Abstract: A security laminate (1) including in order a transparent oriented polyester support (2), a subbing layer (3) and an adhesive layer (4) which is coated on top of the subbing layer, wherein the binder of the adhesive layer is based on a mixture of a first and a second polymer in a weight ratio from 50/50 to 90/10, wherein the first polymer is a copolymer comprising vinyl acetate and at least 85 wt % of vinyl chloride based on the total weight of the first polymer; wherein the second polymer is a copolymer of styrene, butadiene and methylmethacrylate or a copolymer of vinyl butyral, vinyl acetate and vinyl alcohol; and wherein the binder of the subbing layer is based on a polyester-urethane copolymer.
Type:
Grant
Filed:
September 3, 2012
Date of Patent:
September 6, 2016
Assignee:
Agfa-Gevaert N.V.
Inventors:
Vera Drieghe, Peter Cantraine, Bart Waumans, Walther Wouters, Ingrid Geuens
Abstract: A color laser markable laminate includes at least a transparent polymeric support and a color forming layer including a leuco dye; an infrared dye; and a polymeric binder including vinyl acetate and at least 85 wt % of vinyl chloride based on the total weight of the binder; wherein the color laser markable laminate includes a specific phenol stabilizer sterically hindered by a ring containing three nitrogen atoms. A method for preparing a color laser marked document is also disclosed.
Type:
Grant
Filed:
March 12, 2013
Date of Patent:
August 2, 2016
Assignee:
AGFA-GEVAERT
Inventors:
Bart Waumans, Paul Callant, Johan Loccufier
Abstract: The present invention relates to a dispersion comprising metallic, metal oxide or metal precursor nanoparticles and a polymeric dispersant, the dispersant comprising an anchor group with affinity for the metallic, metal oxide or metal precursor nanoparticles that is chemically bonded to a polymeric backbone characterized in that the dispersant has a 95 wt. % decomposition at a temperature below 300° C. as measured by Thermal Gravimetric Analysis. It further relates to metallic fluids or inks prepared from the dispersion and to the preparation of the dispersion and the metallic fluid or inks.
Type:
Grant
Filed:
December 19, 2011
Date of Patent:
March 1, 2016
Assignee:
Agfa-Gevaert N.V.
Inventors:
Xavier André, Dirk Bollen, Johan Loccufier
Abstract: A dispersion includes metallic, metal oxide, or metal precursor nanoparticles; a thermally cleavable polymeric dispersant; an optional dispersion medium; and a thermally cleavable agent. Pastes, coated layers, and patterns may contain the dispersion. A method for producing the specific thermally cleavable dispersant and for producing the metallic nanoparticle dispersions. The dispersions allow the reduction or avoidance of organic residue in coated layers and patterns on substrates, the use substrates of low thermal resistance, and faster processing times.
Abstract: A dispersion includes metallic, metal oxide, or metal precursor nanoparticles; a thermally cleavable polymeric dispersant; an optional dispersion medium; and a thermally cleavable agent. Pastes, coated layers, and patterns may contain the dispersion. A method for producing the specific thermally cleavable dispersant and for producing the metallic nanoparticle dispersions. The dispersions allow the reduction or avoidance of organic residue in coated layers and patterns on substrates, the use substrates of low thermal resistance, and faster processing times.
Abstract: A method to prepare a metallic nanoparticle dispersion includes the steps of forming a metallic precursor dispersion or solution by adding a metallic precursor to a dispersion medium including: (a) a solvent according to Formula I, and wherein R1 and R2 represent an optionally substituted alkyl group, R1 and R2 may form a ring, (b) a carboxylic acid according to Formula II, R—COOH??Formula II wherein R is an optionally substituted C2-C7 alkyl, alkenyl or alkynyl group, reducing the metallic precursor with a reducing agent to form metallic nanoparticles, sedimenting the metallic nanoparticles to obtain a highly concentrated metallic nanoparticle dispersion comprising at least 15 wt % of metallic nanoparticles.
Type:
Application
Filed:
March 18, 2014
Publication date:
December 24, 2015
Applicant:
AGFA GEVAERT
Inventors:
Dirk BOLLEN, Nicolas VRIAMONT, Jaroslav KATONA
Abstract: A back sheet for a photovoltaic module includes a polymeric support and a weather resistant layer, the weather resistant layer including a binder containing a crosslinkable group and an aliphatic isocyanate crosslinking agent, characterized in that the weather resistant layer further includes an aromatic or an alicyclic isocyanate crosslinking agent, and wherein the molar ratio of the isocyanate groups of the aliphatic isocyanate crosslinking agents to the isocyanate groups of the aromatic and/or alicyclic crosslinking agents is ?3.
