Abstract: Disclosed is a process comprising preparing a product stream rich in naphthalene and 2-monoiodonaphthalene comprising contacting hydrogen and a feed stream containing iodonaphthalenes selected from the group consisting of monoiodonaphthalene, diiodonaphthalene and triiodonaphthalene and mixtures thereof with an X or Y type zeolite containing an ion selected from the group consisting of sodium, potassium and rubidium and a metal selected from the group selected from the group consisting of palladium, platinum, rhodium and ruthenium.
Type:
Grant
Filed:
September 10, 1990
Date of Patent:
June 25, 1991
Assignee:
Eastman Kodak Company
Inventors:
Victor H. Agreda, Thomas H. Larkins, Jr.
Abstract: A process is disclosed for preparing biaryl, bidentate ligands comprising:(1) contacting a biaryl compound having the structural formula: ##STR1## with a proton abstracting agent under conditions suitable to form a biaryl dianion, which is then(2) contacted with a Group V compound of the formula: ##STR2## where X' is halogen or a suitable leaving group.
Type:
Grant
Filed:
January 25, 1988
Date of Patent:
June 25, 1991
Assignee:
Eastman Kodak Company
Inventors:
Jerome L. Stavinoha, Gerald W. Phillips, Thomas A. Puckette, Thomas J. Devon
Abstract: Disclosed is a process for preparing polymeric compositions which are suitable for coating medicaments or for use in cosmetic formulations and the novel compositions prepared therefrom. The process makes stable, colloidal, latex-like dispersions of coating polymers which can be readily dried to form polymeric powder materials. The process makes use of a novel combination of a water-in-oil emulsifier and an oil-in-water emulsifier.
Type:
Grant
Filed:
June 4, 1990
Date of Patent:
June 18, 1991
Assignee:
Eastman Kodak Company
Inventors:
Stephen H. W. Wu, Carol J. Greene, Mahendra K. Sharma
Abstract: Disclosed is a process for the preparation of bis-acylamido aromatic compounds by reacting certain arylene dihalides with certain arylene dihalides in the presence of a copper catalyst. The process may be utilized in the synthesis of arylenediamines.
Abstract: Disclosed is a process for the preparation of aqueous solutions of acetoacetamide wherein diketene and aqueous ammonia having an ammonia concentration of about 6.0 to 9.0 weight percent are continuously fed to a reaction zone at rates which maintain in the reaction zone a pH of about 7.0 to 8.2 and a residence time of about 20 to 150 minutes while (i) maintaining the temperature of the reaction zone at about 40.degree. to 75.degree. C. and (ii) subjecting the contents of the reaction zone to vigorous agitation. An aqueous product solution having an acetoacetamide concentration of about 25 to 35 weight percent is continuously removed from the reaction zone.
Abstract: Provided are 1,5-bis(4-carboxycyclohexyl)-3-pentanol and its esters and processes for their preparation. Also provided are polyester compositions containing this residue, thermosetting coating compositions containing the polyesters, and coatings and casted or molded articles made therefrom.
Type:
Grant
Filed:
November 13, 1990
Date of Patent:
June 18, 1991
Assignee:
Eastman Kodak Company
Inventors:
William W. Blount, Jr., Joseph R. Zoeller
Abstract: A process for producing elemental iodine and a copoly(arylene sulfide) corresponding to the structure ##STR1## wherein y is in the range of 0.001 to 0.15, x is in the range of 0.02 to 0.65 and n is at least 100, consisting essentially of (1) reacting at a temperature above about 175.degree. C., a mixture of diiodobenzene and diiodobiphenyl and elemental sulfur to produce the copoly(arylene sulfide), and (2) recovering the elemental iodine.
Type:
Grant
Filed:
June 11, 1990
Date of Patent:
June 4, 1991
Assignee:
Eastman Kodak Company
Inventors:
David R. Fagerburg, Mark Rule, Joseph J. Watkins, Paul B. Lawrence
Abstract: The present invention is directed to a hot-melt adhesive containing at least one propylene/1-hexane copolymer. The adhesive contains an amount of a low viscosity, substantially crystalline wax, having a melting point of about 90.degree. C. to about 125.degree. C., sufficient to improve the elastic delamination resistance of the adhesive. The adhesive are particularly useful in disposable diaper construction.
Type:
Grant
Filed:
October 2, 1989
Date of Patent:
June 4, 1991
Assignee:
Eastman Kodak Company
Inventors:
Bruce W. Foster, Clyde N. Clubb, Richard K. Stuart, Jr.
