Patents Assigned to Air Liquide Advanced Technologies U.S. LLC
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Patent number: 10525399Abstract: A composite fiber comprising sorbent particles (at 50 wt %) in a polymeric matrix that comprises a polymer or blend of polymers including at least one thermoplastic polymer, the extrudates being produced by thermal-induced phase separation or diffusion-induced phase separation from a dope suspension of the thermoplastic polymer, an optional solvent and the sorbent particles. The polymer or blend of polymers is able to withstand exposure to temperatures at or above 220° C. without experiencing significant detrimental effects upon the sorbent capacity of the sorbent particles. The fiber exhibits an elongation at break of at least 5%.Type: GrantFiled: December 29, 2017Date of Patent: January 7, 2020Assignees: L'Air Liquide Societe Anonyme Pour L'Etude Et L'Exploitation Des Procedes Georges Claude, Air Liquide Advanced Technologies U.S. LLCInventors: Philippe A. Coignet, Dean W. Kratzer, Sudhir S. Kulkarni, Edgar S. Sanders, Jr.
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Publication number: 20190381450Abstract: Disclosed is a method for producing a liquid hydrocarbon comprising dividing a feed gas into a first feed gas stream and a second feed gas stream, separating the first feed gas stream through a membrane separation unit into an acid gas-enriched permeate gas stream and a biphasic non-permeate stream of acid gas-reduced hydrocarbon-enriched gas and liquid, separating the biphasic non-permeate stream of acid gas-reduced hydrocarbon-enriched gas and liquid into a first liquid hydrocarbon stream and an acid gas-depleted methane-rich gas stream, expanding the second feed gas stream to produce a hydrocarbon gas stream containing the acid gas in equilibrium with a second liquid hydrocarbon stream with an expander, commingling the first liquid hydrocarbon stream with the second liquid hydrocarbon stream to produce the liquid hydrocarbons product, commingling the acid gas-enriched permeate gas stream with the hydrocarbon gas stream containing the acid gas and collecting the acid gas-depleted methane-rich gas stream.Type: ApplicationFiled: June 19, 2018Publication date: December 19, 2019Applicants: L'Air Liquide, Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges Claude, AIR LIQUIDE ADVANCED TECHNOLOGIES U.S. LLCInventors: Fan Z. WORLEY, Edgar S. Sanders, JR.
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Publication number: 20190321780Abstract: Nitrogen is removed from biogas using a three-stage separation system based on gas separation membranes. The first stage separates a biomethane feed stream into a first permeate gas stream and a first retentate gas stream. The second stage separates the first permeate stream into a biomethane product gas and a first low quality biomethane gas stream. The third stage separates the first retentate into a second low quality biomethane gas stream and a waste gas. A biogas feed stream is pretreated to remove amounts of water, VOCs, and CO2 to yield a methane-enriched biogas stream. The methane-enriched biogas stream is compressed together with the first and second low quality biomethane gas streams to form the biomethane feed stream.Type: ApplicationFiled: April 23, 2018Publication date: October 24, 2019Applicant: Air Liquide Advanced Technologies U.S. LLCInventors: Benjamin BIKSON, Yong DING, Michael J. MITARITEN
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Patent number: 10450522Abstract: Biogas containing H2S and CO2 is upgraded by removing H2S using PTSA and CO2 using two stages of gas separation membranes. The first stage permeate may optionally be used a regeneration gas stream. The second stage permeate may optionally be used a cool down gas stream. The PTSA unit includes two or more adsorbent beds each selective for water, VOCs, and H2S over CO2 and for H2S over methane.Type: GrantFiled: December 3, 2018Date of Patent: October 22, 2019Assignee: Air Liquide Advanced Technologies U.S. LLCInventor: Michael J. Mitariten
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Publication number: 20190271439Abstract: A mobile dispenser may be used to at least partially fill hydrogen tanks of fuel cell-powered vehicles. The dispenser uses a purely mechanical control of the fill using an orifice plate across which a pressure differential is maintained through use of a backpressure regulator whose reference pressure is controlled by a differential pressure regulator. Because it does need or use electrical power, it may be used in situations where no electrical power is available or convenient.Type: ApplicationFiled: March 1, 2019Publication date: September 5, 2019Applicant: Air Liquide Advanced Technologies U.S. LLCInventors: Jorge E. LOPEZ, Aaron HARRIS, Chad NICKELL, Gerhard M. SCHMIDT, Owen C. OWENS, Per OLSSON
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Publication number: 20190224617Abstract: The invention relates to a process for recovering methane from digester biogas or landfill gas. More specifically, the invention pertains to biomethane production that substantially removes carbon dioxide from a digester biogas or landfill gas using first, second, and third purification stages each comprising one or more membranes selective for carbon dioxide over methane. A retentate from the first stage is separated by the one more membranes of the second stage into a second state retentate, forming a biomethane product gas. A permeate from the first stage is separated by the one or more membranes of the third stage into a third stage retentate and a third stage permeate. Recovery of methane from the biogas is boosted by feeding the third stage retentate to the first purification stage. The recovery may be optionally further boosted by compressing the second stage permeate with the biogas at a main compressor.Type: ApplicationFiled: January 24, 2018Publication date: July 25, 2019Applicant: AIR LIQUIDE ADVANCED TECHNOLOGIES U.S. LLCInventor: Michael J. MITARITEN
