Patents Assigned to Air Liquide Global E&C Solutions Germany GmbH
  • Patent number: 10131542
    Abstract: Embodiments of the invention include a method for degassing liquid sulphur in a container, a first area of the container being flooded with liquid sulphur and a second area of the container being flooded with a gas, and a gas flow being injected into the first area, wherein liquid sulphur is sprayed into the second area. Embodiments of the invention include a device for degassing liquid sulphur having a container comprising two adjacent areas, the first area being flooded with liquid sulphur and the second area being flooded with gas, and having at least one device for injecting a gas flow into the first area, characterized by a device for spraying liquid sulphur opening into the second area. Other embodiments are also included herein.
    Type: Grant
    Filed: November 5, 2012
    Date of Patent: November 20, 2018
    Assignees: Air Liquide Global E&C Solutions Germany GmbH, NGD Consult
    Inventors: Jean Nougayrede, Wolfgang Nehb, Eckhard Juengst
  • Patent number: 9758291
    Abstract: A port arrangement is configured for accessing a demountable component in an interior of an apparatus or container. The port arrangement includes an inner port having a port tube and forming a releasable connection with an internal component. The port tube of the inner port is guided through an outer port that is to an outer jacket.
    Type: Grant
    Filed: November 18, 2010
    Date of Patent: September 12, 2017
    Assignee: AIR LIQUIDE GLOBAL E&C SOLUTIONS GERMANY GMBH
    Inventors: Peter Weigand, Gunter Quass, Jens von Waaden
  • Patent number: 9643843
    Abstract: A method for reforming hydrocarbon-containing feed gas into synthesis gas, involving processing of the feed gas by pre-reforming at least partially converting one or more higher hydrocarbons into methane, and heating the feed gas by exothermic catalytic partial oxidation of hydrocarbons before the introduction thereof into the main reforming zone, and, subsequent to the pre-reforming, reforming the pre-reformed product with the addition of a controlled quantity of an oxidizing agent.
    Type: Grant
    Filed: June 8, 2012
    Date of Patent: May 9, 2017
    Assignee: AIR LIQUIDE GLOBAL E&C SOLUTIONS GERMANY GMBH
    Inventors: Rainer Morgenroth, Andreas Bormann
  • Patent number: 9567549
    Abstract: A process for deodorizing edible oil in a plant includes generating a vacuum in the plant and filling a degassing stage with edible oil which passes through the degassing and separating stages in succession and is treated concurrently with stripping steam; and heating the batch in the separating stages of the stripping column's upper section to 150 to 180° C., middle section to 230 to 260° C., and cooling the lower section to 90 to 120° C.; scrubbing and condensing vapors departing from the separating stages of the upper and lower sections with fatty acid to get mixed fatty acid distillate; indirectly heating a batch in a first separating stage in the stripping column middle section; and condensing that batch from separation stages vapors of the stripping column middle section and fractionating selectively into a first and second fatty acid phase, respectively rich and poor in sterols and tocopherols.
    Type: Grant
    Filed: December 24, 2010
    Date of Patent: February 14, 2017
    Assignee: AIR LIQUIDE GLOBAL E&C SOLUTIONS GERMANY GMBH
    Inventors: Juergen Gabor, Steffen Reichwein
  • Patent number: 9511361
    Abstract: A catalyst containing a pentasil-type alumosilicates and a binder, in the form of spheres having an average diameter between 0.3 and 7 mm, wherein the BET surface area of the catalyst ranges from 300 to 600 m2/g. Also disclosed is a method for producing the catalyst, wherein primary crystallites of the aluminosilicate having an average diameter of at least 0.01 ?m and less than 0.1 ?m are mixed with the binder, shaped into spheres having an average diameter between 0.3 and 7 mm, and subsequently calcined. Also disclosed is the use of the catalyst for converting methanol into olefins, in particular propylene. Also disclosed is a method for producing olefins from methanol, in which a feed gas is fed across the catalyst.
    Type: Grant
    Filed: November 16, 2010
    Date of Patent: December 6, 2016
    Assignees: CLARIANT PRODUKTE (DEUTSCHLAND) GMBH, AIR LIQUIDE GLOBAL E&C SOLUTIONS GERMANY GMBH
    Inventors: Götz Burgfels, Manfred D. Frauenrath, Nadine Fromm, Angelika Glienke, Martin Rothämel, Sven Pohl
  • Patent number: 9505684
    Abstract: A process and a plant for producing an olefin stream from a hydrocarbon mixture feed stream, wherein the olefin stream is depleted as regards its content of oxygen-containing organic compounds (oxygenates) as compared to the feed stream. The hydrocarbon mixture feed stream is charged to a separation column operated by a thermal separation process, for example to a distillation column, wherein a material stream enriched in oxygenates is withdrawn via a side outlet and removed from the process. The process according to the invention is particularly useful for processing the product streams obtained in the olefin synthesis by an OTO process.
