Abstract: A pyrolysis heater particularly for the cracking of hydrocarbons in the production of olefins has a burner arrangement in the firebox which includes staged combustion low NOx hearth burners firing upwardly in the firebox adjacent to the walls. Wall stabilizing gas fuel injection tips, located at an elevation above the hearth burners, inject fuel upwardly between the walls and the flame from the hearth burners. This prevents rollover of the flame onto the process heater coil and overheating of the coil.

Abstract: A process and apparatus for the recovery of ethane and heavier components from a hydrocarbon feed gas stream. Feed gas stream is cooled and separated into a vapor stream and a condensed stream. Vapor stream is divided into a first and a second gas streams. First gas stream is expanded and sent to a fractionation tower. Second gas stream is supplied to an absorber tower. At least a part of the first liquid stream is cooled and sent to the absorber. Absorber column produces a lean vapor stream and a second condensed stream. Lean vapor stream is cooled and sent to the fractionation tower. Second condensed stream is subcooled and supplied to the fractionation tower. Temperatures and pressures of the streams and columns are maintained to recover a major portion of ethane and heavier hydrocarbon components as bottom product, and produce at the fractionation tower overhead, a residue gas stream.

Abstract: In one aspect, the invention provides a catalyst for the production of synthesis gas, the catalyst comprising a) from about 0.1 to about 1.3% by weight of nickel that is supported on modified support, and b) a promoting agent. The catalyst can also comprise a dispersing agent. In another aspect, the invention provides a process for preparing the catalyst above, and a process for the catalytic partial oxidation of methane using the same catalyst.

Abstract: A method for treating zeolite particles to remove organic templating agent therefrom is accomplished by calcining the zeolite particles in a fluidized-bed at a temperature of no more than about 600° C. for a period of time sufficient to remove at least about 50% of the organic templating agent.

Abstract: An integrated process combines olefin epoxidation with production of cyclohexanone and cyclohexanol for nylon. Cyclohexanone and cyclohexanol normally produced by the oxidation of cyclohexane, in which cyclohexyl hydroperoxide is generated and is removed or decomposed down stream. However, this invention utilizes the intermediate of cyclohexyl hydroperoxide as an oxidant for the olefin epoxidation and meanwhile generates a valuable product.

Abstract: A catalytic material includes microporous zeolites supported on a mesoporous inorganic oxide support. The microporous zeolite can include zeolite Beta, zeolite Y (including “ultra stable Y”—USY), mordenite, Zeolite L, ZSM-5, ZSM-11, ZSM-12, ZSM-20, Theta-1, ZSM-23, ZSM-34, ZSM-35, ZSM-48, SSZ-32, PSH-3, MCM-22, MCM-49, MCM-56, ITQ-1, ITQ-2, ITQ-4, ITQ-21, SAPO-5, SAPO-11, SAPO-37, Breck-6, ALPO4-5, etc. The mesoporous inorganic oxide can be e.g., silica or silicate. The catalytic material can be further modified by introducing some metals e.g. aluminum, titanium, molybdenum, nickel, cobalt, iron, tungsten, palladium and platinum. It can be used as catalysts for acylation, alkylation, dimerization, oligomerization, polymerization, hydrogenation, dehydrogenation, aromatization, isomerization, hydrotreating, catalytic cracking and hydrocracking reactions.

Abstract: A process for the production of alkylbenzene includes the steps of introducing benzene and an olefin feed into a first alkylation reaction zone in the presence of a first alkylation catalyst under first alkylation reaction conditions to produce alkylbenzene and a vapor containing unconverted olefin; absorbing the unconverted olefin into an aromatic stream containing benzene and alkylbenzene; and, introducing the aromatic stream containing absorbed olefin into a second alkylation reaction zone containing a second alkylation catalyst under second alkylation reaction conditions to convert the absorbed olefin and at least some of the benzene of the aromatic stream to alkylbenzene. The process is particularly advantageous for the alkylation of benzene with ethylene to produce ethylbenzene. About 99.

Abstract: A process for the production of alkylbenzene includes introducing benzene and an olefin feed into a first alkylation reaction zone in the presence of a first alkylation catalyst under first alkylation reaction conditions to produce a first alkylation effluent containing alkylbenzene and a first alkylation overhead stream. The first alkylation overhead stream is separated into a liquid portion containing benzene and a vapor portion containing unconverted olefin and ethane. A major portion of the unconverted olefin in the vapor portion of the first alkylation overhead stream is absorbed into a de-ethanized aromatic lean oil stream containing benzene and alkylbenzene in an absorption zone to produce a rich oil stream containing olefins and at least some of the ethane.

Abstract: A two-tower scheme process for the recovery of propane and heavier components from a hydrocarbon gas stream is provided. Feed gas is cooled, partially condensed, and then separated to give a first liquid stream and a first vapor stream. First liquid stream is sent to a distillation tower that recovers at the bottoms a major portion of propane and heavier components and produces an overhead gas stream. First vapor stream is expanded and sent as bottom feed to the absorber. Absorber produces an absorber overhead stream containing essentially all the ethane and lighter components and an absorber bottoms stream. Absorber bottoms stream is heated and sent to the distillation tower as middle feed. Absorber overhead stream is warmed and optionally compressed. A part of the compressed stream is substantially condensed and sent to absorber as top feed. The process and apparatus can be used to recover ethane and heavier hydrocarbons.