Type:
Application
Filed:
December 17, 2013
Publication date:
November 5, 2015
Applicant:
AGFA-GEVAERT
Inventors:
Frank VANGAEVER, Ijya SRIVASTAVA, Hubertus VAN AERT
Abstract: A method of producing a security document includes the steps of producing a first part of a colour image by colour laser marking a security document precursor; and producing a second part of the colour image by a second imaging technique different from laser marking. The resulting security document is more difficult to falsify.
Abstract: A radiation curable composition for preparing a polymeric membrane includes a) a membrane polymer selected from the group consisting of a polysulfone (PSU), a polyether sulfone (PES), a polyether etherketone (PEEK), a polyvinylchloride (PVC), a polyacrylonitrile (PAN), a polyvinylidene fluoride (PVDF), a polyimide (PI), a polyamide (PA) and copolymers thereof; b) a hydrophobic monomer or oligomer having at least two free radical polymerizable groups independently selected from the group consisting of an acrylate group, a methacrylate group, an acrylamide group, a methacrylamide group, a styrene group, a vinyl ether group, a vinyl ester group, a maleate group, a fumarate group, an itaconate group, and a maleimide group; and c) an organic solvent for the membrane polymer and the hydrophobic monomer. A polymeric membrane and a method for manufacturing the membrane are also disclosed.
Abstract: A set of laminates includes an outer laminate and an inner laminate, wherein the outer laminate includes a transparent polymeric support includinq on a first side of the support a colour laser markable layer containing an infrared dye having an absorption maximum ?max(IR-1) in the infrared region; wherein the inner laminate includes a transparent polymeric support including on, a first side of the transparent polymeric support, a colour laser markable layer containing an infrared dye having an absorption maximum ?max(IR-2) in the infrared region and, on a second side of the transparent polymeric support, a colour laser markable layer containing an infrared dye having an absorption maximum ?max(IR-3) in the infrared region; and the conditions a) and b) are satisfied: ?max(IR-1)>?max(IR-2)>?max(IR-3); and??a) ?max(IR-1)>1100 nm and ?max(IR-3)<1000 nm.
Type:
Application
Filed:
October 10, 2013
Publication date:
October 1, 2015
Applicant:
AGFA-GEVAERT
Inventors:
Bart Waumans, Paul Callant, Ingrid Geuens, Bart Aerts
Abstract: A radiation curable ink includes a) a monomer including at least one vinyl ether group and at least one (meth)acrylate group; b) a monomer including a five membered cyclic anhydride; and c) an aliphatic tertiary amine. The radiation curable ink allows stable inkjet printing on solder masks exhibiting good adhesion and high scratch resistance after curing.
Abstract: A security film including, in order, a transparent biaxially oriented polyethylene terephthalate support (1), a subbing layer (2, 2?) and a laser markable layer (3, 3?) comprising a laser additive and one or more polymers selected from the group consisting of polystyrene, polycarbonate and styrene acrylonitrile.
Type:
Grant
Filed:
December 17, 2010
Date of Patent:
June 30, 2015
Assignee:
Agfa-Gevaert N.V.
Inventors:
Carlo Uyttendaele, Bart Aerts, Bart Waumans, Ingrid Geuens
Abstract: A method of color laser marking a security document precursor including at least: a transparent biaxially stretched polyethylene terephthalate foil; at least one colorless color forming layer for generating a color different from black containing at least an infrared absorber a color forming compound and a polymeric binder; and a laser markable polymeric support or a laser markable layer for generating a black color; comprising the steps of: laser marking the colorless color forming layer through the transparent polymeric foil with a infrared laser used in continuous wave mode to generate a color different from black; and laser marking the laser markable polymeric support or the laser markable layer through the transparent polymeric foil with the same infrared laser but used in a pulsed mode to generate a black color.
Type:
Grant
Filed:
September 4, 2012
Date of Patent:
June 30, 2015
Assignee:
Agfa-Gevaert N.V.
Inventors:
Bart Waumans, Paul Callant, Ingrid Geuens
Abstract: A security film including a support (1) and a laser markable layer (3), wherein the laser markable layer includes i) a laser additive; ii) a polymer selected from the group consisting of polystyrene, polycarbonate and styrene acrylonitrile; iii) an initiator; and iv) at least 15 wt % of radiation curable compound based on the total dry weight of the laser markable layer, wherein the radiation curable compound has a viscosity of less than 100 mPa·s at 25° C. and at a shear rate of 100 s?1. A security document and a method for preparing the security film are also disclosed.
