Patents Represented by Attorney William W. McDowell, Jr.
  • Patent number: 4094744
    Abstract: An aqueous dispersion of a biologically-active protein bound to polyurethane is formed by (a) admixing the protein and an isocyanate-capped liquid polyurethane prepolymer to form a solution; and (b) dispersing the solution in water.
    Type: Grant
    Filed: December 10, 1976
    Date of Patent: June 13, 1978
    Assignee: W. R. Grace & Co.
    Inventors: Frank Joseph Hartdegen, Wayne Elliott Swann
  • Patent number: 4088739
    Abstract: An improved process for preparing synthetic ferrierites having the absorption and catalytic properties characteristic of 5 to 8 angstrom zeolites which comprises promoting an alkaline reaction mixture comprising Group I and/or Group II cations, a source of silica, a source of alumina with lithium cations. The promoted reaction mixture is seeded with natural or synthetic ferrierite seeds, and heated to convert the mass to the synthetic ferrierite.The product has the empirical formula, 0.1 to 0.9 Li.sub.2 O:0.1:0.9 R.sub.2 0:Al.sub.2 O.sub.3 :6 to 25 SiO.sub.2 wherein R.sub.2 O is Na.sub.2 O, K.sub.2 O, or Rb.sub.2 O and/or Cs.sub.2 O; 0.1 to 0.9 Li.sub.2 O:0.1 to 0.9 WO:Al.sub.2 O.sub.3 :6 to 25 SiO.sub.2 wherein WO is BaO, CaO, MgO or SrO; or (Li.sub.2 O:R.sub.2 O:WO):Al.sub.2 O.sub.3 :6-25 SiO.sub.2 where R.sub.2 O is any R.sub.2 O above and WO is any WO above.
    Type: Grant
    Filed: June 25, 1976
    Date of Patent: May 9, 1978
    Assignee: W. R. Grace & Co.
    Inventors: David E. W. Vaughan, Grant C. Edwards
  • Patent number: 4084020
    Abstract: This invention is directed to polyenes derived from hydantoin acids, amines and esters. The polyene is typically a reaction product of a hydantoin amine, e.g., N,N'-bis(3-aminopropyl)-dimethylhydantoin, a diisocyanate and an unsaturated ether, e.g., trimethylolpropane diallyl ether. Upon exposure to a free radical generator, e. g., actinic radiation, in combination with a polythiol, this polyene cures to a solid, insoluble, chemically resistant, crosslinked polythioether product having excellent heat stability.
    Type: Grant
    Filed: June 17, 1976
    Date of Patent: April 11, 1978
    Assignee: W. R. Grace & Co.
    Inventors: Eckart Mathias, Charles Robert Morgan
  • Patent number: 4082459
    Abstract: An analytical cell assembly comprising a base with a radiation source mounted on one end, an enclosure on the other end, and a cell proper, with cell heating means, within the enclosure. The enclosure and cell have cooperative fluid flow connections whereby the cell is modular and may be simply lifted out of the enclosure. The enclosure also includes a collimating lens assembly interposed between the cell within the enclosure and the source outside the enclosure on the base. The entire assemblage of source, enclosure and cell can be moved as a unit, making it modular, or just the cell can be moved as a module leaving the enclosure and the source in place in an instrument using the invention cell assembly.
    Type: Grant
    Filed: May 27, 1976
    Date of Patent: April 4, 1978
    Assignee: Chemed Corporation
    Inventor: Court Lone Wolfe
  • Patent number: 4082830
    Abstract: This invention relates to a strippable coating process and a coating composition therefor comprising (1) a latex, (2) a coagulant for said latex and (3) a debonding agent consisting essentially of a substantially non-volatile additive which is adhesive to at least one of either the coated substrate or coagulated coating, more soluble in water than in the coagulated latex polymer component and having a solubility parameter at least 2(calories/cc).sup.1/2 higher than the coagulated latex polymer component.The protective coating is formed by impinging a stream of a latex and a stream of a coagulant, the two streams being oppositely charged, onto a substrate. After drying an external debonding agent is applied between the coating and the substrate and thereafter the coating is stripped from the substrate.
    Type: Grant
    Filed: April 23, 1974
    Date of Patent: April 4, 1978
    Assignee: W. R. Grace & Co.
    Inventor: Joseph A. Cogliano
  • Patent number: 4081598
    Abstract: This invention is directed to novel halogen-containing polythiols which impart improved flame retardancy to radiation cured thiol-ene compositions.
    Type: Grant
    Filed: May 16, 1977
    Date of Patent: March 28, 1978
    Assignee: W. R. Grace & Co.
