Patents Assigned to A. Schulman, Inc.
-
Publication number: 20190382545Abstract: Foamed reactor made thermoplastic polyolefins (rTPOs), and articles made therefrom, are described. The compositions have an rTPO combined with a foaming agent. The foaming agent can be a physical blowing agent and/or a chemical foaming agent, and may include optional nucleating agents. Some compositions utilize a masterbatch having one or more chemical foaming agents to foam the rTPOs. The rTPOs have a large melt flow rate range and flexural modulus range that translate into a broad scope of potential applications and foamed architecture. This allows the combination of rTPOs and foaming agents to be fine-tuned for selected foaming application.Type: ApplicationFiled: June 14, 2019Publication date: December 19, 2019Applicant: A. SCHULMAN, INC.Inventors: VASSILIOS GALIATSATOS, FABIO CECCARANI, CHICHANG SHU, RYAN KRAMB, IGNAZIO TRIASSI
-
Publication number: 20190382549Abstract: Foamed propylene-based reactor made polyolefins, and articles made therefrom, are described. The compositions have a resin that is a reactor made propylene based random copolymer or terpolymer with high comonomer content, combined with a foaming agent. The foaming agent can be at least one physical blowing agent or at least one chemical foaming agent, and may include optional nucleating agents. Reactor made copolymers and terpolymers have a large range of high comonomer content and therefore have physical properties such as increased flexibility, high gloss, lower sealing temperature, and improved compatibility with other polyolefins. These properties translate into a broad scope of potential applications and foamed architecture. This allows the combination of the copolymer or terpolymer, and foaming agents to be fine-tuned for selected foaming application.Type: ApplicationFiled: June 14, 2019Publication date: December 19, 2019Applicant: A. SCHULMAN, INC.Inventors: VASSILIOS GALIATSATOS, FABIO CECCARANI, CHICHANG SHU, RYAN KRAMB, IGNAZIO TRIASSI
-
Publication number: 20190292878Abstract: A polymetaphosphate composition and method for temporarily scaling a perforation in a wellbore to facilitate a treatment therein and a well tool which can include a flow path, and a flow blocking device which selectively prevents flow through the flow path. The well tool can include a polymetaphosphate composition. A method of constructing a downhole well tool can include forming a structure of a solid mass comprising a polymetaphosphate composition, and incorporating the structure into the well tool.Type: ApplicationFiled: June 11, 2019Publication date: September 26, 2019Applicant: A. SCHULMAN, INC.Inventors: BRADLEY L. TODD, STANLEY J. HEATH
-
Patent number: 10352127Abstract: A polymetaphosphate composition and method for temporarily sealing a perforation in a wellbore to facilitate a treatment therein and a well tool which can include a flow path, and a flow blocking device which selectively prevents flow through the flow path. The well tool can include a polymetaphosphate composition. A method of constructing a downhole well tool can include forming a structure of a solid mass comprising a polymetaphosphate composition, and incorporating the structure into the well tool.Type: GrantFiled: October 21, 2015Date of Patent: July 16, 2019Assignee: A. Schulman, Inc.Inventors: Bradley L. Todd, Stanley J. Heath
-
Publication number: 20190169433Abstract: Disclosed herein are high performance semi-aromatic polyamide compounds having improved performance indicators for various applications, including alkaline battery end cap seal assembly applications. In one preferred embodiment, the disclosure relates to compounds comprising a semi-aromatic polyamide component comprising recurring terephthalamide and/or isophthalamide units, an impact modifier component comprising a modified polyolefin elastomer, one or more synergistic blends of sterically hindered phenolic stabilizers and phosphonates and one or more relatively high molecular weight organic phosphite stabilizers, and a fine talc nucleating agent.Type: ApplicationFiled: November 30, 2018Publication date: June 6, 2019Applicant: A. Schulman, Inc.Inventor: Ying Shi
-
Patent number: 9914868Abstract: Provided is a method of treating a subterranean formation comprising: preparing a well servicing fluid comprised of a base fluid, a temporary compacted material wherein the temporary compacted material is a compacted organic acid; placing the well servicing fluid into a subterranean formation; and allowing the temporary compacted material to gradually dissolve.Type: GrantFiled: March 4, 2014Date of Patent: March 13, 2018Assignee: A. SCHULMAN, INC.Inventors: Charles J. Busceme, Bradley L. Todd, Stanley J. Heath
-
Patent number: 9873772Abstract: Monomodal foamed polymeric compositions containing clay nucleating agents are described. The clays are preferably sepiolite, palygorskite/attapulgite, or combinations thereof. Also described are processes for forming the foamed compositions.Type: GrantFiled: December 16, 2013Date of Patent: January 23, 2018Assignee: A. SCHULMAN, INC.Inventors: Juan Antonio Igualada, Jose Luis Feijoo
-
Patent number: 9783653Abstract: Foamed polymeric compositions containing clay nucleating agents are described. The clays are preferably sepiolite, palygorskite/attapulgite, or combinations thereof. Also described are processes for forming the foamed compositions. The resulting products find particular application as insulation and packaging materials.Type: GrantFiled: May 12, 2011Date of Patent: October 10, 2017Assignee: A. SCHULMAN, INC.Inventors: Juan-Antonio Igualada, Jose-Luis Feijoo
