Abstract: In various embodiments, rapid, sensitive detection of molecular hydrogen is achieved by chemically converting hydrogen to water vapor and then detecting the water vapor as a surrogate for the hydrogen. Detection may be enhanced by dampening variation in ambient water vapor and rapidly actively modulating a hydrogen-derived water vapor component. For example, the detector may receive sample gas that includes ambient water vapor and hydrogen, dry the sample gas to dampen variation in the ambient water vapor, divide the sample gas into a chemical conversion flow and a bypass flow, chemically convert hydrogen in the chemical conversion flow to water vapor, alternate between measuring water vapor in the converted chemical conversion flow or the bypass flow to produce a water vapor signal, separate the water vapor signal in the time domain to extract a hydrogen-derived water vapor signal, and output a hydrogen signal based on the hydrogen-derived water vapor signal.

Abstract: In various embodiments, rapid, sensitive detection of molecular hydrogen is achieved by receiving sample gas that includes ambient water vapor and hydrogen, passing the sample gas through a gas dryer, chemically converting hydrogen in the sample gas to water vapor to produce converted sample gas, measuring water vapor in the converted sample gas to produce a water vapor signal, separating the water vapor signal in the time domain into an ambient water vapor signal and a hydrogen-derived water vapor signal, wherein the gas dryer dampens variation in the ambient water vapor signal, and outputting a hydrogen signal that describes molecular hydrogen in the sample gas that is based on the hydrogen-derived water vapor signal.

Abstract: In one embodiment, a return flux linear alternator employs a magnet assembly that includes a pair of permanent ring magnets with opposing polarity and a pair of air gaps. The additional permanent ring and air gap complete a magnetic flux loop of the alternator rather than the magnet pole, as in traditional designs. An alternator coil assembly includes a pair of oppositely wound coil sections that each linearly move through a respective one of the pair of air gaps. In addition, the return flux linear alternator may employ a variety of structures to increase mechanical strength, including a reinforcement fabric, and a variety of structures to increase electrical efficiency, including a thermally conductive but electrically nonconductive spacer between the coil sections and multiple pairs of electrical leads.

Abstract: In one embodiment, a CO2 leak detection instrument detects leaks from a site (e.g., a CO2 sequestration facility) using rapid concentration measurements of CO2, O2 and optionally water concentration that are achieved, for example, using laser spectroscopy (e.g. direct absorption laser spectroscopy). Water vapor in the sample gas may not be removed, or only partially removed. The sample gas may be collected using a multiplexed inlet assembly from a plurality of locations. CO2 and O2 concentrations may be corrected based on the water concentration. A resulting dataset of the CO2 and O2 concentrations is analyzed over time intervals to detect any changes in CO2 concentration that are not anti-correlated with O2 concentration, and to identify a potential CO2 leak in response thereto. The analysis may include determining eddy covariance flux measurements of sub-surface potential carbon.

Abstract: In one embodiment, a photoacoustic effect measurement instrument for measuring a species (e.g., a species of PM) in a gas employs a pair of differential acoustic cells including a sample cell that receives sample gas including the species, and a reference cell that receives a filtered version of the sample gas from which the species has been substantially removed. An excitation light source provides an amplitude modulated beam to each of the acoustic cells. An array of multiple microphones is mounted to each of the differential acoustic cells, and measures an acoustic wave generated in the respective acoustic cell by absorption of light by sample gas therein to produce a respective signal. The microphones are isolated from sample gas internal to the acoustic cell by a film. A preamplifier determines a differential signal and a controller calculates concentration of the species based on the differential signal.

Abstract: This invention provides a coil and magnet assembly that is operatively interconnected with an oscillating free piston that moves along an axis. A coil mounting disk is operatively connected to a coil assembly. A magnet assembly is mounted on a magnet base. The magnet assembly is coaxial with respect to the coil assembly. The coil assembly and the magnet assembly are in oscillating motion with respect to each other in conjunction with oscillating motion of the free piston. A spring assembly comprising a plurality springs, symmetrically positioned about the axis, extend between the magnet base and the coil mounting disk, so as to move in conjunction with the oscillating motion along the axis. At least some of the springs are conductive and electrically connect the mounting disk to the magnet base. The piston can reside in a casing that is part of either a two-stroke engine or a fluid pump.

