Patents Represented by Attorney William J. Spatz
  • Patent number: 7445758
    Abstract: An apparatus for performing continuous flow chemical reactions such as oxidation, oxidative dehydrogenation and partial oxidation processes involving a reactor design characterized by controlled/optimized addition of a reactant with the objective of: (i) avoiding the explosion regime of the reactant mixture (e.g., hydrocarbon/oxidant mixture); (ii) maximizing the selectivity of the reaction to the desired product; (iii) limiting the reactor temperature gradient and therefore the threat of reaction runaway; and (iv) controlling the operating temperature of the reaction zone so that desirable temperature range is maintained over the entire zone.
    Type: Grant
    Filed: September 8, 2005
    Date of Patent: November 4, 2008
    Assignee: Saudi Basic Industries Corporation
    Inventors: Alaa Eldin M. Adris, Fahad A. Al-Sherehy, Mustafa A. Soliman, Tarique Hakeem, Shickh Kareemuddin, Abdullah A. Al-Nutaifi, Munawwar Saudagar, Shahid M. Azam
  • Patent number: 7420095
    Abstract: Process for reduction of bromine index in aromatics, comprising the steps of feeding an aromatics feed stream which contains olefin impurities to a distillation column; withdrawing an overhead stream from the distillation column; subjecting at least a portion of the overhead stream to a treatment for the alkylation or polymerization of olefin in a clay treater to provide a purified overhead stream which is then injected to the aromatics feed stream.
    Type: Grant
    Filed: December 19, 2002
    Date of Patent: September 2, 2008
    Assignee: Saudi Basic Industries Corporation
    Inventor: Mohammed Sabri Abdelghani
  • Patent number: 7268268
    Abstract: A process for the dimerization of at least one olefin with a carbon number between 2 and 10 by contacting the feed with a catalyst system comprising at least: (a) tectometallosilicate zeolite with having TON-type structure, (b) tectometallosilicate zeolite with having MTT-type structure, (c) tectometallosilicate zeolite with the same structure as that of the ZSM-48 zeolite, or (d) silicoaluminophosphate (SAPO) zeo-type with AEL-type structure; under dimerization condition to produce highly branched olefins.
    Type: Grant
    Filed: April 19, 2001
    Date of Patent: September 11, 2007
    Assignee: Saudi Basic Industries Corporation
    Inventors: Farouk al-Soufi, Sami A. I. Barri, Yajnavalkya Subrai Bhat, Altaf Husain
  • Patent number: 7256319
    Abstract: The present invention provides a catalyst composition for the production of olefins by oxidative dehydrogenation of hydrocarbons, and of using such catalyst compositions. The catalysts of the present invention include compositions of the formula: XxYyWOz wherein X is at least one element selected from the group consisting of Li, Na, K, Rb, Cs, and Fr; Y is at least one element selected from the group consisting of B, Al, Ga, In, Ti, C, Si, Ge, Sn, and Pb; x is 0.5-2.5; y is 0.05-5; and z is the number of oxygen atoms required to satisfy the valancy of X, Y, and W in said composition. The methods and catalysts of the present invention are specifically useful for the combined production of propene and isobutene at relatively high conversion, selectivity, and productivity, and with minimal side products.
    Type: Grant
    Filed: March 7, 2003
    Date of Patent: August 14, 2007
    Assignee: Saudi Basic Industries Corporation
    Inventors: Saeed M. Al-Zahrani, Ahmad E. Abasaeed, Nimir O. Elbashir, Mazhar A. Abdulwahed
  • Patent number: 6160162
    Abstract: A mixed metal oxide Mo--V--Ga--Pd--Nb--X (where X=La, Te, Ge, Zn, Si, In or W) catalytic system providing a higher selectivity to acrylic acid in the low temperature partial oxidation of propane with a molecular oxygen-containing gas.
    Type: Grant
    Filed: October 21, 1999
    Date of Patent: December 12, 2000
    Assignee: Saudi Basic Industries Corporation
    Inventors: Khalid Karim, Yajnavalkya Subrai Bhat, Syed Irshad Zaheer, Abdullah Bin Nafisah
  • Patent number: 6156928
    Abstract: A mixed metal oxide catalytic system consisting of molybdenum, vanadium, lanthanum and palladium providing higher yields of acetic acid in low temperature single stage oxidation of ethane with molecular oxygen-containing gas without or with reduced production of by-products such as ethylene and CO.
