Abstract: Dynamically vulcanized multi-component polymer blends are prepared containing thermoplastic polyolefins, non-vulcanized rubber, and ethylene-vinyl acetate-maleic anhydride terpolymer crosslinked in situ. The dynamically vulcanized blend is prepared from a crosslinkable composition containing thermoplastic polyolefin, rubber, non-crosslinked ethylene-vinyl acetate-maleic anhydride terpolymer, epoxy, and tertiary amine. The crosslinkable composition is crosslinked at an elevated temperature for sufficient time to crosslink the ethylene-vinyl acetate maleic anhydride terpolymer without substantial decomposition forming uniform dispersion of small particles of rubber and ethylene-vinyl acetate-terpolymer in the thermoplastic polyolefin matrix.
Abstract: Disclosed is a composition comprising(A) a chlorinated polyolefin,(B) a cationic surfactant,(C) glacial acetic acid,(D) a salt of an oxyacid of sulfur, and(E) water.
Type:
Grant
Filed:
August 12, 1991
Date of Patent:
March 30, 1993
Assignee:
Eastman Kodak Company
Inventors:
Greg A. King, Stephen L. Poteat, Paul J. Greene, Jonathan E. Lawniczak, James A. Stykes
Abstract: A method for determining the concentration of an acidic metal carbonyl hydride in an organic liquid by measuring the conductivity or pH of the liquid. The air addition to a continuous air demetallating unit may be controlled by feedback from the conductivity or pH measurement of the effluent.
Abstract: Melt processable copolyesters having improved thermal stability are prepared from 1,4-butanediol, minor amounts of trans-4,4'-stilbenedicarboxylic acid and a dicarboxylic acid selected from terephthalic acid, isophthalic acid, and mixtures thereof.
Type:
Grant
Filed:
November 4, 1991
Date of Patent:
March 16, 1993
Assignee:
Eastman Kodak Company
Inventors:
John C. Morris, Winston J. Jackson, Jr.
Abstract: Provided are polyester compositions having thermally stable colorants copolymerized therein, said colorants comprised of at least one electron-rich aromatic moiety attached to a negatively substituted 2,5-dioxypyrrolin-3-yl moiety and containing at least one, and preferably, two polyester reactive groups. Also provided are polyester color concentrates and blends of the colored polyester compositions with other thermoplastic polymers and shaped or formed articles comprised of same.
Type:
Grant
Filed:
August 19, 1991
Date of Patent:
March 16, 1993
Assignee:
Eastman Kodak Company
Inventors:
Max A. Weaver, Clarence A. Coates, William W. Parham, Samuel D. Hilbert, James J. Krutak, Wayne P. Pruett
Abstract: Disclosed are clear thermoplastic molding compositions comprising an aromatic polycarbonate, a polyester of terephthalic acid and 1,4-cyclohexanedimethanol, and the copolymeric transesterification product of the polycarbonate and polyester.
Type:
Grant
Filed:
May 30, 1991
Date of Patent:
March 16, 1993
Assignee:
Eastman Kodak Company
Inventors:
James D. Small, Jr., Robert W. Seymour, Thomas E. Flora
Abstract: Provided are novel light-absorbing polyurethane compositions and blends of said polyurethane compositions with other thermoplastic polymers. Also provided are shaped or formed articles comprised of the light-absorbing polyurethane compositions and light-absorbing thermoplastic polymer blends.
Type:
Grant
Filed:
September 27, 1991
Date of Patent:
March 16, 1993
Assignee:
Eastman Kodak Company
Inventors:
James J. Krutak, Max A. Weaver, William W. Parham, Wayne P. Pruett
Abstract: Disclosed are processes for the preparation of alkyl (alkoxycarbonylcyclohexyl)cyclohexenecarboxylates by the dimerization of alkyl 3-cyclohexenecarboxylates and the dehydrogenation of the alkyl (alkoxycarbonylcyclohexyl) cyclohexenecarboxylates to dialkyl biphenyldicarboxylates. The processes are especially useful for the preparation of dialkyl 4,4'-biphenyldicarboxylates which are intermediates in the preparation of high performance polyesters.
Type:
Grant
Filed:
September 13, 1991
Date of Patent:
March 16, 1993
Assignee:
Eastman Kodak Company
Inventors:
J. Adrian Hawkins, Patricia N. Mercer, Michael Bellas
Abstract: Aqueous application systems for applying additives to polymeric particles, methods of preparing aqueous emulsions which include at least one processing, stabilizing or other functional polymer additive and an emulsifiable wax. Also disclosed are methods of applying additives to polymeric particles and to polymeric particles treated by such methods.
Abstract: Disclosed is a class of bis(phenolic-amine)quinone compounds which are useful as stablizers for polyolefins. The bis(phenolic-amine)quinone compounds inhibit oxidative degradation of polyolefins which is attributable to heat and/or ultraviolet light and is promoted or accelerated by metals, e.g., copper, in contact with the polyolefin. The compounds also exhibit excellent thermal stability.