Abstract: In one embodiment, active (continuous or intermittent) passivation may be employed to prevent interaction of sticky molecules with interfaces inside of an instrument (e.g., an infrared absorption spectrometer) and thereby improve response time. A passivation species may be continuously or intermittently applied to an inlet of the instrument while a sample gas stream is being applied. The passivation species may have a highly polar functional group that strongly binds to either water or polar groups of the interfaces, and once bound presents a non-polar group to the gas phase in order to prevent further binding of polar molecules. The instrument may be actively used to detect the sticky molecules while the passivation species is being applied.

Abstract: In example embodiments, particle collection efficiency in aerosol analyzers and other particle measuring instruments is improved by a particle capture device that employs multiple collisions to decrease momentum of particles until the particles are collected (e.g., vaporized or come to rest). The particle collection device includes an aperture through which a focused particle beam enters. A collection enclosure is coupled to the aperture and has one or more internal surfaces against which particles of the focused beam collide. One or more features are employed in the collection enclosure to promote particles to collide multiple times within the enclosure, and thereby be vaporized or come to rest, rather than escape through the aperture.

Abstract: In one embodiment, an apparent equilibrium constant involving a clumped isotope in a gaseous sample is measured by acquiring sample spectra of portions of the gaseous sample at different pressures. An external bulb coupled to a sample cell is filled with the gaseous sample. A first portion of the gaseous sample is transferred from the external bulb to the sample cell, where it is at a first pressure. A first sample spectrum is obtained. Then, a second portion of the gaseous sample is transferred from the external bulb to the sample cell, where it is at a second, different pressure. A second sample spectrum is obtained. An apparent equilibrium constant for the clumped isotope is calculated by determining a first isotopic ratio at the first pressure, determining a second isotopic ratio at the second pressure, and taking a product of the first isotopic ratio and the second isotopic ratio.

Abstract: In one embodiment, an improved multi-pass cell for a long path-length spectrometer is designed to include a perturbing mirror that causes a base pattern of reflections to be repeated multiple times, where each subsequent base pattern of reflections is rotated about the axis at an angle from a prior base pattern, to circulate the base patters about the cell. The base pattern may be a Herriott cell pattern. The improved multi-pass cell may be constructed with a concave front mirror centered along an axis of the cell, and a concave back mirror centered along the axis and facing the front mirror. The perturbing mirror may be centered along the axis, facing the front mirror and located at a perturbing mirror spacing in front of the back mirror or behind the back mirror, depending on the implementation.

Abstract: In example embodiments, particle collection efficiency in aerosol analyzers and other particle measuring instruments is improved by a particle capture device that employs multiple collisions to decrease momentum of particles until the particles are collected (e.g., vaporized or come to rest). The particle collection device includes an aperture through which a focused particle beam enters. A collection enclosure is coupled to the aperture and has one or more internal surfaces against which particles of the focused beam collide. One or more features are employed in the collection enclosure to promote particles to collide multiple times within the enclosure, and thereby be vaporized or come to rest, rather than escape through the aperture.

Abstract: In one embodiment, a frequency generator produces an excitation signal, a local oscillator signal, and a reference signal at a difference frequency of the excitation signal and local oscillator signal. The excitation signal is applied to a physical system to produce a response signal, which is mixed with the local oscillator signal. A filter selects a difference frequency component. The frequencies of the excitation signal and/or local oscillator signal are varied, such that the magnitude of the difference frequency is constant, but a sign of the difference frequency changes from positive to negative. The phase shift of the difference frequency component, with respect to the reference signal, at each of the two signs of the difference frequency, is measured. The measured phase shift at the negative sign is subtracted from the measured phase shift at the positive sign, and the difference is divided in half, to produce a result.

Abstract: In one embodiment, a frequency generator produces an excitation signal, a local oscillator signal, and a reference signal at a difference frequency of the excitation signal and local oscillator signal. The excitation signal is applied to a physical system to produce a response signal, which is mixed with the local oscillator signal. A filter selects a difference frequency component. The frequencies of the excitation signal and/or local oscillator signal are varied, such that the magnitude of the difference frequency is constant, but a sign of the difference frequency changes from positive to negative. The phase shift of the difference frequency component, with respect to the reference signal, at each of the two signs of the difference frequency, is measured. The measured phase shift at the negative sign is subtracted from the measured phase shift at the positive sign, and the difference is divided in half, to produce a result.

Abstract: This invention overcomes the disadvantages of the prior art by providing a power generating system particularly suitable for field use in remote locations, which is fuel-efficient, relatively quiet, tolerant of dust, capable of operating on low-grade logistics and diesel-like fuels and capable of generating between 500 W and 2 KW of continuous electrical power. This generating system employs a two-cycle MICE generator having a piston that operates within a cylinder, and an interconnected, axially moving piston shaft that oscillates an alternator coil within a magnetic core. The piston shaft is attached to, and resisted by, the free end of a strong spring with a second, opposing end fixed to the MICE casing. To control operation of the MICE generator a clipper circuit is employed with a set threshold to resolve peaks and an adjustable harshness for applying load to the coil based upon an amps/volt harshness setting.

