition including a halogenated organosulfur compound or a metal salt thereof, and a cover including an inner cover layer having an outer diameter of greater than about 1.58 in and a material hardness of less than about 72 Shore D and an outer cover layer having a hardness of greater than about 50 Shore D and a material hardness of less than about 50 Shore D.
Type:
Grant
Filed:
January 17, 2003
Date of Patent:
November 1, 2005
Assignee:
Acushnet Company
Inventors:
Christopher Cavallaro, Ryan W Bosanko, Peter R Voorheis
Abstract: A golf ball with a center and a cover layer formed over the center is disclosed. The center exhibits a high velocity and is soft with a compression of less than about 75. The cover layer is soft with a Shore D hardness on the ball of less than about 58. The cover layer includes an ionomer component and a metallocene polymer component. The ionomer component can be a single ionomer or a blend of ionomers. The metallocene polymer component can be a single metallocene polymer or a blend of metallocene polymers.
Abstract: A golf ball comprising a core and a cover, wherein the core or the cover comprises a thermoplastic or thermoset composition comprising a polyurethane prepolymer formed from a reactant A comprising an isocyanate; and a reactant B comprising a polyether polyol having a repeating branched oxyalkylene monomer unit, or a polymerized polyol formed from a chiral diol or a chiral cyclic ether.
Abstract: A golf ball is provided that has improved aerodynamic efficiency, resulting in increased flight distance for golfers of all swing speeds, and more particularly for golfers possessing very high swing speeds, such as those who can launch the balls at an initial speed greater than 160 miles per hour and more particularly at initial ball speed of about 170 miles per hour or higher. The golf ball of the present invention combines lower dimple count with multiple dimple sizes to provide higher dimple coverage and improved aerodynamic characteristics.
Abstract: A golf ball comprising a core formed from a composition comprising a metal salt of an unsaturated organic acid and at least one co-curing agent comprising an unsaturated imide or a metallic derivatives thereof; and a cover layer.
Abstract: A golf ball comprising a core comprised of a polymer containing an acid group fully-neutralized by an organic acid or a salt, a cation source, or a suitable base thereof, the core having a first Shore D hardness, a compression of no greater than about 80, and a diameter of no less than about 1.53 inches; and a cover formed of a blend comprising polyurethanes and polyureas or a copolymer comprising urethane and urea segments.
Type:
Grant
Filed:
February 6, 2003
Date of Patent:
September 6, 2005
Assignee:
Acushnet Company
Inventors:
Murali Rajagopalan, Michael J. Sullivan
Abstract: A method of forming a golf ball core includes compression molding a core material in a mold cavity to form a partially-cured core, then the partially-cured core is removed from the mold cavity and placed in a medium to continue curing until it is substantially-cured. The method can also be used to form a golf ball by adding the step of forming a cover layer over the substantially-cured core.
Abstract: A method for increasing adhesion between golf ball layers comprising the steps of providing a golf ball layer having a first surface; preparing the first surface for treatment; exposing the first layer to a silane; providing a second golf ball layer; and adhering the second layer to the first via the silane. Additionally, a golf ball including an inner component, a molecular monolayer, and at least one cover layer, wherein the inner component and the at least one cover layer have differing surface energies and the cover layer is adhered to inner component with the molecular monolayer.
Abstract: A golf ball including a core, a cover, and, optionally, an intermediate layer disposed between the core and the cover, wherein at least one of the core, cover layer, or optional intermediate layer includes at least one dendritic macromolecule.
Type:
Grant
Filed:
June 6, 2003
Date of Patent:
August 2, 2005
Assignee:
Acushnet Company
Inventors:
William E Morgan, Kevin M Harris, Murali Rajagopalan, Shenshen Wu, Manjari Kuntimaddi
Abstract: A golf ball comprising a core and a cover, wherein at least one of the core and the cover is formed of a composition comprising an organic, inorganic, or metallic nanoparticulate material having a particle size of less than about 1000 nm and at least one matrix material.
Type:
Grant
Filed:
January 4, 2002
Date of Patent:
July 19, 2005
Assignee:
Acushnet Company
Inventors:
Murali Rajagopalan, Mitchell E. Lutz, Peter R. Voorheis
Abstract: A golf ball comprising a core and a cover disposed about the core, wherein the core comprises a center and at least one outer core layer adjacent the center, and the cover comprises at least one inner cover layer and an outer cover layer, wherein the center has an outer diameter from about 0.375 in to about 1.4 in and deflection of greater than about 4.5 mm under a load of 100 Kg, the outer core layer has an outer diameter of from about 1.4 in to about 1.62 in, the inner cover layer has an outer diameter of greater than about 1.58 in and a material hardness of less than about 72 Shore D, and the outer cover layer has a hardness of greater than about 50 Shore D.
Type:
Grant
Filed:
February 13, 2001
Date of Patent:
July 5, 2005
Assignee:
Acushnet Company
Inventors:
Christopher Cavallaro, Ryan B. Bosanko, Edmund A. Hebert
Abstract: A golf ball comprising a core having a compression greater than about 55; and an outer cover comprising an acid-functional polyurethane, polyurea, or copolymer thereof, the outer cover having a Shore D hardness of at least about 25, a thickness of from at least about 0.02 inches to about 0.03 inches, and a specific gravity of at least about 0.7.
Type:
Grant
Filed:
July 14, 2003
Date of Patent:
June 7, 2005
Assignee:
Acushnet Company
Inventors:
Shenshen Wu, Shawn Ricci, Murali Rajagopalan, Michael J. Sullivan