Type:
Grant
Filed:
March 30, 1992
Date of Patent:
February 23, 1993
Assignee:
Eastman Kodak Company
Inventors:
Richard H. S. Wang, Ping P. Shang, Daniel A. Jervis
Abstract: A process is disclosed for the preparation of 1,4-dioxy-2-butenes by reacting 3,4-epoxy-1-butene with an oxygen nucleophile in the presence of a Pd(O) complex catalyst.
Abstract: Disclosed is a process for the preparation of crystalline copolyesters from substantially amorphous, diethylene glycol-containing copolyesters wherein the a zeolite is incorporated in the substantially amorphous copolyester to promote crystallization upon heating a particulate form of the resulting copolyester at crystallizing effective temperatures.
Type:
Grant
Filed:
April 18, 1991
Date of Patent:
February 16, 1993
Assignee:
Eastman Kodak Company
Inventors:
Michael L. Cassell, Waylon L. Jenkins, Gerry F. Rhodes
Abstract: Provided are 1,5-bis(4-carboxycyclohexyl)-3-pentanol and its esters and processes for their preparation. Also provided are polyester compositions containing this residue, thermosetting coating compositions containing the polyesters, and coatings and casted or molded articles made therefrom.
Type:
Grant
Filed:
May 1, 1992
Date of Patent:
February 16, 1993
Assignee:
Eastman Kodak Company
Inventors:
William W. Blount, Jr., Joseph R. Zoeller
Abstract: Disclosed are novel catalysts useful for the hydrogenation of carbonyl-containing compounds at mild conditions of temperature and pressure to produce alcohols or amines is disclosed. The catalysts comprise palladium and zinc on a catalyst support material and are obtained by the steps of:(a) providing a catalyst support material on which is deposited zero-valent palladium in a uniformly and highly dispersed form;(b) contacting the palladium-bearing support material of (a) with zinc or a reducible compound thereof; and, preferably,(c) heating the palladium- and zinc-bearing support of (b) at a temperature of about 200.degree. to 400.degree. C. in the presence of an oxygen-containing gas.
Abstract: Modified cellulose esters are described that are prepared by grafting melamine moieties onto the backbone of cellulose esters. The resulting materials are useful in coating applications for wood, leather, and metal substrates and yield highly solvent-resistant coatings with enhanced properties when heated in the presence of an acid catalyst.
Abstract: Disclosed is composition comprising an admixture of(A) from 99 to 1 weight percent, based on the weight of the admixture, of a copoly(arylene sulfide) corresponding to the structure[(--A--S--).sub.1-x (--A--S--S--).sub.x ].sub.nwherein A is a divalent substituted or unsubstituted aromatic radical, x is in the range of 0.5 to 0.001 and n is at least 25, and(B) from 1 to 99 weight percent, based on the weight of the admixture, of an bisphenol-A polycarbonate having an inherent viscosity of at least 0.3.
Type:
Grant
Filed:
July 12, 1991
Date of Patent:
January 26, 1993
Assignee:
Eastman Kodak Company
Inventors:
Shriram Bagrodia, David R. Fagerburg, Joseph J. Watkins, Paul B. Lawrence
Abstract: Disclosed is a composition comprising(A) from 99.9 to 60 weight percent, based on the weight of the composition, of a copoly(arylene sulfide) and(B) from 0.1 to 40 weight percent, based on the weight of the composition, of an ethylene-propylene rubber.
Type:
Grant
Filed:
January 13, 1992
Date of Patent:
January 19, 1993
Assignee:
Eastman Kodak Company
Inventors:
Shriram Bagrodia, David R. Fagerburg, Steven Gedon, Joseph J. Watkins, Paul B. Lawrence, Mark Rule
Abstract: Disclosed is a process for removing chlorine-containing impurities from quinone compounds such as p-bezonquinone. The process involves extracting a quinone compound containing 1000 ppm or more chlorine with heptane, cyclohexane or a mixture thereof and separating the quinone compound from the extraction mixture. The process provides a means for obtaining quinone compounds containing 50 ppm or less chlorine.
Abstract: A composition for increased bioavailability of Vitamin E. The composition contains a Vitamin E material, a surface active agent, an inert carrier, and, optionally, a flow agent.
Type:
Grant
Filed:
February 11, 1991
Date of Patent:
January 12, 1993
Assignee:
Eastman Kodak Company
Inventors:
Carol J. Greene, Stephen H. W. Wu, Andreas M. Papas
Abstract: Process for applying multi-layer extrusion coatings to substrate at low temperature is described, employing as one extrusion coating layer a defined polyethylene-containing component, and, as the second extrusion coating layer at least one second extrudable polymeric composition. Also provided are novel extrusion coated articles comprising substrate having coated thereon defined polyethylene-containing component and at least one other extrudable polymeric composition. These articles display good adhesion of extrusion coating material to the substrate without the degradation of the extrudable coatings caused by exposure to excessive levels of heat as is required for successful extrusion coating employing prior art materials.