Abstract: Disclosed is a composition comprising a polyester of terephthalic acid, 1,4-butanediol and/or 1,4-cyclohexanedimethanol, a halogenated organic compound, an antimony compound and a polymer of at least one olefin which contains acid, anhydride or epoxide functional groups. The composition has improved flame resistance. Also disclosed is a method for improving the flame resistance of polymeric compositions.
Abstract: Disclosed is glass fiber reinforced thermoplastic sheet material suitable for various compression molding applications. The glass fibers useful in this invention are described in detail, and the thermoplastic composition is poly(ethylene terephthalate), poly(cyclohexylene dimethylene terephthalate) or a blend of either of these polyesters with each other and/or polycarbonate.
Abstract: A method for the preparation of biaryl compounds is disclosed which comprises contacting an aryl halide with a tertiary-alkyl organometallic reagent (or the precursor components thereof) in the presence of a catalyst comprising a nickel compound and a coordinating ligand under conditions suitable for the formation of biaryl compound.In an alternate embodiment of the present invention, nickel(O) compounds are prepared from nickel(II) compounds by contacting a nickel(II) compound with a combination of an organophosphine and a bidentate nitrogen-containing coordinating ligand, and a tertiary-alkyl organometallic reagent (or the precursor components thereof) in an aprotic, non-polar, ether-containing solvent system for a time and under conditions suitable for the formation of nickel(0) compound.
Abstract: Disclosed is a polymer and process for producing the polymer using a complex of titanium alkoxide with an alkali or alkaline earth metal salt.
Abstract: Disclosed are carboxyl polyesters which are useful in the formulation of powder coating compositions. The polyesters are characterized by the presence of terminal carboxycyclohexanecarboxylate groups. Also disclosed is a process for the preparation of the carboxyl polyesters from similar hydroxy polyesters.
Abstract: This invention relates to a method of preparing poly(ethylene 2,6-naphthalene dicarboxylate) by the polycondensation reaction of ethylene glycol and dimethyl-2,6-naphthalene dicarboxylate, using a dimethyl-2,6-naphthalene dicarboxylate starting material which contains significant amounts of methyl hydrogen 2,6-naphthalene dicarboxylate as a contaminant. The methyl hydrogen 2,6-naphthalene dicarboxylate moiety is incorporated into the polymer structure by initially esterifying the methyl hydrogen 2,6-naphthalene dicarboxylate acid end-group with ethylene carbonate, in the presence of an amine or ammonium catalyst, before the polyesterification/polycondensation reaction is performed.
Abstract: Disclosed are catalyst compositions comprised of chemically-mixed, copper-titanium oxides and the use of such catalyst compositions in the hydrogenation of certain esters to obtain the alcohol corresponding to the acid residue of the ester.
Type:
Grant
Filed:
February 5, 1990
Date of Patent:
April 30, 1991
Assignee:
Eastman Kodak Company
Inventors:
Gether Irick, Jr., Patricia N. Mercer, Kenneth E. Simmons
Abstract: Disclosed is an apparatus for cleaning the interior of elongated tubular objects such as pipes, tubes, etc., using a reciprocating lance having a cleaning fluid spray head at its end. Fluid pressure provides reciprocating movement to the lance. The cleaning fluid pressure is independent of the fluid which provides movement to the lance, thereby maintaining the desired fluid pressure to the nozzle through the complete cycle of reciprocation.
Type:
Grant
Filed:
January 29, 1990
Date of Patent:
April 30, 1991
Assignee:
Eastman Kodak Company
Inventors:
Andrew E. McLeod, Gaines C. Fields, Donald J. Sanders
Abstract: Method for the highly selective transesterification of alkyl 3-alkoxypropionates, as well as several novel alkoxypropionate compounds, are provided. Transesterification catalyzed by titanium alkoxides or tin compounds does not catalyze the Michael reaction, and therefore, provide highly selective transesterification reactions of these reactive materials.
Abstract: Disclosed are copolyesters comprising an acid component of 4,4'-biphenyldicarboxylic acid and a glycol component comprising 1,4-cyclohexanedimethanol and 1,6-hexanediol. The copolyesters exhibit unusually high tensile strengths.
Type:
Grant
Filed:
June 8, 1990
Date of Patent:
April 30, 1991
Assignee:
Eastman Kodak Company
Inventors:
John C. Morris, Winston J. Jackson, Jr.
Abstract: Disclosed are copolyesters comprising an acid component of 4,4'-biphenyldicarboxylic acid and a glycol component comprising 1,4-cyclohexanedimethanol and 1,4-butanediol. The copolyesters exhibit unusually high tensile strengths.
Type:
Grant
Filed:
June 4, 1990
Date of Patent:
April 30, 1991
Assignee:
Eastman Kodak Company
Inventors:
John C. Morris, Winston J. Jackson, Jr.