-
Patent number: 8182906Abstract: A multilayer structure includes a clear polyolefin layer, a colored polyolefin layer, and a random polyolefin backing layer. The colored and backing layers are coextruded and are permanently bonded at a layer interface, which is exclusive of an adhesive. The structure has a DOI of 70 or greater and passes a gravelometer impact test per the GM9508P standard, with a 10 pint load, at a ?30° C. temperature, and at an impact angle of 30 degrees. Among other uses, the structures are appropriate for use as body panels in the motor vehicle industry. The structures display a “class A” finish and meet a variety of requirements for durability and weatherability. An ABA structured backing layer and a method of making it are also described herein.Type: GrantFiled: August 26, 2011Date of Patent: May 22, 2012Assignee: A. Schulman, Inc.Inventor: Dennis C. Smith
-
Publication number: 20120064317Abstract: A multilayer structure includes a clear polyolefin layer, a colored polyolefin layer, and a random polyolefin backing layer. The colored and backing layers are coextruded and are permanently bonded at a layer interface, which is exclusive of an adhesive. The structure has a DOI of 70 or greater and passes a gravelometer impact test per the GM9508P standard, with a 10 pint load, at a ?30° C. temperature, and at an impact angle of 30 degrees. Among other uses, the structures are appropriate for use as body panels in the motor vehicle industry. The structures display a “class A” finish and meet a variety of requirements for durability and weatherability. An ABA structured backing layer and a method of making it are also described herein.Type: ApplicationFiled: August 26, 2011Publication date: March 15, 2012Applicant: A. SCHULMAN, INC.Inventor: Dennis C. Smith
-
Publication number: 20110230587Abstract: The present invention relates to articles comprising flavored polymeric compositions. More specifically, the invention relates to articles comprising flavored polymeric compositions comprising “flavor enhancing agents” alone, or in combination with, other flavorants. The articles comprising a flavored polymeric composition do not have to be consumed, significantly destructed, masticated or fully or partially dissolved to release flavor.Type: ApplicationFiled: March 3, 2011Publication date: September 22, 2011Applicant: A. SCHULMAN, INC.Inventors: Kari L. MacInnis, Tomy Widya, Corey Capasso
-
Patent number: 8007902Abstract: A multilayer structure includes a clear polyolefin layer, a colored polyolefin layer, and a random polyolefin backing layer. The colored and backing layers are coextruded and are permanently bonded at a layer interface, which is exclusive of an adhesive. The structure has a DOI of 70 or greater and passes a gravelometer impact test per the GM9508P standard, with a 10 pint load, at a ?30° C. temperature, and at an impact angle of 30 degrees. Among other uses, the structures are appropriate for use as body panels in the motor vehicle industry. The structures display a “class A” finish and meet a variety of requirements for durability and weatherability. An ABA structured backing layer and a method of making it are also described herein.Type: GrantFiled: August 27, 2009Date of Patent: August 30, 2011Assignee: A. Schulman, Inc.Inventor: Dennis C. Smith
-
Publication number: 20100055233Abstract: The present invention relates to optimization of flavored polymeric compositions and methods of producing optimized flavored polymeric compositions. More specifically, the invention relates to flavored polymeric compositions comprising “flavor enhancing agents” alone or in combination with other flavorants as well as polymeric articles made from the same, wherein articles made from such polymeric compositions are not intended to be consumed, significantly destructed, masticated or fully or partially dissolved to release flavor.Type: ApplicationFiled: August 28, 2009Publication date: March 4, 2010Applicant: A. SCHULMAN, INCInventors: Kari L. Macinnis, Tomy Widya
-
Publication number: 20100015426Abstract: A multilayer structure includes a clear polyolefin layer, a colored polyolefin layer, and a random polyolefin backing layer. The colored and backing layers are coextruded and are permanently bonded at a layer interface, which is exclusive of an adhesive. The structure has a DOI of 70 or greater and passes a gravelometer impact test per the GM9508P standard, with a 10 pint load, at a ?30° C. temperature, and at an impact angle of 30 degrees. Among other uses, the structures are appropriate for use as body panels in the motor vehicle industry. The structures display a “class A” finish and meet a variety of requirements for durability and weatherability. An ABA structured backing layer and a method of making it are also described herein.Type: ApplicationFiled: August 27, 2009Publication date: January 21, 2010Applicant: A. SCHULMAN, INC.Inventor: Dennis C. Smith
-