Abstract: A cracking furnace for the pyrolysis heating of an organic feedstock includes a heating section and at least one convection section. In one embodiment the furnace includes first and second convection sections positioned along opposite sides of the heating section. The openings for admitting flue gas to the convection sections can be at the top or the bottom of the heating section. In another embodiment the furnace includes a plurality of passageways for the communication of flue gas from the heating section to the convection section. The passageways can be positioned at the top or the bottom of the heating section. The passageways provide a more even flow of flue gas through the heating section by preventing recirculation of the flue gas within the heating chamber.

Abstract: A process for the hydrogenation of a hydrocarbon feed containing unsaturated components includes providing a catalyst including at least one noble metal on a non-crystalline, mesoporous inorganic oxide support having at least 97 volume percent interconnected mesopores based upon mesopores and micropores, a BET surface area of at least 300 m2/g and a pore volume of at least 0.3 cm3/g; and, contacting the hydrocarbon feed with hydrogen in the presence of said catalyst under hydrogenation reaction conditions.

Abstract: A process and apparatus for controlling or reducing the heating value or BTU content of NGL recovered from LNG streams. LNG pipelines have a maximum allowable heating value that LNG must be within prior to entering the pipeline. If the LNG heating value is too high, the components contributing to the high heating value must be removed prior to being introduced in the pipeline. The process controls the heating value of the residue LNG gas stream by splitting a feed stream and warming at least a portion of the feed stream. Substantial differences in enthalpy content and temperature between the two portions of the feed stream exist prior to being sent to a fractionation tower.

Abstract: An apparatus for converting at least one nitrogen oxide, such as NO, O2, or N2O converts oxide in the presence of a catalyst supported on a metal mesh-like structure. The mesh-like structure is preferably fibrous formed of metal or ceramic fibers which may include knitted wire, sintered metal fibers and so on and has a porosity greater than about 85%. The mesh is formed into channels, preferably corrugations, and includes vortex generators, which generate turbulence to create a pressure differential across the mesh, to promote flow of fluids through the mesh pores which normally do not exhibit flow therethrough in the absence of such pressure differential. Preferred embodiments of structured packing and monoliths are disclosed each having a catalyst preferably in the mesh pores and/or coated on the fibers for converting the nitrogen oxide.

Abstract: A catalytic material includes a microporous zeolite supported on a mesoporous inorganic oxide support. The microporous zeolite can include zeolite beta, zeolite Y or ZSM-5. The mesoporous inorganic oxide can be, e.g., silica or alumina, and can optionally include other metals. Methods for making and using the catalytic material are described herein.

Abstract: A process for treating organic compounds includes providing a composition which includes a substantially mesoporous structure of silica containing at least 97% by volume of pores having a pore size ranging from about 15 ? to about 30 ? and having a micropore volume of at least about 0.01 cc/g, wherein the mesoporous structure has incorporated therewith at least about 0.02% by weight of at least one catalytically and/or chemically active heteroatom selected from the group consisting of Al, Ti, V, Cr, Zn, Fe, Sn, Mo, Ga, Ni, Co, In, Zr, Mn, Cu, Mg, Pd, Pt and W, and the catalyst has an X-ray diffraction pattern with one peak at 0.3° to about 3.5° at 2?. The catalyst is contacted with an organic feed under reaction conditions wherein the treating process is selected from alkylation, acylation, oligomerization, selective oxidation, hydrotreating, isomerization, demetalation, catalytic dewaxing, hydroxylation, hydrogenation, ammoximation, isomerization, dehydrogenation, cracking and adsorption.

Abstract: A process for the fluid catalytic cracking of hydrocarbons includes contacting relatively heavy hydrocarbons with a fluidized particulate catalyst in a reaction zone under catalytic cracking conditions to convert at least some of the heavy hydrocarbons to light olefins having from 3 to 4 carbon atoms, conveying a reaction mixture containing spent catalyst particles and a gaseous stream containing the light olefins and other reaction products to a cyclone separation system directly connected to the reaction zone, at least part of the cyclone separation system being positioned within an interior space enclosed by a vessel, the interior space including a stripping region and an upper region in which the cyclone separation system is positioned. The cyclone separation system includes at least one cyclone connected directly to the reaction zone and having an interior pressure at least 0.05 psig lower than the pressure in the stripping region.

Abstract: A material especially useful for the selective oxidation of hydrocarbons and other organic compounds includes a non-crystalline, porous inorganic oxide having at least 97 volume percent mesopores based on micropores and mesopores, and at least one catalytically active metal selected from the group consisting of one or more transition metal and one or more noble metal.

Abstract: An olefin isomerization process employs a basic metal oxide catalyst, such as magnesium oxide, which retains at least about 85 percent of its initial activity for at least about 168 hours of on-stream time. The catalyst is preferably a high purity magnesium oxide. The olefin isomerization process and catalyst described herein are advantageously used for the production of a terminal olefin such as 1-butene from an internal olefin such as 2-butene.

Abstract: A marine buoy for the offshore support of subsea production and drilling activities that has a closed-bottomed base section with a solid ballast and variable ballast chambers, a chamber in the base section for storing equipment and supplies, and an upper section with a smaller cross-sectional area than the base section having an elevator shaft leading from the top of the upper section to the chamber in the base section. The upper section supports a deck for housing process equipment for operations that the marine buoy is supporting.

Abstract: A process for the alkylation of paraffins with olefins includes contacting the paraffin with the olefin under alkylation conditions with a zeolite having an AAI number of at least about 1.0. In a preferred process isobutane is alkylated with cis-2-butene to produce a high octane (RON) gasoline product containing trimethylpentane isomers.