Abstract: This invention provides a system and method for balanced-demodulation procedures that remove image clutter even in the presence of scene motion. A system that employs balanced demodulation moves a chopping reticle located in the intermediate focal plane where front end optics focus a high-resolution image. The chopping reticle has a checkerboard pattern of clear and opaque cells and moves in an uneven rate (e.g. ?x??y) along the x-axis and y-axis. The resulting image is projected on a focal plane array from which differences are calculated to generate the desired balanced demodulation value. This invention further provides a foveal enhancement of the baseline spatial-modulation staring sensor. In this enhancement the WFOV low-resolution conventional image is displayed to the operator, but with a selectable subarea of that image replaced by a conventionally generated high-resolution image at the same scale.

Abstract: This invention overcomes the disadvantages of the prior art by providing a power generating system particularly suitable for field use in remote locations, which is fuel-efficient, relatively quiet, tolerant of dust, capable of operating on low grade logistics and diesel-like fuels and capable of generating between 500 W and 2 KW of continuous electrical power. This generator employs a miniature internal combustion engine/generator (MICE) having a piston moving within a cylinder arranged for two-cycle operation, and an interconnected, axially arranged piston shaft that oscillates an alternator coil within a magnetic core. The piston shaft is opposed by a strong, multiple-helix spring. The cylinder head, in which the piston operates, is cooled by moving (electrically pumped) fluid in a cooling head, or by another heat-transfer mechanism. The MICE generator's intake arrangement includes a preheater heated by a heated fluid flow thereon.

Abstract: This invention overcomes the disadvantages of the prior art by providing a power generating system particularly suitable for field use in remote locations, which is fuel-efficient, relatively quiet, tolerant of dust, capable of operating on low grade logistics and diesel-like fuels and capable of generating between 500 W and 2 KW of continuous electrical power. This generating system employs a two-cycle MICE generator having a piston that operates within a cylinder, and an interconnected, axially moving piston shaft that oscillates an alternator coil within a magnetic core. The piston shaft is attached to, and resisted by, the free end of a strong spring with a second, opposing end fixed to the MICE casing. To control operation of the MICE generator a dual clipper circuit is operatively connected with the alternator coil.

Abstract: This invention provides a system and method that enables the use of incoherent light sources, such as light emitting diodes, to provide for the detection of gaseous species which exhibit broadband absorption features (e.g., nitrogen dioxide and the halogen gases). The light emitting diode (LED) is an ideal light source for such an arrangement in that it can be modulated at high frequencies (allowing for omission of external modulation equipment) and provides sufficient illumination within a reasonably narrow wavelength band as compared to, for instance, an incandescent light source. A further advantage of a LED as a light source compared to alternatives such as a gas discharge or arc lamp is that the light output of the LED is highly stable, limited by the stability of the current source used to drive it. Use of a confocal or near-confocal resonant optical cavity maximizes coupling of the light source to the cavity.

Abstract: A non-contact, extractive sampling system and method is provided for measuring the exhaust gas composition and fine particle composition of exhaust emissions of various types of vehicles under actual operating conditions. A portion (or sample) of an exhaust plume of a vehicle is pulled or extracted through an extraction sampling tube, via a vacuum pump, to a remote trace gas detection system where the concentration of one or more constituents present in the sample of exhaust plume may be measured. In this regard, the invention enables vehicle emissions measurements to be made at a location remote from roadway, rather than using known, “cross-path” remote emissions sensing systems.

Abstract: This invention overcomes the disadvantages of the prior art by providing a power generating system particularly suitable for field use in remote locations, which is fuel-efficient, relatively quiet, tolerant of dust, capable of operating on low-grade logistics and diesel-like fuels and capable of generating between 500 W and 2 KW of continuous electrical power. This generating system employs a two-cycle MICE generator having a piston that operates within a cylinder, and an interconnected, axially moving piston shaft that oscillates an alternator coil within a magnetic core. The piston shaft is attached to, and resisted by, the free end of a strong spring with a second, opposing end fixed to the MICE casing. To control operation of the MICE generator a clipper circuit is employed with a set threshold to resolve peaks and an adjustable harshness for applying load to the coil based upon an amps/volt harshness setting.