Abstract: A method for recovering isobutyric acid from a solution thereof in concentrated aqueous hydrogen fluoride, the latter having served as the reaction medium for effecting the carbonylation of propylene. The method features the partial removal of anhydrous hydrogen fluoride from said solution to provide an aqueous phase of reduced hydrogen fluoride content from whence the isobutyric acid is extracted with optimum efficiency with an immiscible organic solvent.
Type:
Grant
Filed:
February 4, 1980
Date of Patent:
June 2, 1981
Assignee:
Ashland Oil, Inc.
Inventors:
Bhupendra C. Trivedi, Dace Grote, Thomas O. Mason
Abstract: A copper chromite catalyst having improved activity is prepared by forming a basic copper ammonium chromate complex in a known manner. The complex is decomposed by sintering at temperatures near 300.degree. C. to yield a copper chromite catalyst of improved activity. The copper chromite catalyst is especially useful in liquid phase production of furfuryl alcohol from furfural by hydrogenation. The hydrogenation reaction takes place at low pressure, e.g. under 30 atmospheres, due to the increased activity of the catalyst.
Abstract: A fiberglass bag filtering unit adapted for use in filtering gaseous streams containing suspended solid particulates wherein a reverse flow of compressed air is utilized during the cleaning cycle, said unit featuring the advantage of being conveniently adjustable to provide a requisite degree of cloth tension without causing excessive stress conditions to occur at any part of the bag where retained by the support elements of the unit.
Abstract: A fatty acid is converted to the corresponding carbon length alcohol by the liquid phase hydrogenation of the carboxylic acid in the presence of a co-catalyst system consisting essentially of activated rhenium metal in combination with an extrinsic metal catalyst in the form of one of the platinum metals.
Abstract: A method for the preparation of N,N-dialkyl derivatives of mono- and diacyl hydrazines wherein the corresponding unsubstituted acid hydrazide is reductively alkylated with an aldehyde.
Type:
Grant
Filed:
August 27, 1976
Date of Patent:
January 31, 1978
Assignee:
Ashland Oil, Inc.
Inventors:
Robert A. Grimm, Neil A. Randen, Christopher L. Demas
Abstract: A co-reagent system in the form of an admixture of a metal chelation collector and a mono- or dialkyl substituted phosphoric acid is adapted for selectively removing ferric iron from base metal electrolytic solutions in accordance with the liquid-liquid ion exchange extraction technique.
Type:
Grant
Filed:
May 10, 1976
Date of Patent:
January 10, 1978
Assignee:
Ashland Oil, Inc.
Inventors:
Alvin D. Cronberg, James A. Hartlage, Joe W. Cotton
Abstract: Compounds (aminimides) of the class wherein a negatively charged nitrogen atom of an acylamide is directly bonded to a cationic nitrogen atom having one hydroxyethyl and two methyl substituents represent uniquely effective catalysts for the trimerization of the isocyanate radical. These aminimides are especially useful as catalysts for the preparation of rigid polyisocyanate-polyisocyanurate foams.
Abstract: A method for disengaging catalyst particulates from the effluent of a riser tube in the operation of a FCC unit. The catalyst component of the resultant ascending fluid stream is propelled from the riser tube into the catalyst disengaging or collection chamber by virtue of the inertial momentum associated therewith. The vaporous hydrocarbon conversion products containing only residual entrained amounts of catalyst, being passively restrained from entering the disengaging chamber, are simultaneously diverted to a fractionation unit via a cyclonic separator.
Type:
Grant
Filed:
November 26, 1976
Date of Patent:
January 3, 1978
Assignee:
Ashland Oil, Inc.
Inventors:
George D. Myers, Paul W. Walters, Robert L. Cottage
Abstract: The oil furnace process for the production of tread grade rubber reinforcing carbon black is modified in respect of the manner in which a carbon black producing feedstock oil is introduced into the cracking zone so as to facilitate the formation of carbon black of requisite structure characteristics having improved particle size distribution.
Abstract: A process for producing stable urea-aldehyde polymers with high structural strength from two storable liquid ingredients. In this process, partially cured liquid urea-formaldehyde resin is reacted with an aqueous cross-linking solution comprising one or more alkyl or aryl dialdehydes containing two to eight molecular carbons and the hydrogen ion concentration needed to catalyze the completion of the reaction of the dialdehydes and the urea-formaldehyde. The process for producing urea-aldehyde polymers, having improved structural strength and reduced aldehyde vapor emission during their production and prolonged use, is especially effective for manufacturing products for the building industry, such as urea-aldehyde insulating foam, wood-filled particle board, and plywood. The increased polymer strength and the elimination of the hazardous and objectionable aldehyde odor is achieved by maintaining the molecular ratio of total aldehyde moieties to urea to about 1.