    Type: Grant
    Filed: April 21, 2011
    Date of Patent: November 29, 2016
    Assignee: AIR LIQUIDE GLOBAL E&C SOLUTIONS GERMANY GMBH
    Inventors: Hermann Bach, Thomas Renner, Martin Rothaemel, Michael Wilken
  • Patent number: 9504978
    Abstract: A cooled reactor for the production of dimethyl ether by catalytic dehydration of methanol in the gas phase, the reactor having an adiabatic catalyst bed as starting zone, a moderator zone cooled by direct or indirect heat exchange, and optionally an adiabatic catalyst bed as conditioning zone. The conversion of methanol to dimethyl ether is increased and the formation of undesired by-products is decreased.
    Type: Grant
    Filed: September 18, 2012
    Date of Patent: November 29, 2016
    Assignees: L'AIR LIQUIDE, SOCIÉTÉ ANONYME POUR L'ETUDE ET L'EXPLOITATION DES PROCÉDÉS GEORGES CLAUDE, AIR LIQUIDE GLOBAL E&C SOLUTIONS GERMANY GMBH
    Inventors: Bernd Ahlers, Manuela Gil De Tober, Eckhard Seidel
  • Patent number: 9296672
    Abstract: A method for producing methanol from inert-rich syngas includes installing a catalytic pre-reactor is upstream of the single or mufti-stage synthesis loop, a first part of the syngas being converted to methanol in the catalytic pre-reactor. Furthermore, an inert gas separation stage, for example a pressure swing adsorption system or a membrane system, is connected downstream of the synthesis loop, whereby a hydrogen-enriched syngas stream can be returned to the synthesis loop. In the processing of methane-rich syngas, the inert gas separation stage may also comprise an autothermal reformer in which methane is converted to carbon oxides and hydrogen, which are also returned into the synthesis loop.
    Type: Grant
    Filed: March 22, 2012
    Date of Patent: March 29, 2016
    Assignee: AIR LIQUIDE GLOBAL E&C SOLUTIONS GERMANY GMBH
    Inventors: Philipp Marius Hackel, Rainer Morgenroth, Andreas Bormann, Veronika Gronemann
  • Patent number: 9278328
    Abstract: A reformer tube for producing synthesis gas by steam reforming of hydrocarbon-containing feed gases, preferably natural gas, includes one or more helically coiled heat exchanger tubes which are arranged within a catalyst bed of a reforming catalyst and are helically coiled over part of their length located within the catalyst bed and are otherwise straight are present, where the straight proportion of the heat exchanger tubes and/or the helix pitch of the helically coiled part alters within the catalyst bed and matching to requirements of the pressure drop, the heat exchange properties, and the corrosion resistance.
    Type: Grant
    Filed: November 7, 2012
    Date of Patent: March 8, 2016
    Assignees: L'AIR LIQUIDE, SOCIETE ANONYME POUR L'ETUDE ET L'EXPLOITATION DES PROCEDES GEORGES CLAUDE, AIR LIQUIDE GLOBAL E&C SOLUTIONS GERMANY GMBH
    Inventors: Holger Schlichting, Ulrich Wolf, Sven Pohl, Dieter Ulber, Udo Zolnowski, Antonio Coscia, Julien Cances, Frederic Camy-Peyret, Fabrice Mathey
  • Patent number: 9272904
    Abstract: This invention relates to the production of synthesis gas by partial oxidation of liquid or gaseous, carbonaceous fuel in the presence of an oxygen-containing oxidant, wherein the fuel, the oxidant and a moderator are separately supplied to a burner and wherein the fuel and the moderator are mixed in a mixing chamber of the burner, before they are brought in contact with the oxidant. To reduce the load of the burner in particular during operation with transient conditions, the oxidant is centrally introduced through an outlet opening of the burner into a combustion chamber and the mixture of fuel and moderator is introduced through the outlet opening into the combustion chamber concentrically around the oxidant.
    Type: Grant
    Filed: April 17, 2014
    Date of Patent: March 1, 2016
    Assignee: Air Liquide Global E&C Solutions Germany GmbH
    Inventors: Matthias Mueller-Hagedorn, Holger Schlichting, Guenther Heinz
  • Patent number: 9085500
    Abstract: A process for producing a product containing C3H6 and C2H4 includes simultaneous conversion of MeOH and EtOH in an adiabatic sequentially operated reactor containing a plurality of reaction stages. Each of the plurality of reaction stages of the reactor is provided with a fixed bed of a form-selective catalyst. A gaseous feed stream including MeOH, DME and H2O is charged to at least a first of the reaction stages of the reactor with a temperature in a range of 300 to 600° C. at a pressure in a range of 0.1 to 20 bar[a]. EtOH is fed into at least, one of the reaction stages of the reactor.