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Publication number: 20190201838Abstract: Helium-containing natural gas is processed with three gas separation stages to produce a natural gas product and a Helium-containing gas that may be injected into the reservoir from which the Helium-containing natural gas is obtained. A permeate from the first gas separation membrane stage is compressed and fed to the second gas membrane stage. The permeate from the second gas separation membrane stage is recovered as the Helium-containing gas that may be injected into the reservoir. The non-permeate from the second gas separation membrane stage is fed to the third gas separation membrane stage. The non-permeate from the first gas separation stage is a natural gas product. A permeate from the third gas separation membrane stage is combined with a non-permeate from the first gas separation membrane stage before it is compressed and fed to the second gas separation membrane stage.Type: ApplicationFiled: December 21, 2018Publication date: July 4, 2019Applicant: Air Liquide Advanced Technologies U.S. LLCInventor: Benjamin BIKSON
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Publication number: 20190184341Abstract: The invention is directed to preparation of hollow fiber membrane devices that exhibit improved durability and mechanical strength in air separation operations such as generation of nitrogen enriched air on board aircraft. In particular the invention provides for preparation of hollow fiber membrane modules with terminal tubesheets of superior mechanical properties and improved long term durability in air separation operations.Type: ApplicationFiled: December 18, 2018Publication date: June 20, 2019Applicants: L'Air Liquide, Societe Anonyme Pour I' Etude et I' Exploitation des Procedes Georges Claude, Air Liquide Advanced Technologies U.S, LLCInventors: Moutushi Dey, Matthew Metz, James Macheras, Benjamin Bikson, Tao Li
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Publication number: 20190169517Abstract: Biogas containing H2S and CO2 is upgraded by removing H2S using PTSA and CO2 using two stages of gas separation membranes. The first stage permeate may optionally be used a regeneration gas stream. The second stage permeate may optionally be used a cool down gas stream. The PTSA unit includes two or more adsorbent beds each selective for water, VOCs, and H2S over CO2 and for H2S over methane.Type: ApplicationFiled: December 3, 2018Publication date: June 6, 2019Applicant: Air Liquide Advanced Technologies U.S. LLCInventor: Michael J. MITARITEN
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Publication number: 20190060835Abstract: A feed fluid mixture including at least one condensable component and at least one non-condensable component is separated into a gaseous permeate and an at least partially liquid retentate with a gas separation membrane through simultaneous condensation of at least one of said at least one condensable component on a retentate side of the membrane and permeation of at least one of said at least one non-condensable component through the membrane.Type: ApplicationFiled: August 28, 2018Publication date: February 28, 2019Applicant: Air Liquide Advanced Technologies U.S. LLCInventors: Yong Ding, Benjamin Bikson
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Publication number: 20190030482Abstract: The invention relates to a process for recovering methane from digester biogas or landfill gas. More specifically, the invention pertains to a method for producing biomethane that removes impurities from a compressed digester biogas with staged membrane modules of at least two different types, to produce a biomethane having at least 94% CH4, below 3% of CO2, and below 4 ppm of H2S.Type: ApplicationFiled: September 21, 2017Publication date: January 31, 2019Applicant: Air Liquide Advanced Technologies, U.S. LLCInventors: Yong DING, Michael J. Mitariten
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Patent number: 10179883Abstract: Biogas containing H2S and CO2 is upgraded by removing H2S using PTSA and CO2 using two stages of gas separation membranes. The first stage permeate may optionally be used a regeneration gas stream. The second stage permeate may optionally be used a cool down gas stream. The PTSA unit includes two or more adsorbent beds each selective for water, VOCs, and H2S over CO2 and for H2S over methane.Type: GrantFiled: February 2, 2018Date of Patent: January 15, 2019Assignee: Air Liquide Advanced Technologies U.S. LLCInventor: Michael J. Mitariten
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Publication number: 20180361310Abstract: Natural gas may be purified by removing C3+ hydrocarbons and CO2 in respective first and second gas separation membrane stages to yield conditioned gas lower in C3+ hydrocarbons and CO2 in comparison to the un-conditioned natural gas.Type: ApplicationFiled: August 22, 2018Publication date: December 20, 2018Applicant: Air Liquide Advanced Technologies, U.S. LLCInventors: Sandeep K. KARODE, Yong DING
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Patent number: 10143961Abstract: Natural gas may be purified by removing C3+ hydrocarbons and CO2 in respective first and second gas separation membrane stages to yield conditioned gas lower in C3+ hydrocarbons and CO2 in comparison to the un-conditioned natural gas.Type: GrantFiled: December 2, 2016Date of Patent: December 4, 2018Assignee: Air Liquide Advanced Technologies U.S. LLCInventors: Sandeep K. Karode, Yong Ding
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Publication number: 20180296967Abstract: A plurality of extrudates comprises sorbent particles (at 50 wt %) in a polymeric matrix that comprises a polymer or blend of polymers including at least one thermoplastic polymer, the extrudates being produced by thermal-induced phase separation or diffusion-induced phase separation from a dope suspension of the thermoplastic polymer, an optional solvent and the sorbent particles. The polymer or blend of polymers is able to withstand exposure to temperatures at or above 220° C. without experiencing significant detrimental effects upon the sorbent capacity of the sorbent particles.Type: ApplicationFiled: December 29, 2017Publication date: October 18, 2018Applicants: L'Air Liquide, Societe Anonyme Pour l'Etude et l'Exploitation des Procedes Georges Claude, AIR LIQUIDE ADVANCED TECHNOLOGIES U.S. LLCInventors: Philippe A. Coignet, Dean W. Kratzer, Sudhir S. Kulkarni, Edgar S. Sanders, JR.