    Inventors: Charles R. Morgan, David E. Kramm
  • Patent number: 4080484
    Abstract: This invention relates to polyenes containing at least two ethylenically unsaturated bonds per molecule formed by reacting in substantially stoichiometric amounts, (1) a primary diamine, (2) a member of the group consisting of a benzenoid-containing dianhydride, acid anhydride and anhydride acid halide and (3) an ethylenically unsaturated alcohol. The thus formed amide-acid polyene either per se or after being cured in combination with a polythiol in the presence of a free radical generator will, upon heating, imidize.
    Type: Grant
    Filed: December 23, 1976
    Date of Patent: March 21, 1978
    Assignee: W. R. Grace & Co.
    Inventor: Eckart Mathias
  • Patent number: 4079019
    Abstract: Attrition resistant and stable catalyst composition comprising crystalline aluminosilicate zeolites e.g. rare earth exchanged zeolites dispersed in an inorganic matrix containing synthetic amorphous silica-alumina and clay are prepared by a process which reduces the level of polluting ammonium salts by eliminating the use of ammonium hydroxide in the steps prior to primary filtration. During the synthesis of the amorphous inorganic matrix wherein alkali metal silicate and aluminum salt solutions are gelled and subsequently combined with zeolitic materials, the ammonia reagent is replaced by non-polluting additives such as magnesium or calcium hydroxides (or oxides) prior to a primary filtration stage without decreasing the catalytic activity of the resulting zeolite promoted hydrocarbon conversion catalysts.
    Type: Grant
    Filed: February 18, 1976
    Date of Patent: March 14, 1978
    Assignee: W. R. Grace & Co.
    Inventors: Julius Scherzer, David Evan William Vaughan, John Storey Magee
  • Patent number: 4078118
    Abstract: This invention relates to compositions of the formula: ##STR1## wherein n is 0 to 2 and at least 1 and not more than 2n + 2 of the A groups are ester radicals of the structure ##STR2## wherein R is a straight chain or branched, saturated or unsaturated hydrocarbon radical containing 11 to 19 carbon atoms and at least 2 and not more than 2n + 3 of the A groups are ester radicals of the structure ##STR3## wherein m is 0 to 1. The composition is formed by reacting one mole of a mono, di- or tri-pentaerythritol of the formula: ##STR4## WHEREIN N IS 0-2 WITH 2N + 4 MOLES OF A MIXTURE OF MONOCARBOXYLIC ACIDS FROM THE GROUP CONSISTING OF (A) AT LEAST 1 AND NOT MORE THAN 2N + 2 MOLES OF RCOOH wherein R is a straight chain or branched, saturated or unsaturated hydrocarbon radical containing 11 to 19 carbon atoms and (b) at least 2 and not more than 2n + 3 of HSCH.sub.2 (CH.sub.2).sub.m COOH wherein m is 0 to 1.
    Type: Grant
    Filed: March 23, 1977
    Date of Patent: March 7, 1978
    Assignee: W. R. Grace & Co.
    Inventors: Joseph Donald Moyer, David Edward Kramm
  • Patent number: 4073884
    Abstract: Administration of a broth fraction having enzymatic activity obtained from the fermentation of Streptomyces griseus promotes effective and more efficient utilization of feed in animals.
    Type: Grant
    Filed: December 9, 1976
    Date of Patent: February 14, 1978
    Assignee: W. R. Grace & Co.
    Inventors: Frank J. Hartdegen, Kamal M. Abdo
  • Patent number: 4070992
    Abstract: A combined timer, blow down warning device, chemical pump, and controller for boilers. The circuit comprises an electro-mechanical array of relays, flashing lights and alarms and an electronic tripper which operates from the rate of change in temperature in the blow down tailpipe, to turn off the lights and alarms only after a manual blow down operation has been performed.
    Type: Grant
    Filed: April 23, 1976
    Date of Patent: January 31, 1978
    Assignee: Chemed Corporation
    Inventor: Donald Holdt
  • Patent number: 4070066
    Abstract: Dual wheels for campers, autos, and the like light vehicles to be used in place of a single standard wheel are provided. The arrangement includes an inner wheel which has a portion to be attached to the standard studs on the vehicle wheel hub, and another portion carrying a similar set of studs upon which a second wheel can be mounted outboard of the inner wheel.
    Type: Grant
    Filed: June 8, 1976
    Date of Patent: January 24, 1978
    Assignee: W. R. Grace & Co.
    Inventors: Merlyn Ralph Reppert, James Albert Leslie
  • Patent number: 4068039
    Abstract: A thermosetting resin composition consisting essentially of a solid epoxy resin having a molecular weight in the range 1,000-4,000, 1-15% by weight of the epoxy resin of a curing agent therefor and 0.5 to 3.0% by weight of the composition of a flow control agent consisting essentially of liquid poly(ethyl acrylate) having a number average molecular weight in the range 5,000 to 15,000. The composition when melt compounded and milled to an average particle size diameter of 2-20 microns can be electrostatically deposited onto metallic surfaces such as can interiors to produce an ultra thin (0.3-1.0 mil thick) protective coating on curing.