Publication number: 20090317649Abstract: A multilayer structure includes a clear polyolefin layer, a colored polyolefin layer, and a random polyolefin backing layer. The colored and backing layers are coextruded and are permanently bonded at a layer interface, which is exclusive of an adhesive. The structure has a DOI of 70 or greater and passes a gravelometer impact test per the GM9508P standard, with a 10 pint load, at a ?30° C. temperature, and at an impact angle of 30 degrees. Among other uses, the structures are appropriate for use as body panels in the motor vehicle industry. The structures display a “class A” finish and meet a variety of requirements for durability and weatherability. An ABA structured backing layer and a method of making it are also described herein.Type: ApplicationFiled: August 27, 2009Publication date: December 24, 2009Applicant: A. SCHULMAN, INC.Inventor: Dennis C. Smith
-
Patent number: 6797779Abstract: The subject invention discloses a thermoplastic composition which is comprised of a blend of a thermoplastic polyolefin resin and a modified elastomer, wherein said thermoplastic polyolefin resin selected at least from the group of polyethylene, isotactic polypropylene, syndiotactic polypropylene, polypropylene impact copolymers containing about 1-7% by weight of ethylene, butene, hexene, or octene, polyolefin copolymers such as ethylene-butene, hexene, or octene, polybutene, reactor grade modified polypropylene, metallocene polypropylene, oxypolypropylene, wherein said modified elastomer is comprised of a conjugated diene selected from 1,3-butadiene and isoprene, wherein said modified elastomer is highly branched, wherein said modified elastomer is characterized by having a G′ and G″ frequency crossover of no more than 4 radians/s at 100° C.Type: GrantFiled: March 28, 2003Date of Patent: September 28, 2004Assignees: The Goodyear Tire & Rubber Company, A. Schulman, Inc.Inventors: Manoj Ajbani, Thierry Florent Edme Materne, Christopher Kiehl, Rengarajan Ramesh, Brian D. Fairchild
-
Patent number: 6207761Abstract: A thermoplastic ionomer blend or alloy exhibiting advantageous properties upon molding or extrusion and/or thermoforming, consisting essentially of the following components: A. about 15 to 85 parts by weight of a thermoplastic copolymer containing about 91 to 80 weight percent of alpha-olefin units and about 9 to 20 weight percent of alpha, beta-ethylenically unsaturated carboxylic acid units said carboxylic acid units being about 20 to 90 percent neutralized with metal ions, preferably zinc, B. about 10 to 80 parts by weight of a rubber, preferably a thermoplastic elastomer selected from the group consisting of (a) crosslinked ethylene-propylene-diene copolymers and equivalent polyolefin copolymers such as ethylene-butene, hexene, or octene, (b) acrylonitrile-butadiene copolymers, (c) styrene-butadiene copolymers, and (d) styrene acrylonitrile graft-crosslinked butadiene rubbers, and C.Type: GrantFiled: March 18, 1999Date of Patent: March 27, 2001Assignee: A. Schulman, Inc.Inventors: Dennis C. Smith, Anita Shah, Alain C. Adam, Roy H. Kinsey, Brian D. Fairchild
-
Patent number: 5567797Abstract: The object of the present invention is a polyamide composition containing, in reference to the polyamide composition 0.1 to 1 wt. % terephthaldialdehyde and/or its acetals of C.sub.1 --C.sub.4 alcohols and optionally 3 to 30 wt. % melamine and/or melamine cyanurate as well as a process for the production of the polyamide, a process to increase the shock resistance, notched impact resistance and viscosity of flameproof, halogen-free polyamides, and a process to increase the mass of such polyamides.Type: GrantFiled: February 27, 1995Date of Patent: October 22, 1996Assignee: A. Schulman, Inc.Inventors: Hubert Christ, Wolfgang Schneider
-
Patent number: 4699734Abstract: The invention relates to base polyolefin compositions, and concentrates thereof adapted to be let down or diluted by addition of further polyolefin, flameproofed by incorporation therein of an organohalo flame-retardant and a metal oxide or sulfide synergist, are rendered resistant to exudation by incorporating therein the combination of an epoxy resin, an elastomeric resin, and a nucleating agent, the epoxy resin being present in an amount of from about 0.01 to about 10 percent, the elastomeric resin being present in an amount of from about 0.1 to about 20 percent, and the nucleating agent being present in an amount of from about 0.1 to about 10 percent and non-fogging molded products obtained thereby.Type: GrantFiled: November 6, 1985Date of Patent: October 13, 1987Assignee: A. Schulman, Inc.Inventors: Shirley N. Kendall, Ramesh Rengarajan
-
Patent number: 4528123Abstract: Resistance to cathodic or galvanic disbondment of plastic-metal laminates is obtained by incorporating in the metal bonding plastic material used in forming the laminate an amount of conductive carbon black effective to minimize or prevent disruption of the bond by galvanic action which otherwise would take place in the absence of the conductive carbon black. The conductive carbon black is used in a relatively high concentration, for example, between about 20 and about 40 percent, with the balance of the composition being made up of a polymeric material containing an amount effective to promote bonding between the metal and the polymeric material of an ionomeric copolymer containing about 25 to about 98.5 percent ethylenic units and between about 1.5 to about 30 percent carboxylic acid units, the major proportion of which is in the free acid form. Advantageously, two-thirds or more of the carboxylic units are in the free form and the remainder, if any, are neutralized by zinc.Type: GrantFiled: April 9, 1984Date of Patent: July 9, 1985Assignee: A. Schulman, Inc.Inventor: Wayne F. Nelson