Abstract: A method for improving the processability of foam premixes containing HFC and/or pentane-based blowing agents in polyols is provided, which method comprises adding trans-1,2-dichloroethylene to said premix in an amount effective to enhance said processability.

Abstract: Safety stabilized solid, free-flowing compositions based on t-butyl peroxy maleic acid as well as processes for their preparation and use are disclosed.

Abstract: A crosslinkable composition of a polymeric thermoplastic and/or elastomeric material which is susceptible to scorching when processed at elevated temperatures, prior to crosslinking, in the presence of a free radical initiator, is protected against such scorching by the incorporation therein of a mixture of at least one hydroquinone compound and a sulfur accelerator. This mixture may also contain at least one monomeric allylic, methacrylic, acrylic or diene type coagent. The mixture exhibits a synergistic effect resulting in improved scorch protection for peroxide cured systems when compared with the protection afforded by the components singly.

Abstract: Processes for the controlled radical polymerization of acrylic and related polymers to produce improved low VOC coating materials, or powder coating compositions, the novel polymers so produced, the catalyst systems employed, processes for application of the improved coatings, coatings so produced and objects coated on at least one surface with the novel coatings are disclosed.

Abstract: An improved process for priming a metal surface to improve the adhesion to the surface of a resin coating possessing functional groups that react with epoxide groups, such as amide functionality containing polyamide resins.

Abstract: Compositions are disclosed which comprise mixtures of at least one compound selected from silicone elastomers, bis-, tri- or higher polymaleimides and/or bis-, tri- or higher polycitraconimides, and at least one compound selected from p-phenylene-diamine based antiozonants, sulfur compounds capable of accelerating sulfur vulcanization of polymers capable of being crosslinked by sulfur and polysulfide polymers which when compounded into polymers curable by free radical initiators in the presence of free radical initiators permit substantially tack free surface cure of the polymers by decomposition of the free radical initiator in the presence of molecular oxygen. Compositions containing the above ingredients and at least one free radical initiator, curable compositions containing the combination and processes for making and using the compositions are also disclosed.

Abstract: New and novel copolymers of vinylidene fluoride and hexafluoropropylene containing up to 24% by weight hexafluoropropylene having lower DSC melting temperatures at 8 weight percent or greater nominal HFP content, and having improved solution clarity and fluidity, longer gel times and lower extractables than prior art vinylidene fluoride-hexafluoropropylene copolymers of comparable HFP content whose syntheses are disclosed in sufficient detail to duplicate, to novel compositions of matter and articles of manufacture containing such copolymers, processes for the preparation and use of the copolymers, of the compositions of matter containing such copolymers and of the articles of manufacture containing such copolymers are disclosed. Improved electrochemical cells based on the new and novel copolymers are particularly disclosed.

Abstract: Multi-phase blends of VDF-based polymers are provided which are useful in a variety of applications such as wire and cable, pipe and liner applications, and rotational molding.

Abstract: Vinylidene fluoride polymers are produced by using a C3-C5 hydrocarbon as a chain transfer agent in the free radical polymerization process.

Abstract: Acrylic Modified Fluoropolymers based on vinylidene fluoride polymers are disclosed wherein the acrylic phase is capable of entering into crosslinking reactions. The final cured products provide superior solvent extractability resistance to the fluoropolymer phase.

Abstract: Vinylidene fluoride polymers are produced by using ethane as a chain transfer agent in the emulsion polymerization process. Vinylidene fluoride homopolymers made by the process have a significantly reduced tendency to generate cavities at high temperatures and a greater resistance to discoloration at high temperatures.

Abstract: Weatherable fluoropolymer-acrylic compositions based on the use of C3 and higher straight chain (meth)acrylate esters are provided.

Abstract: Enhanced conversion rates are realized in a suspension polymerization process for styrene through the use of peroxide initiators having one hour half life temperatures from 101° to 111° C. are disclosed. Also disclosed are suitable initiator combinations which provide polymeric products with low residual monomer content at reduced process temperatures, polymerizable compositions containing such initiators and products produced by such processes and compositions.

Abstract: A method for isolating 32 from a crude mixture containing HCl and an azeotropic mixture of 32 and HF is provided without the need to isolate any HF azeotrope.

Abstract: Molecular weight modification of polypropylene by 4-(t-amylperoxy)-4-methyl-2-pentanol and polypropylene so modified suitable for handling and packaging food, beverages and pharmaceuticals and for use in medical devices is disclosed.

Abstract: A conduit for transporting non-volatile liquids is provided in which the conduit's internal surfaces have a surface energy lower than that of the nonvolatile liquid.

Abstract: New and novel copolymers of vinylidene fluoride and hexafluoropropylene having lower or no crystallinity together with processes for their manufacture and use are disclosed.

Abstract: Sulfur free, crosslinking, scorch-retarding compositions for compounding and cure of polymers susceptible to cure by free radical initiators are disclosed.

Abstract: A gas phase process for the preparation of 245fa is provided, wherein 1233zd is contacted with HF in the presence of a supported antimony catalyst.

Abstract: Polymer foams containing nanoclay are provided, the foams having improved properties such as thermal insulation values.