    Type: Grant
    Filed: October 21, 1976
    Date of Patent: January 10, 1978
    Assignee: W. R. Grace & Co.
    Inventors: Donald Wayne Larsen, Jerrold Bain Billmyer
  • Patent number: 4067621
    Abstract: An inexpensive relatively theft-proof hub cap for the center of a vehicle wheel made up of inner and outer caps joined together by a screw thread connection and locking means. Each cup is plastic and molded in one piece. One of various locking arrangements integral with the two cups, with no additionally loose pieces, holds the structure securely on opposite sides of a wheel, while permitting the cups to be readily assembled or disassembled by hand without tools.
    Type: Grant
    Filed: January 20, 1976
    Date of Patent: January 10, 1978
    Assignee: W. R. Grace & Co.
    Inventor: Merlyn Ralph Reppert
  • Patent number: 4061864
    Abstract: This invention is directed to thiol containing compounds having no hydrolytically sensitive groupings which are useful as polymerization transfer agents or as curing agents in curable polymer systems containing polyenes and a free radical initiator. The thiol containing compounds are formed by reacting a polyol with an allylic halide to form a poly(unsaturated ether) whose double bonds are converted to thioesters by free radical catalyzed addition of SH groups from a thiolcarboxylic acid, e.g. thioacetic acid and the like. Hydrolysis of the thioester yields the desired thiol or polythiol derivative. Alternatively the poly(unsaturated ether) is reacted with H.sub.2 S to give the desired thiol or polythiol directly in a single step. The polythiols can be chain extended by any difunctional compound that reacts with the hydroxy groups on the polythiol.
    Type: Grant
    Filed: January 26, 1976
    Date of Patent: December 6, 1977
    Assignee: W. R. Grace & Co.
    Inventors: James Leverette Guthrie, Shrikant Vishwanath Dighe
  • Patent number: 4061662
    Abstract: A process is described which is effective in removing unreacted tolylene diisocyanate (TDI) from a polyisocyanate by bringing said polyisocyanate into contact with molecular sieves.
    Type: Grant
    Filed: June 14, 1976
    Date of Patent: December 6, 1977
    Assignee: W. R. Grace & Co.
    Inventors: Nelson Samuel Marans, Alfred Gluecksmann
  • Patent number: 4058586
    Abstract: A method of preparing zeolitic aluminosilicates particularly those zeolitic aluminosilicates that are characterized by pores in the 4 and 10A sizes that are designated Zeolites A and X by the Linde Division of Union Carbide Corporation in which compacts of the Zeolites A and X, metakaolin, clay mixture undergo crystallization at a temperature of 200.degree. to 700.degree. F. The crystallization is carried out in a calciner or other type of drying equipment. Normally the formed particles furnish all of the liquid needed for crystallization. If desired, however, additional steam may be added during the crystallization process.
    Type: Grant
    Filed: February 25, 1976
    Date of Patent: November 15, 1977
    Assignee: W. R. Grace & Co.
    Inventors: Chang Whan Chi, Gordon Herman Hoffman, Emil Eichhorn
  • Patent number: 4049592
    Abstract: The invention disclosed is directed to biodegradable hydrophilic polyurethane structures prepared by using an isocyanate capped hydroxyester polyol reactant with large amounts of aqueous reactant. The resultant foam has economy in handling, and upon contact with liquids or body fluids, the foam is highly absorptive while being readily biodegradable after use.
    Type: Grant
    Filed: October 12, 1976
    Date of Patent: September 20, 1977
    Assignee: W. R. Grace & Co.
    Inventors: Nelson Samuel Marans, Alan Ricky Pollack
  • Patent number: 4045396
    Abstract: Fire retardancy and wrinkle resistance are imparted to cellulosic textiles by impregnation of said textiles with the phosphoalkylated reaction product of a polyisocyanate and an alkyleneamine.
    Type: Grant
    Filed: October 20, 1976
    Date of Patent: August 30, 1977
    Assignee: W. R. Grace & Co.
    Inventors: Nelson Samuel Marans, Alfred Gluecksmann
  • Patent number: RE29647
    Abstract: A process for producing solid sugars wherein separate feeds of sucrose solution and of fine sucrose particles are dispersed in a current of heated air, whereby the particles are coated with the solution which is evaporated leaving a solid product containing substantially all the sugar fed to the process.
    Type: Grant
    Filed: December 9, 1976
    Date of Patent: May 30, 1978
    Assignee: W. R. Grace & Co.
    Inventors: Preston Leonard Veltman, Johannes C. J. Verdonk, Lars Olav Thomsen