Abstract: A method is provided for preparing [.sup.18 F]2-fluoro-2-deoxyglucose with an anion exchange resin by effecting an exchange reaction between an aqueous solution of [.sup.18 F]fluoride containing an alkali metal carbonate or bicarbonate, such as sodium bicarbonate, and an anion, such as bicarbonate or carbonate, on the anion exchange resin followed by the displacement reaction with 1,3,4,6-tetra-O-acetyl-2-O-trifluoromethanesulfonyl-.beta.-D-mannopyranose to form the resulting 2-fluoro-2-deoxyglucose tetraacetate. Improved yields of the [.sup.18 F]2-fluoro-2-deoxyglucose are obtained when the alkali bicarbonate or carbonate is used in the target water.
Type:
Grant
Filed:
July 18, 1994
Date of Patent:
July 25, 1995
Assignee:
General Electric Company
Inventors:
Bruce F. Johnson, Maxim Y. Kiselev, Johan Ulin
Abstract: Process for isolating macrocyclic polyester oligomers from impurities comprising the step of subjecting solutions of macrocyclic polyester oligomers to protonated molecular sieves.
Type:
Grant
Filed:
December 9, 1994
Date of Patent:
July 18, 1995
Assignee:
General Electric Company
Inventors:
Gregory L. Warner, Paul R. Wilson, Jean E. Bradt
Abstract: The electrical field at the surface of an electrode is graded by depositing a semiconductive coating thereon. An electrode substrate is powered at a preselected temperature and power. A mixture of gases is then passed through an electrical discharge to ionize at least a portion thereof to form the semiconductive coating on the surface of the electrode. A diamondlike carbon (DLC) film is deposited by plasma enhanced chemical vapor deposition onto a substrate. A substrate is maintained at a preselected DLC forming temperature and is negatively biased at a first preselected voltage. A first gaseous mixture of hydrocarbons and argon is then passed through an electrical discharge to at least partially ionize the hydrocarbons to form DLC film on the substrate. The substrate is then negatively biased at a second preselected voltage lower than the first preselected voltage.
Abstract: Heat curable organopolysiloxane compositions are provided utilizing a vinyl silicone organopolysiloxane fluid, a silicon hydride siloxane and an effective amount of a preformed latent platinum catalyst resulting from the reaction in the substantial absence of organopolysiloxane fluid, between a zero valent platinum catalyst and an organic nitrogen compound, such as 2,2'-bipyridine or diethyl azodicarboxylate.
Type:
Grant
Filed:
November 19, 1993
Date of Patent:
July 11, 1995
Assignee:
General Electric Company
Inventors:
Chris A. Sumpter, Larry N. Lewis, William B. Lawrence
Abstract: A method is provided for recovering phenol values from bisphenol A tar by treating the bisphenol A tar with an alkyl phenol, such as cresol in the presence of an acid catalyst. In addition to recovering phenol, there is obtained a variety of dialkyl 9,9-dimethylxanthenes which can be converted to dicarboxylic acids and their corresponding diesters which are useful polymer intermediates.
Abstract: A method is provided for regenerating deactivated sulfonated aromatic organic ion-exchange resin beds, such as a polystyrene ion-exchange resin bed, having chemically combined amino organo mercaptan groups with anhydrous phenol at an elevated temperature.
Abstract: Diamond is produced by chemical vapor deposition on a substrate by hot filament activation of a hydrogen-hydrocarbon gas mixture. An edge of the substrate faces the filament at a distance; therefrom up to about 1 mm. and preferably about 0.3-0.7 mm., and the substrate is moved relative to the filament to maintain this spacing as diamond forms thereon. Diamond formation proceeds at an improved rate, and in single crystal configuration under certain conditions.
Type:
Grant
Filed:
June 13, 1994
Date of Patent:
June 13, 1995
Assignee:
General Electric Company
Inventors:
Thomas R. Anthony, James F. Fleischer, Robert H. Ettinger
Abstract: Graphite formation on a diamond surface during laser etching is inhibited or the graphite is removed by contact with a gaseous material such as elemental hydrogen, elemental oxygen, an inert gas or a source of hydroxyl radicals. Preferably, the article being etched is cooled and maintained in an inert atmosphere during etching.
Abstract: A novel apparatus for isolating solids or wetcakes from fluids is disclosed. Said apparatus is closed to the atmosphere and comprises a slip joint and a floating auger which allows for solid recovery under pressure in the absence of substantial solvent volatilization.
