Abstract: An intermediate for preparing (meth)acrylated photoinitiators according to Formula (I): wherein: R1 is selected from the group consisting of hydrogen and a methyl group; A represents a group including at least one photoinitiating moiety; L represents a n+o-valent linking group including at least one carbon atom; n and o each independently represent an integer from 1 to 4; p is equal to 0 or 1; X represents a group selected from the group consisting of Cl, Br, I, and R2SO3; and R2 represents an optionally substituted group selected from the group consisting of an alkyl group, an alkenyl group, an alkynyl group, an alkaryl group-, an aralkyl group, an aryl group and a heteroaryl group. Also, a method for the preparation of (meth)acrylated photoinitiators by ?-elimination of HX from the intermediate according to Formula (I).
Abstract: A liquid radiation curable composition for inkjet printing includes a photoinitiating system consisting of one or more diffusion hindered photoinitiators selected from the group consisting of non-polymeric di- or multifunctional initiators, oligomeric or polymeric initiators, and polymerizable initiators, and one or more polymerizable co-initiators, wherein at least one of the polymerizable co-initiators is a polymerizable aromatic tertiary amine. Inkjet inks, an inkjet printing process, and packaging materials may include the liquid radiation curable composition.
Abstract: An inkjet printing method includes the steps of a) providing a white inkjet ink and at least one colour inkjet ink to an inkjet printer; and b) jetting the white inkjet ink at a higher temperature than the colour inkjet ink onto an ink-receiver. The difference in jetting temperature between the white inkjet ink and the colour inkjet ink is at least 5° C. Inkjet ink sets and inkjet printers are also disclosed.
Abstract: A print head mounting assembly and a method of mounting and positioning a print head on a print head carriage framework suitable for mounting in a printing system includes a print head positioning device for receiving a print head, and a print head mounting tile having a mounting surface for mounting the print head positioning device. The print head mounting tile is adjustably mounted on the print head carriage framework such that it provides a mounting surface for the print head positioning device that is level with a reference printing surface, when the print head carriage framework is mounted in the printing system. The print head positioning device is adjustably mounted on the print head mounting tile such that the print head, being received in the print head positioning device, is accurately positioned on the mounting surface of the print head mounting tile.
Type:
Grant
Filed:
May 30, 2006
Date of Patent:
November 23, 2010
Assignee:
Agfa Graphics NV
Inventors:
Werner Van De Wynckel, Albert Brals, Bart Verhoest, Bartholomeus Verlinden
Abstract: A receiver table (1) is provided for holding a receiver in a digital printer using a shuttle (2) carrying the printheads (3), e.g. an ink-jet printer, which is divided in small table segments (5) of which height and orientation can be adjusted. By adjusting the segments (5) the table (1) can be deformed to obtain a constant receiver-printhead distance even if the guidance of the shuttle (2) has deviations or exhibits bending during shuttling. Table segments (5) are preferably mounted on a deformable table support (13). The receiver-printhead “throw distance” can be calibrated by measuring the distance profile and adjusting adjustments screws or bolts to align the table segments (5) to the ideal printing distance.
Type:
Grant
Filed:
May 5, 2006
Date of Patent:
November 23, 2010
Assignee:
Agfa Graphics NV
Inventors:
Bart Verhoest, Luciaan De Coux, Dirk De Ruijter
Abstract: The present invention provides new intermediate compounds enabling the preparation of N-meso substituted cyanine, merocyanine or oxonole dyes wherein the N-meso substituent comprises electron withdrawing groups and wherein such N-meso substituents are introduced at the intermediate level. These intermediates enable the formation of dyes having in the meso-position N-substituents comprising electron withdrawing groups without the need for further derivatization of the meso-substituent at the dye level.
Abstract: A Naphthol AS colorant according to Formula (I): wherein R1, R2, R3, R4 and R5 are each independently selected from the group consisting of hydrogen, methyl, ethyl, halogen, methoxy, ethoxy, —CONH-phenyl and —NO2, wherein the group Q is a group including two carboxyl groups or salts thereof. The Naphthol AS colorant may also be used for making colored layers and non-aqueous pigment dispersions.
