Abstract: A new catalyst for converting hydrocarbons, especially for reforming hydrocarbons, is disclosed. Also disclosed is a hydrocarbon conversion process using the catalyst as well as a method for making the catalyst. The catalyst comprises a platinum group component, a tin component, an indium component and a halogen component with a porous support material, wherein there is about 0.6 or more wt. %, on an elemental basis, indium present. In a preferred embodiment of the invention the catalyst is utilized in the catalytic reforming of hydrocarbons boiling in the gasoline range to produce a high octane reformate suitable for gasoline blending or a high aromatics content reformate suitable for use as a petrochemical feedstock.

Abstract: Prepacked well screen and casing assembly for use in wells provides very substantial savings in the expense and time required to complete a well as compared to the conventional techniques of down-hole perforating and gravel packing. The assembly includes an external casing or liner member which would be provided with a large number of perforations during manufacture. A pipe base screen jacket assembly is positioned concentrically within the casing and attached to it by readily machinable upper and lower annular ring members. The hollow cylindrical annulus between the screen and casing is filled with a resin-coated gravel pack material which is cured after the fill operation to maintain its integrity. The assembly can be hung in the uncased producing zone of a new well by a liner hanger or could be placed in an existing cased well which is to be reworked by first milling away the existing casing in the production zone.

Abstract: Zerovalent Group VIII metals dispersed on titanium dioxide reduced and calcined at a temperature less than about 300.degree. C. are hydrothermally stable hydrogenation catalysts which may be used advantageously in the reduction of aqueous solutions of carbohydrates. The use of ruthenium on titanium dioxide in the hydrogenation of glucose affords sorbitol in excellent yields with quite high selectivity.

Abstract: A process for producing liquid elemental sulfur from a CO.sub.2 -rich gaseous stream containing H.sub.2 S. The gas is contacted with at least a stoichiometric amount of gaseous oxygen in the presence of liquid water with a fixed bed comprising a catalyst selected from the group consisting of a transition metal phthalocyanine compound dispersed on a support at a specific pH and temperature. A preferred support is activated carbon.

Abstract: Alkylaromatic compounds may be synthesized by reacting an aromatic compound with a mixture of carbon monoxide and hydrogen at alkylation conditions in the presence of a dual-function catalyst. The catalyst system will comprise (1) a composite of oxides of copper, zinc and aluminum or chromium, and (2) an alumino-silicate which may be either in crystalline or amorphous form.

Abstract: A new catalyst composition comprising a platinum group component, a tin component, an indium component, an alkali or alkaline earth component and a porous support material wherein the atomic ratio of indium to platinum group component is more than 1.0 is disclosed. The catalyst is particularly useful for dehydrogenating hydrocarbons. In one embodiment of the invention, detergent range normal paraffins (C.sub.10 -C.sub.15 or higher) are dehydrogenated to the corresponding normal olefins in the presence of the subject catalyst and hydrogen.

Abstract: An adsorbent suitable for use in separating sucrose from a solution with potassium chloride and betaine. The adsorbent comprises activated carbon bound with a binder material consisting essentially of a water permeable organic polymer from the group cellulose nitrate, a cellulose ester and/or a mixture thereof. Another aspect of the invention is a method of manufacturing the adsorbent comprising (a) mixing together a powder of activated carbon, a powder of binder and a liquid organic solvent to form a malleable mixture; (b) forming the malleable mixture into discrete formations; (c) removing the solvent from the formations to obtain hard dry formations; and (d) breaking the hard dry formations into particles of desired sizes.

Abstract: A process for separating a normal C.sub.6 olefin hydrocarbon from a mixture of the same with a C.sub.6 olefin branched chain and/or cyclic hydrocarbon. The process comprises contacting the mixture at separation conditions with a molecular sieve comprising a crystalline silica. The normal C.sub.6 olefin hydrocarbon is selectively retained and will be recovered from the molecular sieve by displacement with a displacement material comprising pentene-1 or butene-1. The process preferably employs a simulated moving bed.

Abstract: A process for the conversion of a hydrocarbon charge stock is disclosed which process comprises reacting the charge stock with hydrogen at hydrocracking conditions in contact with a catalytic composite having improved selectivity to middle distillate product during hydrocracking which comprises alumina, a crystalline aluminosilicate, a Group VIB metal component and a Group VIII metal component and which catalytic composite is prepared by the method comprising admixing the alumina and crystalline aluminosilicate with a peptizing agent and an aqueous solution of a modified linear aliphatic polyether surfactant to form a dough; extruding the dough into discrete particles; and calcining and drying the particles.