Type:
Grant
Filed:
December 17, 2010
Date of Patent:
April 21, 2015
Assignee:
Agfa-Gevaert N.V.
Inventors:
Carlo Uyttendaele, Bart Aerts, Bart Waumans, Ingrid Geuens
Abstract: A security document precursor including, in order, at least: a) a transparent biaxially stretched polyethylene terephthalate foil; b) a colorless color forming layer containing at least an infrared absorber, a color forming component and a polymeric binder; and c) a polymeric support; wherein the colorless color forming layer contains at least one component forming a compound having a melting temperature of less than 20° C. upon laser marking the colorless color forming layer with an infrared laser. Methods for securing a security document using the security document precursor are also disclosed.
Type:
Grant
Filed:
December 2, 2011
Date of Patent:
March 10, 2015
Assignee:
Agfa-Gevaert N.V.
Inventors:
Bart Waumans, Ingrid Geuens, Paul Callant, Hubertus Van Aert
Abstract: Disclosed is a printable paper comprising a water-resistant support having two optionally subbed sides and a single layer on at least one of said optionally subbed sides, wherein said single layer has no substantial compositional variation, has a layer thickness of at least 3 ?m, a pore volume of at least 1.2 mL/m2 and comprises at least one porous pigment. Also disclosed is a process for producing such a printable paper and use thereof in printing.
Abstract: A method of preparing a security laminate including the steps of: a) providing a polyethylene terephthalate substrate (1); b) stretching the polyethylene terephthalate substrate in either a longitudinal or a transversal direction; c) coating and drying a first coating composition (2) on the stretched polyethylene terephthalate substrate; d) stretching the coated polyethylene terephthalate substrate in the longitudinal or transversal direction not selected in step b) in order to obtain a coated biaxially stretched polyethylene terephthalate substrate having a layer of the first coating composition with a dry thickness between 50 nm and 400 nm; e) coating and drying a second coating composition (3) on top of the dry layer on the biaxially stretched substrate, wherein the first coating composition contains a copolymer selected from the group consisting of a hydroxyl—functional, partially-hydrolyzed vinyl chloride/vinyl acetate copolymer and a polyester-urethane copolymer; and wherein the second coating compositi
Type:
Grant
Filed:
March 28, 2011
Date of Patent:
March 10, 2015
Assignee:
Agfa-Gevaert N.V.
Inventors:
Ingrid Geuens, Bart Waumans, Vera Drieghe
Abstract: The invention relates to an assembly of a porous metallic gas diffusion substrate and a polymeric separator membrane for use in an alkaline electrolyser or alkaline fuel cell. The polymeric separator membrane of the assembly comprises inorganic hydrophilic particulates dispersed in an organic polymeric binder. The polymeric separator membrane is gas tight when filled with electrolyte. The polymeric separator membrane is penetrating into at least a top portion of the porous metallic gas diffusion substrate. Also disclosed is a method to produce such an assembly via coating a paste on a porous metallic gas diffusion substrate.
Type:
Application
Filed:
March 11, 2013
Publication date:
March 5, 2015
Applicants:
NV BEKAERT SA, AGFA-GEVAERT NV
Inventors:
Erik Dekempeneer, Inge Schildermans, Johan Vanbrabant, Bo Hong, Luc Vanmaele, Guido Desie, Willem Mues
Abstract: A dispersion includes metallic, metal oxide, or metal precursor nanoparticles; a thermally cleavable polymeric dispersant an optional dispersion medium; and a thermally cleavable agent. Pastes, coated layers, and patterns may contain the dispersion. A method for producing the specific thermally cleavable dispersant and for producing the metallic nanoparticle dispersions. The dispersions allow the reduction or avoidance of organic residue in coated layers and patterns on substrates, the use substrates of low thermal resistance, and faster processing times.
Abstract: A method for preparing a color laser marked article comprising the steps of: a) infrared laser marking a security element including a polymeric support and a color forming layer comprising a color forming compound, an infrared dye and a polymeric binder comprising vinyl acetate and at least 85 wt % of vinyl chloride based on the total weight of the binder; and b) exposing the laser marked security element with light having a wavelength higher than 440 nm. The light exposure of step b) hinders the falsification of an issued security document without significant increase of background density.