    Type: Grant
    Filed: November 25, 2009
    Date of Patent: July 21, 2015
    Assignee: AIR LIQUIDE GLOBAL E&C SOLUTIONS GERMANY GMBH
    Inventors: Henning Buchold, Harald Koempel, Sven Pohl, Martin Rothaemel, Ulrich Wagner
  • Patent number: 9040594
    Abstract: A method for producing methanol from a synthesis gas containing hydrogen and carbon oxides with a high content of inert components includes passing the synthesis gas through a synthesis reactor so as to catalytically convert a part of the carbon oxides to methanol. The methanol is separated from the obtained mixture from the reactor. The mixture liberated from methanol is separated into a cycle stream and a purge stream. The cycle stream is recirculated so as to form a synthesis circle and combined with a fresh gas stream including hydrogen and carbon oxides before being charged into the synthesis reactor. The purge stream is supplied to a secondary reactor so as to catalytically convert a further part of the hydrogen and carbon oxides to methanol. Further methanol is separated the obtained mixture including synthesis gas, inert components and methanol vapor.
    Type: Grant
    Filed: July 16, 2010
    Date of Patent: May 26, 2015
    Assignee: AIR LIQUIDE GLOBAL E&C SOLUTIONS GERMANY GMBH
    Inventors: Andreas Bormann, Veronika Gronemann, Rainer Morgenroth, Jan Hagemann, Holger Schlichting, Philipp Marius Hackel
  • Patent number: 9011562
    Abstract: A method for producing a synthesis-gas product gas and a vapor stream includes catalytic steam reforming a hydrocarbonaceous feedstock in a steam reformer. The hot synthesis-gas product gas stream is cooled in a heat exchanger to form a cooled synthesis-gas product gas stream and a first partial vapor stream, which is supplied to the product vapor stream. The reforming furnace is operated so as to burn a burner feedstock in burners, cool a hot flue gas stream from the burners in a heat exchanger to form a cooled flue gas stream and a second partial vapor stream, and separate the cooled flue gas stream into a waste gas stream and a flue gas recirculation stream. The flow of the recirculated flue gas is increased with decreasing flow of the synthesis-gas product gas to obtain an approximately constant product vapor stream by increasing the second partial vapor stream.
    Type: Grant
    Filed: December 8, 2010
    Date of Patent: April 21, 2015
    Assignee: Air Liquide Global E&C Solutions Germany GmbH
    Inventors: Bernd Polster, Alexander Roesch, Matthew Shaver, Dieter Ulber, Ulrich Wolf
  • Patent number: 8884074
    Abstract: A process produces dimethyl ether (DME) from methanol (MeOH). The process includes charging a feed mixture consisting of raw MeOH and a process-internally obtained return flow substantially consisting of unconverted MeOH and reaction water to an MeOH column. The feed mixture is evaporated in the MeOH column to form a first distillate substantially consisting of vaporous MeOH. The first distillate is supplied to a reactor and the MeOH is converted to DME by splitting off water in the reactor so as to form a reaction mixture. The reaction mixture is withdrawn from the reactor, charged to a mixture column and separated into a bottom product substantially consisting of water and a second distillate substantially consisting of DME and MeOH. The second distillate is separated in a DME column into a third distillate substantially consisting of DME, a bottom product consisting essentially of water-poor MeOH, and uncondensable gases discharged overhead.
    Type: Grant
    Filed: November 19, 2009
    Date of Patent: November 11, 2014
    Assignee: Air Liquide Global E&C Solutions Germany GmbH
    Inventors: Bernd Ahlers, Gerhard Birke, Harald Koempel, Hermann Bach, Martin Rothaemel, Waldemar Liebner, Walter Boll, Veronika Gronemann
  • Patent number: 8871961
    Abstract: A process for continuous production of biodiesel from vegetable oils or animal fats by transesterification with methanol or ethanol to give crude fatty acid alkyl esters, subsequent washing with water in a wash column to remove water-soluble impurities, subsequent drying by vaporization of the water content and subsequent removal of steryl glycosides by adsorption onto calcium bentonite, wherein the adsorption column(s) used is/are regenerated in a first step, for desorption of the steryl glycosides, by rinsing with a mixture consisting of fatty acid alkyl esters and methanol or ethanol, and in a subsequent second step, for removal of methanol residues, by rinsing with fatty acid alkyl esters or with gaseous nitrogen or carbon dioxide.
    Type: Grant
    Filed: March 2, 2011
    Date of Patent: October 28, 2014
    Assignee: Air Liquide Global E&C Solutions Germany GmbH
    Inventors: Eckhard Seidel, Rudolf Boensch, Norbert Palauschek, Helmut Saft