Abstract: This invention relates to extruding films made from vinylidene chloride copolymers. Specifically, this invention relates to a method for lowering the oxygen permeability and enhancing the thermal stability and enhancing the melt shear stability of packaging films having a layer of vinylidene chloride copolymer film by adding a processing aid such as an epoxy resin to vinylidene chloride copolymer of low molecular weight. The conventional stabilizer/plasticizer combination of epoxy resin and 2-ethyl-hexyl diphenyl phosphate may be employed with the vinylidene chloride copolymer. The layer of vinylidene chloride copolymer can be as thin as 0.18 mil.
Abstract: A container such as a jerry can can be produced with one or more handles molded with the blow molded body of the container. This invention eliminates the need for separate injection molded inserts. A first pair of molds, and a second pair of molds having a lower and upper section, are used in the apparatus to close a top portion and a bottom and/or draped portions of a standard parison.
Abstract: A film/foil panel comprises a substrate such as a thermoformed film; a first film/foil combination; an insulating material; a second film/foil combination; a top web in sealing relationship to the substrate; the film/foil combinations substantially enclosing therebetween the insulating material; and the insulating material and enclosing film/foil combinations disposed between and enclosed by the substrate and top web.
Abstract: An impact resistant film suitable for medical solution pouches and the packaging of parenteral materials generally includes an interior layer of an ethylene vinyl acetate copolymer and outer layers of a propylene homopolymer or copolymer blended with a styrene ethylene butylene styrene copolymer. In some cases, a flexible copolyester may be substituted for one of the outer blend materials. Sacrificial layers may be optionally included on one or both outer surfaces of the film to improve processing. Additional interior layers of olefin polymers and copolymers such as EVA, and polymeric adhesive layers can also be included. At least one of the EVA or polymeric adhesive layers preferably includes a carbonate of an alkali metal. The flexible copolyester layer preferably includes a high molecular weight stabilizer.
Abstract: A barrier foam tray contains recycled reclaim of barrier foam. The tray comprises a sheet of foamed polystyrene (PS) having laminated to it a flexible barrier film. The foamed polystyrene part can have admixed therein from 0.0001% up to 30% by weight of the flexible barrier film. The barrier film contains a barrier polymer such as ethylene vinyl alcohol copolymer (EVOH). The tray is made by grinding laminate scrap and extruding reclaim therefrom with virgin polystyrene.
Type:
Grant
Filed:
October 1, 1990
Date of Patent:
June 2, 1992
Assignee:
W. R. Grace & Co.-Conn.
Inventors:
Gerald G. Gusavage, Thomas A. Hessen, Thomas R. Hardy, Susan R. Flye, Henry G. Schirmer
Abstract: Laminated sheet material 9 comprises a laminate of a polyvinyl alcohol or other water-disintegratable film 12 with a thin coextruded film comprising a melt-bondable layer 15 and an impermeable layer 14. The laminate is odor impermeable but water disposable and so can be used to form a toilet-disposable ostomy bag by melt-sealing around the edges 10 between the facing melt-sealable surfaces 15.
Abstract: A multilayer laminate comprises a machinable inner component perforated film, preferably of a propylene homopolymer or copolymer, a first outer component film bonded to one side of the inner component film, and a second outer component film bonded to the opposite side of the inner component film, each of the first and second outer component films providing high gas permeability and low moisture transmission and including a bonding layer of ethylene copolymers and an outer heat sealable layer.
Abstract: Striped films of the invention can have two or more preferably polymeric layers, of which at least one continuous or discontinuous layer includes a pigmented resin. The striped film is produced by modifying conventional coextrusion dies to restrict the flow of a pigmented melt stream. The result is a striped film useful for identifying the contents of a package made from the film, tamper evidence, counterfeit protection and verification of properties. The stripes can be of one or more colors, and vary in width and spacing. The pigment can be a material visible in ordinary light, or a material invisible in ordinary light but visible in e.g. ultraviolet light.
Abstract: The packaging of high profile, high abuse products, like bone-in meat cuts and/or fresh/processed fish, often results in vacuum loss, especially when the vacuum skin packaging (VSP) process is used. To reduce this problem a highly formable, highly abuse resistant film is provided wherein at least 25% of the total thickness comprises ionomer.
Abstract: The present invention provides a process for increasing the orientation rate during manufacturing a heat-shrinkable (oriented) polymeric film including: (a) introducing a pro-rad agent to a cross-linkable polymer by blending the cross-linking agent with the cross-linkable polymer, (b) extruding the blended cross-linkable polymer, (c) subjecting the extruded polymer to irradiation, (d) orienting the extruded polymer in at least one direction, and (e) recovering an oriented polymeric film, wherein (f) both the original amount of pro-rad agent and the dosage of irradiation are to an extent sufficient to provide an amount of cross-linking effective to accomplish an increased orientation rate during the orientation step.