Abstract: A monomer with a chromophore group represented by Formula (I): wherein AR1 represents a substituted or unsubstituted aromatic group; AR2 represents a substituted or unsubstituted aromatic group or a substituted or unsubstituted alkyl group; and R represents a substituted or unsubstituted alkyl group, with the proviso that one of R, AR1, and AR2 has a substituent with a polymerizable functional group. The monomer can be advantageously used to prepare polymeric dispersants for pigment dispersion, especially inkjet inks.
Type:
Grant
Filed:
July 4, 2006
Date of Patent:
October 12, 2010
Assignee:
Agfa Graphics NV
Inventors:
Geert Deroover, Wojciech Jaunky, Lambertus Groenendaal, Johan Loccufier
Abstract: A flatbed printing machine is provided with a printing table and a pressing device for a medium to be printed. The pressing device features parallel guide rails on both sides of the printing table, through which a pressing rail that is moveable above the printing table is guided. The pressing device is particularly applicable to a digital ink-jet flatbed printing machines.
Type:
Grant
Filed:
May 25, 2006
Date of Patent:
October 12, 2010
Assignee:
Agfa Graphics NV
Inventors:
Stefan Holzer, Markus Hilpert, Konrad Vosteen
Abstract: The method of preparing a lithographic printing plate precursor according to the present invention comprises the steps of: providing an aluminum support; graining and anodizing the aluminum support; without applying a hydrophilic layer on the anodized aluminum support, coating a composition which is photopolymerizable upon absorption of light having a wavelength in the range of from 350 nm to 450 nm and comprising a polymerizable monomer or oligomer, a binder and a photo-initiator on the grained and anodized aluminum support to form a photopolymerizable layer; coating an overcoat on the photopolymerizable layer; characterized in that the ratio of the total solid amount of polymerizable monomer and oligomer to the total solid amount of binder is from 1.0 to 2.0.
Type:
Application
Filed:
December 17, 2008
Publication date:
September 30, 2010
Applicant:
AGFA GRAPHICS NV
Inventors:
Veerle Verschueren, Peter Hendrikx, Willi-Kurt Gries, Marc Van Damme
Abstract: A printing table for a flatbed printing machine, for example, a large format digital flatbed printing machine, has a printing table base and a printing table plate disposed on the printing table base. The printing table base is connected by several connecting elements to the printing table plate. The connecting elements permit movement of the printing table plate relative to the printing table base, in particular movement caused by thermal expansion, only in a direction parallel to the printing table surface and only proceeding from a certain area of the printing table plate, the area having a point or line form and being fixed relative to the printing table base.
Abstract: A method for making a lithographic printing plate is disclosed which comprises the steps of: (1) providing a heat-sensitive lithographic printing plate precursor comprising on a support having a hydrophilic surface or which is provided with a hydrophilic layer, a heat-sensitive coating, (2) image-wise exposing said precursor with IR-radiation or heat, and (3) developing said image-wise exposed precursor with an alkaline developing solution, characterised in that a sludge inhibiting agent is present in said precursor or in said developing solution or in said precursor and said developing solution, and wherein said sludge inhibiting agent is a triazaindolisine compound. According to the above method, the formation of sludge is inhibited or reduced.
Type:
Application
Filed:
August 13, 2008
Publication date:
September 9, 2010
Applicant:
Agfa Graphics NV
Inventors:
Johan Loccufier, Stefaan Lingier, Mark Lens
Abstract: A heat-sensitive imaging element includes an IR dye having a structure according to Formula I, wherein at least one of the Rd groups is a group which is transformed by a chemical reaction, induced by exposure to IR-radiation or heat, into a group which is a stronger electron-donor than the Rd; or wherein at least one of the Ra groups is a group which is transformed by a chemical reaction, induced by exposure to IR-radiation or heat, into a group which is a stronger electron-acceptor than the Ra. The imaging element is able to form a visible print-out image with a high contrast directly after image-wise exposure by IR-radiation or heating.