    Type: Grant
    Filed: February 8, 2000
    Date of Patent: December 5, 2000
    Assignee: Saudi Basic Industries Corporation
    Inventors: Khalid Karim, M. H. Al-Hazmi, Asad Khan
  • Patent number: 6143928
    Abstract: A mixed metal oxide catalytic system consisting of molybdenum, vanadium, palladium, lanthanum, niobium and X, wherein X is copper and/or chromium, providing higher yields of acrylic acid and acrolein in the low temperature oxidation of propylene with a molecular oxygen-containing gas without the production of side products such as CO.
    Type: Grant
    Filed: August 10, 1998
    Date of Patent: November 7, 2000
    Assignee: Saudi Basic Industries Corporation
    Inventors: Khalid Karim, Yajnavalkya Subrai Bhat, Syed Irshad Zaheer, Abdullah Bin Nafisa
  • Patent number: 6143921
    Abstract: Methods for the catalytic production of vinyl acetate monomer from ethane, ethylene or an ethane/ethylene mixture using a first catalyst containing MoVNbPd, MoVLaPdNbX (where X is Al, Ga, Ge or Si) or MoVNbX (where X is P, B, Hf, Te, As or mixtures thereof) in the first step of oxidation and using a conventional VAM catalyst for the second step. The method produces high yields to acetic acid and vinyl acetate without the coproduction of carbon monoxide.
    Type: Grant
    Filed: May 14, 1999
    Date of Patent: November 7, 2000
    Assignee: Saudi Basic Industries Corporation
    Inventors: Khalid Karim, Alaa E. M. Adris
  • Patent number: 6124412
    Abstract: The present invention relates to a new olefin polymerization catalyst composition, and methods of preparing and methods of using the catalysts to polymerize various olefinic monomers in either gas or slurry phase reactions. The principal advance over the previous art of record involves using alumoxanes or combinations of alumoxanes as catalyst preactivators. Polymers prepared from these catalysts posses productivity increased as high as 40 percent. At the same time, the bulk density remains relatively constant. Additionally, the total amount of cocatalyst species needed to effectively practice the invention is relatively low.
    Type: Grant
    Filed: December 29, 1997
    Date of Patent: September 26, 2000
    Assignee: Saudi Basic Industries Corporation
    Inventors: Abdulmalik Bin-Taleb, Raju Raghavan, Abdulwhab Al-Sadoon
  • Patent number: 5858172
    Abstract: Wood pulp sheets treated with triacetin and other compounds, or solutions or emulsions of same, having increased softness while maintaining absorbency, and methods for producing same. More particularly, the invention relates to the treatment of wood pulp useful for making a fluff pulp using a softening agent including alkyl ethers, aryl ethers and formic, ethanoic and propanoic esters of low molecular weight glycols, such as triacetin, propylene glycol diacetate and 2-phenoxyethanol.
    Type: Grant
    Filed: September 15, 1997
    Date of Patent: January 12, 1999
    Assignee: Rayonier Inc.
    Inventors: Karl D. Sears, Peter R. Abitz
  • Patent number: 5841012
    Abstract: High space velocity catalysts useful in the substantial elimination of chloroprene and trichloroethylene from an industrial product stream of ethane dichloride; the last is useful in the production of vinyl chloride.
    Type: Grant
    Filed: January 2, 1997
    Date of Patent: November 24, 1998
    Assignee: Saudi Basic Industries Corporation
    Inventors: Hicham Idriss, Adbulrahman Saleh Al-Ubaid, Saeed Mohammed Al-Wahabi, Khalid El Yahyaoui
  • Patent number: 5557031
    Abstract: Improved concrete or mortar materials wherein cement in the precursors for these is replaced by electric arc furnace dust in amounts from 0+% to 4% or more based on the amount of cement by weight. In addition, the electric arc furnace dust can be used as an additive to obtain the same effect.
    Type: Grant
    Filed: October 6, 1994
    Date of Patent: September 17, 1996
    Inventors: Faisal H. Al-Sugair, Abdulaziz I. Al-Negheimish, Rajeh Z. Al-Zaid
  • Patent number: 5512176
    Abstract: Polyurethane polymers useful as hydrogels wherein the polyol is a specific polyol of block copolymers and a method for desalination of water.