Type:
Grant
Filed:
December 29, 1993
Date of Patent:
May 23, 1995
Assignee:
General Electric Company
Inventors:
James Day, Ganesh Kailasam, Godavarthi S. Varadarajan, Kenneth M. Carroll
Abstract: Addition-curable platinum group metal catalyzed silicone compositions are provided which utilize a bis[trialkyloxysilylalkylene]amine or urea adhesion promoter. Cohesive bonding can be effected on both plastic and metal substrates at temperatures of 100.degree. C. or below in less than 1 hour.
Abstract: Novel thermally stable resins comprising halogens and not epoxide termination groups are described. The thermally stable resins may be employed in polymer systems to yield flame retardant polymer compositions.
Abstract: Room temperature vulcanizable platinum group metal catalyzed silicone compositions are provided which utilize an N-heterocyclic adhesion promoter, such as 2,6 bis(trimethoxysilyltrimethyleneoxy)pyridine. Cohesive bonding is effected on various substrates.
Abstract: Substrates comprising blends of at least one polyphenylene ether and at least one poly(alkenylaromatic compound) (e.g., polystyrene) are treated with aqueous tetravalent cerium in a concentration of at least about 0.1 M, preferably acidified with nitric acid, to improve adhesion to metal coatings subsequently deposited nonelectrolytically; for example, by electroless deposition. The metallized articles are heat treated following metal deposition. Further metal coatings may be deposited, preferably followed by further heat treatment.
Abstract: Bisphosphine oxide monomers and homologs thereof may be incorporated into polycarbonates in order to obtain a flame retardant polymer. More particularly, bis[2,5-(diphenylphosphine oxide)]-1,4-hydroquinone and homologs thereof may be used to prepare flame retardant polycarbonates that retain high glass transition temperature and high impact resistances.
Abstract: Low thermal conductivity insulation for refrigerators and the like is produced by blowing a resinous foam in an inert (e.g., nitrogen) atmosphere with a mixture of carbon dioxide and a low thermal conductivity inert gas such as krypton or xenon. The foam is then sealed in a gas-impervious enclosure and carbon dioxide is removed therefrom, typically by inclusion in said enclosure of a solid material reacted therewith such as an alkaline reagent. The final partial pressure of the low thermal conductivity gas in the enclosure is in the range of about 20-200 torr, and the total pressure is up to 110% of said partial pressure.
Abstract: A method is provided for effecting the removal of cured polyurethane paint from the surface of aromatic polycarbonate blend surfaces. Effective removal of thermally cured polyurethane paint from aromatic polycarbonate blend surface can be achieved by immersing the painted aromatic polycarbonate blend in an aqueous bath containing organic solvent, an alkali metal hydroxide and a surfactant.
Abstract: A process for the redistribution of an organic polycarbonate composition. The process involves melt equilibrating a starting polycarbonate composition (which may be a single polycarbonate or a mixture of polycarbonates, and may be or include recycled polycarbonate) having an initial weight average molecular weight in the presence of a carbonate redistribution catalyst and in the absence of branching agents, under conditions such that a redistributed polycarbonate composition is formed having a weight average molecular weight different from, and typically lower than, the initial weight.
Type:
Grant
Filed:
December 1, 1993
Date of Patent:
May 9, 1995
Assignee:
General Electric Company
Inventors:
Allen J. Campbell, David M. Dardaris, Gary R. Faler, Patrick J. McCloskey, Thomas L. Evans
Abstract: A method is provided for making bisphenol by condensing a ketone and a phenol in the presence of a sulfonated aromatic organic polymeric ion-exchange catalyst having aminoorganomercaptan groups using a phenol having less than 1 ppm of hydroxyacetone.
Abstract: The present invention is directed to a method of making polycarbonates by the melt condensation of diarylcarbonate and dihydric phenol in the presence of a tetraorganophosphonium carboxylate salt, such as tetrabutylphosphonium acetate.
Type:
Grant
Filed:
March 7, 1994
Date of Patent:
May 2, 1995
Assignee:
General Electric Company
Inventors:
Joseph A. King, Jr., Patrick J. McCloskey
Abstract: Heat curable primerless silicone compositions are provided comprising an aqueous/organic solvent silicone dispersion in combination with an adhesion promoter, such as acrylate or methacrylate ester, for example, a caprolactone acrylate or methacrylate adhesion promoter. Composites of a thermoplastic substrate, such as a polycarbonate, and the thermally cured primerless silicone compositions are also provided.