Abstract: A masking film suitable for masking during electrostatic spray painting is disclosed. In one embodiment the masking film is made from an acid copolymer/quaternary amine mixture which is permanently antistatic. The acid copolymer is a copolymer of (i) a major amount by mol % of an alpha-olefin of the formula RCH.dbd.CH.sub.2 wherein R is H or C.sub.1 to C.sub.8 alkyl, and (ii) a minor amount by mol % of an alpha,beta-ethylenically unsaturated carboxylic acid. The quaternary amine is of the formula [(R.sup.1)(R.sup.2)(R.sup.3)(R.sup.4)N].sup.+ [X].sup.- wherein R.sup.1 is selected from H, aryl, or C.sub.1 to C.sub.50 alkyl optionally having one or more non-contiguous C.dbd.O or NHC.dbd.O or --S-- or --O-- in the carbon chain, or the same as R.sup.2 ; each of R.sup.2, R.sup.3, and R.sup.4 is the same or different and selected from H, C.sub.1 to C.sub.18 alkyl optionally substituted with one or more OH or from --(R.sup.5 --O).sub.a --H where a is an integer from 1 to 10 and R.sup.
Type:
Grant
Filed:
July 25, 1990
Date of Patent:
March 17, 1992
Assignee:
W. R. Grace & Co.-Conn.
Inventors:
William P. Roberts, Charles R. Morgan, Marvin R. Havens
Abstract: A multilayer laminated film useful in chub packaging comprises a core film comprising a biaxially oriented film, and an outer hot blown film bonded to each of the opposing surfaces of the core layer, at least one of the films including a layer of an oxygen barrier polymeric material.
Abstract: A vacuum chamber has its cover 11 adjustable in height by way of two rams 37 and 38 which lift a chamber cover ceiling 39 relative to a sidewall assembly 35, with the agency of an equalizing cylinder 41 to ensure identical lifting and lowering of the ceiling. During adjustment, an inflatable seal 33 around the periphery of the ceiling 39 is relaxed to allow the sliding movement and then after adjustment the seal 33 is re-inflated to ensure complete sealing between the ceiling 39 and the sidewall assembly 35.
Abstract: Described is the presence of both a chemical cross linking agent and irradiation such as electron beam irradiation, in the manufacturing process for making an oriented, i.e. heat-shrinkable, polymeric film. The presence of both results in an amount of cross-linking that is effective to accomplish an increased orientation rate during manufacturing.
Abstract: In order to reduce splitting in a perforated, heat shrinkable, thermoplastic bags made from seamless tubing, rather than employ needle punched perforations, it has been discovered that slits cut by a knife blade will surprisingly reduce the splitting when a product, such as a meat product, is cooked within the bag.
Abstract: Discoloration of meat products due to oxygen starvation in stacked packages is significantly reduced by applying a textured surface to the bottom of the packages. A discrete textured film may be adhered to a tray or supporting member, or the tray or supporting member may itself be textured at its bottom surface.
Abstract: A micro-bubble laminate is made by drawing a heated thermoplastic film through the perforations of a perforated substrate laminated to the film. The bubbles may then be trapped by laminating an additional thermoplastic layer to the laminate construction. This laminate may be used in producing air cushioning or bubble laminates, and the inventive process avoids the intricate and expensive machinery typically used in the production of air cushioning materials.
Abstract: Disclosed is an oriented, heat-shrinkable, packaging film having a layer of polyamide or polyester. The film has a high shrink energy and high modulus.
Type:
Grant
Filed:
December 8, 1989
Date of Patent:
January 7, 1992
Assignee:
W. R. Grace & Co.-Conn.
Inventors:
Steven B. Garland, Donald J. d'Entremont
Abstract: In a vacuum skin package wrinkles and weak spots are avoided by providing a tray as the support or backing member rather than a flat sheet, the angle of the walls as they diverge outwardly being 91.degree. to 160.degree.. Especially useful is such a package when provided with a lid for stacking purposes.
Abstract: A multi-layer film useful in vacuum skin packaging and other vacuum packaging applications, and having a combination of good implosion resistance, formability and high oxygen barrier characteristics, includes a core layer having an oxygen barrier material, intermediate layers of EVA or other ethylene homopolymer or copolymers, polymeric adhesive layers which bond the intermediate layers to respective surfaces of the core layer, a first outer heat-sealable layer, a second outer heat resistant layer, and two moisture resistant layers disposed between respective outer and intermediate layers.