Patents Assigned to A/S Cheminova
  • Patent number: 4282241
    Abstract: The invention provides novel fluoro-imides/amides of the formula: ##STR1## in which at least two of X.sub.1, X.sub.2, X.sub.3 and X.sub.4 are fluorine and any of X.sub.1, X.sub.2, X.sub.3 and X.sub.4 which is not fluorine, is chlorine, and A is selected from:(a) ##STR2## in which R.sub.1 is hydrogen or a halogen atom, preferably chlorine,Z is CH or a nitrogen atom,n is 0 or 1, andR is an alkyl group having 1-6 carbon atoms, preferably methyl, or a halogen atom, preferably chlorine;(b) ##STR3## in which Z, n and R have the above-stated meanings: (c) ##STR4## and (d) ##STR5## and a process for preparing said compounds. Said compounds have valuable fungicidal and miticidal activity.
    Type: Grant
    Filed: January 28, 1980
    Date of Patent: August 4, 1981
    Assignee: A/S Cheminova
    Inventors: Hans B. Madsen, Per D. Klemmensen, Hans Kolind-Andersen
  • Patent number: 4229353
    Abstract: (2,2-Disubstituted vinyl)-.gamma.-butyrolactones of the formula: ##STR1## in which R.sub.1 and R.sub.2 are hydrogen or C.sub.1 -C.sub.6 alkyl, preferably methyl,R.sub.3 and R.sub.4 are hydrogen, C.sub.1 -C.sub.6 alkyl, preferably methyl, or halogen, or, together with the carbon atom to which they are attached, form a cycloalkyl group, andR.sub.5 is C.sub.1 -C.sub.6 alkyl,are prepared by condensing an epoxide of the formula: ##STR2## with a malonic acid ester of the formula: ##STR3## in a basic medium. The butyrolactones of formula I are valuable intermediates for the synthesis of synthetic pyrethroids having insecticidal activity.
    Type: Grant
    Filed: April 3, 1979
    Date of Patent: October 21, 1980
    Assignee: A/S Cheminova
    Inventors: Per D. Klemmensen, Hans Kolind-Andersen, Hans B. Madsen
  • Patent number: 4219558
    Abstract: The invention provides novel fluoro-imides/amides of the formula: ##STR1## in which at least two of X.sub.1, X.sub.2, X.sub.3 and X.sub.4 are fluorine and any of X.sub.1, X.sub.2, X.sub.3 and X.sub.4 which is not fluorine, is chlorine, and A is selected from: ##STR2## in which R.sub.1 is hydrogen or a halogen atom, preferably chlorine,Z is CH or a nitrogen atom,n is 0 or 1, andR is an alkyl group having 1-6 carbon atoms, preferably methyl, or a halogen atom, preferably chlorine; ##STR3## in which Z, n and R have the above-stated meanings: ##STR4## and a process for preparing said compounds. Said compounds have valuable fungicidal and miticidal activity.
    Type: Grant
    Filed: December 7, 1978
    Date of Patent: August 26, 1980
    Assignee: A/S Cheminova
    Inventors: Hans B. Madsen, Per D. Klemmensen, Hans Kolind-Andersen
  • Patent number: 4148901
    Abstract: The invention provides novel fluoro-imides/amides of the formula: ##STR1## IN WHICH AT LEAST TWO OF X.sub.1, X.sub.2, X.sub.3 and X.sub.4 are fluorine and any of X.sub.1, X.sub.2, X.sub.3 and X.sub.4 which is not fluorine, is chlorine, and A is selected from:(a) ##STR2## IN WHICH R.sub.1 is hydrogen or a halogen atom, preferably chlorine, Z is CH or a nitrogen atom,N is 0 or 1, andR is an alkyl group having 1-6 carbon atoms, preferably methyl, or a halogen atom, preferably chlorine;(b) ##STR3## IN WHICH Z, n and R have the above-stated meanings: (C) ##STR4## (d) ##STR5## and a process for preparing said compounds. Said compounds have valuable fungicidal and miticidal activity.
    Type: Grant
    Filed: November 17, 1976
    Date of Patent: April 10, 1979
    Assignee: A/S Cheminova
    Inventors: Hans B. Madsen, Per D. Klemmensen, Hans Kolind-Andersen
  • Patent number: 4138584
    Abstract: A three-step process for the production of chrysanthemic acid esters and their homologues of the formula: ##STR1## in which R.sub.1 and R.sub.2 are hydrogen or C.sub.1 -C.sub.6 alkyl,R.sub.3 and R.sub.4 are C.sub.1 -C.sub.6 alkyl or halogen or, together with the C atom to which they are attached, form a cycloalkyl group, andR.sub.5 is C.sub.1 -C.sub.6 alkyl,Which comprises:(1) decarboxylating a lactone of the formula: ##STR2## (2) treating the resulting decarboxylated lactone to effect ring cleavage, halogenation and esterification to form an ester of the formula: ##STR3## in which X is Cl, Br or I, and (3) TREATING THE ESTER X with a base to effect internal condensation whereby the desired product of formula I is obtained.The esters I are valuable intermediates for the preparation of synthetic pyrethroids having insecticidal activity.
    Type: Grant
    Filed: May 23, 1977
    Date of Patent: February 6, 1979
    Assignee: A/S Cheminova
    Inventors: Per D. Klemmensen, Hans Kolind-Andersen, Hans B. Madsen
  • Patent number: 4061757
    Abstract: This invention is concerned with certain substituted 3-hydroxy- or 3-aminopyridines and their preparation and use. These compounds possess improved juvenile hormonal activity which can be utilized first and foremost to inhibit the metamorphosis of insect larvae and, consequently, can be utilized in the control of insects.
    Type: Grant
    Filed: September 23, 1975
    Date of Patent: December 6, 1977
    Assignee: A/S Cheminova
    Inventors: Hans Berg Madsen, Preben Lindholm Holst, Houk Solli
  • Patent number: 4002615
    Abstract: This invention is concerned with certain terpenoid compounds of substituted hydroxy-alkylpyridines, and their preparation and use. These compounds possess improved juvenile hormonal activity which can be utilized first and foremost to inhibit the metamorphosis of insect larvae and to act as sterilizing or ovicidal agent and, consequently, can be utilized in the control of insects.
    Type: Grant
    Filed: July 25, 1974
    Date of Patent: January 11, 1977
    Assignee: A/S Cheminova
    Inventors: Hauk Solli, Per Dausell Klemmensen, Preben Lindholm Holst, Hans Berg Madsen
  • Patent number: 3941777
    Abstract: This invention is concerned with certain alkyl, terpenoid and olefinic oximethers of some aryl, pyridyl and alifatie aldehydes and ketones, and their preparation and use. These compounds possess improved juvenile hormonal activity which can be utilized first and foremost to inhibit the metamosphosis of insert larvae and to act as sterilizing or ovicidal agent, consequently, can be utilized in the control of insects.
    Type: Grant
    Filed: December 19, 1973
    Date of Patent: March 2, 1976
    Assignee: A/S Cheminova
    Inventors: Hans Berg Madsen, Preben Lindholm Holst, Houk Solli