    Type: Grant
    Filed: June 21, 1994
    Date of Patent: April 30, 1996
    Assignee: Saudi Basic Industries Corporation
    Inventor: E. Allan Blair
  • Patent number: 5402605
    Abstract: An assembly for converting a conventional drill press into an oscillating spindle sander is disclosed. The oscillating spindle sander assembly is comprised of an auxiliary motor which is adapted to be mounted on a drill press. An eccentric drive is attached to the rotating shaft of the auxiliary motor and is used to drive a push rod in a lateral reciprocating motion. The opposite end of the push rod is attached to one of the spindle spokes of the drill press, and causes it to move in a radially reciprocating motion which induces the drill press spindle, drill chuck and a sanding tool mounted therein, to move up and down in an oscillating motion. The oscillating spindle sander assembly of the invention can be easily disabled and the converted drill press returned to normal operation by removing the push rod from the spindle spoke of the drill press.
    Type: Grant
    Filed: April 12, 1993
    Date of Patent: April 4, 1995
    Inventor: Eugene Paules
  • Patent number: 5402991
    Abstract: A tube connector utilized in connecting a drip tube to a header pipe in a heap leach mining percolation system which provides for strength at the normally weak connection between the header pipe and the drip tube. The tube connector includes a housing providing a fluid passageway extending therethrough between a header pipe and a drip tube. A nipple section is formed at one end of the housing for accommodating the drip tube therearound which is of a relatively short length, and hence, a relatively short bending movement, to significantly reduce breakage of the connector during transportation.
    Type: Grant
    Filed: August 10, 1994
    Date of Patent: April 4, 1995
    Assignees: Newmont Mining Corporation, Newmont Gold Company
    Inventor: Allen J. Schindler
  • Patent number: 5368890
    Abstract: A method for depositing continuous cohesive, non-granular tightly adhering deposits on a substrat by using a rotating fibrous transfer means; deposit starting material is a small particle materials such as diamond powder; or powders of complex materials such as superconducting materials such as of the Y--B--C--O type; discrete deposits may be made and thereafter built-up on the substrate.
    Type: Grant
    Filed: April 23, 1993
    Date of Patent: November 29, 1994
    Inventor: Erno N. de Nagybaczon
  • Patent number: 5366592
    Abstract: A sampling device for a batch or continuous pulp digester for reduction of pulp sampling errors such as during a digester "blow" and for improving a pulping process based on the obtained samples.
    Type: Grant
    Filed: October 9, 1992
    Date of Patent: November 22, 1994
    Assignee: ITT Rayonier Inc.
    Inventor: Jerry C. Ford
  • Patent number: 5355820
    Abstract: A method for thread laying and a thread laying machine; thread laying has been achieved by a machine that has a vacuum table and above it a gantry with a thread dispensing device on a shuttle operating in an x- and y- direction; the gantry may be fixed to a pair of carriage on the x-axis driven in unison or each of the carriages may be independently driven; curved threads as well as threads on a mold may be laid down on a substrate; typical material produced is sail material of considerable thread pattern complexity; single threads or a multiple of threads may be laid down through one thread head with an adhesive properly coating the threads; multiple thread heads as well associated apparatus such as laser cutters and the like are mounted on the gantry.
    Type: Grant
    Filed: July 27, 1992
    Date of Patent: October 18, 1994
    Assignee: Sobstad Corporation
    Inventors: Peter G. Conrad, John D. Sullivant
  • Patent number: 5354835
    Abstract: Polyurethane polymers useful as hydrogels wherein the polyol is a specific polyol of block copolymers and a method for desalination of water.
    Type: Grant
    Filed: July 23, 1993
    Date of Patent: October 11, 1994
    Assignee: Saudi Basic Industries Corporation
    Inventor: E. Allan Blair
  • Patent number: 5353708
    Abstract: The invention relates to a method of production of ultradispersed diamond which can be used for the production of abrasive materials, more particularly, this method relates to production of fine diamond powder by explosive means.
    Type: Grant
    Filed: November 8, 1991
    Date of Patent: October 11, 1994
    Inventors: Starvri Y. Stavrev, Slavcho B. Lazarov, Khristo L. Stoev, Lyudmil G. Markov, Valeri I. Ivanov