Type:
Application
Filed:
June 19, 2006
Publication date:
September 2, 2010
Applicant:
AGFA GRAPHICS NV
Inventors:
Paul Callant, Hieronymus Andriessen, Alex Williamson, Christel Geukens, Jos Louwet
Abstract: A method of making a lithographic printing plate comprising the steps of: a) providing a lithographic printing plate precursor comprising a support having a hydrophilic surface or which is provided with a hydrophilic layer, and a coating provided thereon, said coating comprising (i) a contiguous photopolymerisable layer having a photopolymerisable composition, or (ii) a contiguous intermediate layer and thereon a photopolymerisable layer having a photopolymerisable composition, wherein said photopolymerisable composition comprises a polymerisable compound, a polymerization initiator and a first polymer, b) image-wise exposing said coating, c) optionally, heating the precursor, d) developing the precursor by treating the coating of the precursor with a gum solution or by mounting the exposed precursor on a plate cylinder of a lithographic printing press and rotating the plate cylinder while feeding dampening liquid and/or ink to the coating, wherein said contiguous photopolymerisable or intermediate layer furt
Type:
Application
Filed:
November 13, 2008
Publication date:
August 19, 2010
Applicant:
AGFA GRAPHICS NV
Inventors:
Alexander Williamson, Christel Geukens, Hubertus Van Aert, Kristof Heylen
Abstract: A method of making a flexographic printing forme includes the steps of: (1) providing a flexographic support; (2) applying a powder layer on said the support; (3) imagewise jetting a curable composition on the powder layer; (4) at least partially curing the jetted curable composition; (5) repeating steps (2) to (4) until the total thickness of the powder layers is greater than 100 ?m; (6) removal of the powder not embedded in the imagewise jetted and at least partially cured composition; and (7) optionally overall post curing.
Abstract: A method for developing a printing plate precursor comprising the step of immersing the precursor in an aqueous alkaline developing solution comprising a (co) polymer comprising a monomeric unit which is represented by the following formula (I): wherein L is a linking group; R1, R2 and R3 independently represent hydrogen or an alkyl group; R4 represents an optionally substituted hydroxyaryl group; x=0 or 1; y=0 or 1 and when y=0 then x=1 and L is further bound to C* to form a cyclic structure.
Type:
Application
Filed:
August 19, 2008
Publication date:
August 12, 2010
Applicant:
Agfa Graphics NV
Inventors:
Hubertus Van Aert, Pascal Meeus, Stefaan Lingier
Abstract: A method of making a flexographic printing sleeve forme includes the steps of forming a sleeve body by providing one or more at least partially cured uniform layers on a sleeve carrier; forming a relief image on the sleeve body by imagewise jetting a curable jetting fluid; and optionally overall post-curing; characterized in that between formation of the sleeve body and formation of the relief image no polishing or grinding is performed.
Abstract: A method of making a lithographic printing plate comprising the steps of: a) providing a lithographic printing plate precursor comprising (i) a support having a hydrophilic surface or which is provided with a hydrophilic layer, (ii) a photopolymerizable coating on said support, b) image-wise exposing said coating in a plate setter, c) developing the precursor, thereby removing the non-exposed areas of the coating from the support, whereby the developing step is carried out off-press in a gumming unit by treating the coating of the precursor with a gum solution.
Type:
Grant
Filed:
May 18, 2005
Date of Patent:
August 3, 2010
Assignee:
Agfa Graphics NV
Inventors:
Marc Van Damme, Joan Vermmersch, Alexander Williamson, Willi-Kurt Gries
Abstract: A method for making a heat-sensitive negative-working lithographic printing plate precursor including the steps of providing a support having a hydrophilic surface or which is provided with a hydrophilic layer, and applying onto the support a coating solution including an infrared absorbing agent, hydrophobic thermoplastic polymer particles, a hydrophilic binder, and a polymer including siloxane and/or perfluoroalkyl monomeric units.
Abstract: A lithographic printing plate precursor comprising an image-recording layer, said image-recording layer being photopolymerizable upon exposure to light having a wavelength of from 300 to 500 nm and containing a mixture of sensitizers.
Type:
Application
Filed:
May 15, 2008
Publication date:
July 29, 2010
Applicant:
Agfa Graphics NV
Inventors:
Jan Venneman, Peter Hendrikx, Paul Callant, Alexander Williamson