Abstract: Conductive thick film pigment-coated surfaces which possess desirable conductivity and solderability characteristics are formed from an alloy comprising a mixture of a nonnoble conductive metal, a noble metal and at least one oxidizable material. The oxidizable material is present in the alloy in an amount in the range of from about 5% to about 25% by weight, the nonnoble metal in an amount in the range of from about 94% to about 60% by weight and the noble metal in an amount in the range of from about 1% to about 15% by weight of the alloy. The desired product is prepared by admixing a nonnoble metal, an oxidizable material and a noble metal, arc-melting the mixture to form an alloy, grinding the arc-melted alloy to a powdered form, admixing the powder with the carrier binder, depositing said admixture on an inert surface, firing the admixture and surface in an oxygen-containing atmosphere at a temperature in the range of from about 500.degree. to about 950.degree. C.

Abstract: A process for the recovery of glucose from an aqueous mixture of glucose and polysaccharides. The mixture is contacted with an X zeolite containing potassium cations at exchangeable cationic sites and selectively adsorbing glucose in the zeolite. The polysaccharides are removed from the zeolite and the adsorbed glucose recovered by means of a desorbent liquid. Preferred systems for effecting the process are countercurrent and co-current simulating moving beds.

Abstract: An apparatus for the cooling of hot fluidized solid particles.

Abstract: A process is disclosed for treating carbon dioxide-containing gas streams, such as a natural gas, to selectively remove hydrogen sulfide. The process employs an absorption-stripping sequence in which hydrogen sulfide and carbon dioxide are removed from the feed gas. The net overhead vapor of the stripping column is compressed and dried and passed into a fractionation column. Relatively high purity hydrogen sulfide is withdrawn from the bottom of the fractionation column, and the net overhead vapor of the fractionation column is recycled back to the absorption zone.

Abstract: A new catalyst composition for converting hydrocarbons is disclosed. Also disclosed is a method for making the catalyst. The catalyst comprises a platinum group component and a phosphorous component with a porous support material. The catalyst is made by compositing a platinum group component with a porous support material and then contacting that composite with phosphorus or a compound of phosphorus. In a preferred embodiment of the invention a catalyst comprising platinum, phosphorus and chlorine with alumina is utilized in the catalytic reforming of hydrocarbons boiling in the gasoline range to produce a high octane reformate suitable for gasoline blending or a high aromatics content reformate suitable as a petrochemical feedstock.

Abstract: An improved catalytic reforming process is disclosed wherein hydrogen and light hydrocarbons generated in the catalytic reaction zone are passed to a hydrogen production/purification zone and are reacted and processed therein to produce substantially pure hydrogen. A portion of the hydrogen is then admixed with the charge stock to the catalytic reforming zone to provide the hydrogen requirements of the catalytic reforming reaction zone.

Abstract: Gas conversion catalysts which possess a high resistance to catalyst poisoning such as sulfur and/or chlorine-containing compounds, comprise a catalyst composite of copper, zinc and aluminum compounds containing at least one metal selected from the metals consisting of groups IVB, VB, VIB and VIIB of the Periodic Table. This catalyst composition may be used to synthesize methanol from a feedstock of carbon monoxide and hydrogen.

Abstract: A process is disclosed for the production of isopropanol and tertiary butyl alcohol from C.sub.3 and C.sub.4 hydrocarbons. The preferred embodiment of the invention comprises dehydrogenation of paraffins and direct hydration of the resulting olefins. Fractional distillation steps are employed between the dehydrogenation and dehydration zones and in the recycle stream to recover unconverted hydrocarbons leaving the hydration zone. This accommodates different hydration rates and prevents the passage of propylene into the dehydrogenation zone. In an alternative embodiment, the feed stream comprises olefins and is fed to the fractionation system. The dehydrogenation zone may be deleted from this embodiment.

Abstract: A hydrocarbon conversion process is disclosed for the production of lower alcohols and LPG from a mixture of C.sub.3 -minus paraffins and olefins. The feed stream is passed into a hydration zone wherein portions of the ethylene and propylene are converted to ethanol and propanol. The hydrocarbons which are not hydrated are passed into a hydrogenation zone wherein the remaining olefins are converted to paraffins. The feed stream is preferably a hydrogen-containing C.sub.1 to C.sub.3 cut separated from the effluent of a fluidized catalytic cracking unit.

Abstract: A process and related apparatus for separating particulate solids from a stream comprising vapors and particulate solids passed in admixture through an elongated contacting zone. The stream is discharged downwardly at an angle to the vertical along the inside wall of a cylindrical disengagement zone and at an angle to the horizontal of greater than 0.degree. and less than 45.degree.. The solids separate due to centripetal acceleration and fall to the bottom of the disengagement zone.

Abstract: Xylylenediamines may be prepared by reducing the corresponding phthalonitrile with hydrogen in the presence of a catalyst comprising cobalt promoted with titanium composited on a solid support with the added presence of ammonia. By utilizing this particular catalyst with ammonia and a solvent comprising a xylylenediamine, it is possible to effect the reduction at temperatures in the range of from about 80.degree. to about 125.degree. C. and at a pressure not greater than 1000 psig. By utilizing various components of the system it is possible to attain yields of the desired product in excess of 90%.