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Publication number: 20180296966Abstract: A composite fiber comprising sorbent particles (at 50 wt %) in a polymeric matrix that comprises a polymer or blend of polymers including at least one thermoplastic polymer, the extrudates being produced by thermal-induced phase separation or diffusion-induced phase separation from a dope suspension of the thermoplastic polymer, an optional solvent and the sorbent particles. The polymer or blend of polymers is able to withstand exposure to temperatures at or above 220° C. without experiencing significant detrimental effects upon the sorbent capacity of the sorbent particles. The fiber exhibits an elongation at break of at least 5%.Type: ApplicationFiled: December 29, 2017Publication date: October 18, 2018Applicants: AIR LIQUIDE ADVANCED TECHNOLOGIES U.S. LLC.Inventors: Philippe A. Coignet, Dean W. Kratzer, Sudhir S. Kulkarni, Edgar S. Sanders, JR.
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Publication number: 20180223205Abstract: Biogas containing H2S and CO2 is upgraded by removing H2S using PTSA and CO2 using two stages of gas separation membranes. The first stage permeate may optionally be used a regeneration gas stream. The second stage permeate may optionally be used a cool down gas stream. The PTSA unit includes two or more adsorbent beds each selective for water, VOCs, and H2S over CO2 and for H2S over methane.Type: ApplicationFiled: February 2, 2018Publication date: August 9, 2018Applicant: AIR LIQUIDE ADVANCED TECHNOLOGIES U.S. LLCInventor: Michael J. MITARITEN
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Publication number: 20180161732Abstract: One or more polymeric hollow fiber membranes are pyrolyzed to form one or more hollow fiber CMS membranes by directing a flow of pyrolysis gas through a polymeric membrane cartridge (including a porous center tube around which one or more green, polymeric, hollow fiber membranes is arranged) or a bundle of polymeric membranes (including a plurality of green, polymeric hollow fiber membranes oriented so that their ends are disposed with ends of the bundle) in a direction perpendicular to a length direction of the cartridge or bundle in order to sweep away off-gases that are formed during pyrolysis.Type: ApplicationFiled: December 14, 2017Publication date: June 14, 2018Applicants: L'Air Liquide, Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges Claude, Air Liquide Advanced Technologies U.S. LLCInventors: Philippe A. COIGNET, Dean W. KRATZER, Raja SWAIDAN, Edgar S. SANDERS, JR.
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Patent number: 9962659Abstract: A gas separation membrane module includes a seal between a higher pressure gas and a lower pressure gas. The seal includes a compressible sealing member in between sealing surfaces. At least one of the sealing surfaces has corrosion-resistant cladding provided over either low alloy steel or high alloy steel. The cladding reduce the possibility of a seal failure due to corrosion of low alloy or high alloy steel exposed to acid gases or condensed moisture containing acid gases dissolved therein while at the same not requiring that all surfaces of the membrane module exposed to acid gases be provided with cladding.Type: GrantFiled: June 28, 2016Date of Patent: May 8, 2018Assignees: AIR LIQUIDE ADVANCED TECHNOLOGIES U.S. LLC, L'AIR LIQUIDE SOCIETE ANONYME POUR L'ETUDE ET L'EXPLOITATION DES PROCEDES GEORGES CLAUDE, SAUDI ARABIAN OIL COMPANYInventors: Sudhir S. Kulkarni, Karl S. Beers, Jean-Pierre R. Ballaguet, Milind M. Vaidya, Sebastien A. Duval
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Patent number: 9737857Abstract: Parallel membrane elements are arranged in parallel within a pressure vessel. A sealing body is disposed within the pressure vessel and is compressed against an inner surface of the pressure vessel to provide a leak-right seal in between a feed gas side of the sealing body and a non-permeate side of the sealing body. The sealing body may be slid within the pressure vessel without damaging the sealing body and in all cases without requiring mechanical assistance.Type: GrantFiled: January 20, 2017Date of Patent: August 22, 2017Assignee: AIR LIQUIDE ADVANCED TECHNOLOGIES U.S. LLCInventors: Sandeep K. Karode, Karl S. Beers