Patents Assigned to Air Liquide Large Industries U.S.
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Publication number: 20120291481Abstract: The present invention provides a process for recovering hydrogen and carbon dioxide from a process stream utilizing a carbon dioxide separation unit and two membrane separation units. The present invention further provides a process within a hydrogen generation plant to increase recovery of hydrogen and capture equal to or greater than 80% of the carbon dioxide in the syngas stream. By using the process of the present invention, especially in terms of a hydrogen generation plant, it is possible to increase recovery of hydrogen and capture of the carbon dioxide in the syngas stream by balancing the recycle of the hydrogen rich permeate from the hydrogen membrane separation unit to the process unit and/or the water gas shift as capacity allows when a carbon dioxide separation unit, a carbon dioxide membrane separation unit and a hydrogen membrane separation unit are utilized.Type: ApplicationFiled: June 27, 2011Publication date: November 22, 2012Applicants: Air Liquide Large Industries U.S. LP, L'Air Liquide Societe Anonyme Pour L'Etude Et L'Exploitation Des Procedes Georges ClaudeInventors: Paul Terrien, Trapti Chaubey, Purushottam V. Shanbhag, Bhadra S. Grover, Dennis A. Vauk, Arthur Darde, Pascal Marty
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Publication number: 20120291484Abstract: This present invention provides a method to more efficiently recover hydrogen and carbon dioxide, preferably at least 50%, even more preferably at least 75%, and most preferably at least 90% of the carbon dioxide. The present invention further provides the design for capture of at least 80%, carbon dioxide from syngas that allows for the simultaneous production of medium to high amounts of hydrogen in the syngas as a part of the production of hydrogen in a hydrogen generation plant. By using the process of the present invention, especially in terms of a hydrogen generation plant, it is possible to increase recovery of hydrogen and capture of the carbon dioxide in the syngas stream by balancing the recycle of the hydrogen rich permeate from the hydrogen membrane separation units to the process unit and/or the water gas shift as capacity allows when a carbon dioxide separation unit, a carbon dioxide membrane separation unit and two hydrogen membrane separation units are utilized.Type: ApplicationFiled: June 27, 2011Publication date: November 22, 2012Applicants: Air Liquide Large Industries U.S. LP, L'Air Liquide Societe Anonyme Pour L'Etude Et L'Exploitation Des Procedes Georges ClaudeInventors: Paul Terrien, Trapti Chaubey, Purushottam V. Shanbhag, Bhadra S. Grover, Dennis A. Vauk, Arthur Darde, Pascal Marty
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Publication number: 20120291485Abstract: This present invention provides a method to more efficiently recover hydrogen and carbon dioxide, preferably at least 50%, even more preferably at least 75%, and most preferably at least 90% of the carbon dioxide. The present invention further provides the design for capture of at least 80%, carbon dioxide from syngas that allows for the simultaneous production of medium to high amounts of hydrogen in the syngas as a part of the production of hydrogen in a hydrogen generation plant. By using the process of the present invention, especially in terms of a hydrogen generation plant, it is possible to increase recovery of hydrogen and capture of the carbon dioxide in the syngas stream by balancing the recycle of the hydrogen rich permeate from the hydrogen membrane separation units to the process unit and/or the water gas shift as capacity allows when a carbon dioxide separation unit, a carbon dioxide membrane separation unit and two hydrogen membrane separation units are utilized.Type: ApplicationFiled: June 27, 2011Publication date: November 22, 2012Applicants: Air Liquide Large Industries U.S. LP, L'Air Liquide Societe Anonyme Pour L'Etude Et L'Exploitation Des Procedes Georges ClaudeInventors: Paul Terrien, Trapti Chaubey, Purushottam V. Shanbhag, Bhadra S. Grover, Dennis A. Vauk, Arthur Darde, Pascal Marty
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Publication number: 20120291482Abstract: The present invention provides a process for recovering hydrogen and carbon dioxide from a process stream utilizing a carbon dioxide separation unit and two membrane separation units. The present invention further provides a process within a hydrogen generation plant to increase recovery of hydrogen and capture equal to or greater than 80% of the carbon dioxide in the syngas stream. By using the process of the present invention, especially in terms of a hydrogen generation plant, it is possible to increase recovery of hydrogen and capture of the carbon dioxide in the syngas stream by balancing the recycle of the hydrogen rich permeate from the hydrogen membrane separation unit to the process unit and/or the water gas shift as capacity allows when a carbon dioxide separation unit, a carbon dioxide membrane separation unit and a hydrogen membrane separation unit are utilized.Type: ApplicationFiled: June 27, 2011Publication date: November 22, 2012Applicants: Air Liquide Large Industries U.S. LP, L'Air Liquide Societe Anonyme Pour L'Etude Et L'Exploitation Des Procedes Georges ClaudeInventors: Paul Terrien, Trapti Chaubey, Purushottam V. Shanbhag, Bhadra S. Grover, Dennis A. Vauk, Arthur Darde, Pascal Marty
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Publication number: 20120292574Abstract: This present invention provides a method to more efficiently recover hydrogen and carbon dioxide, preferably at least 50%, even more preferably at least 75%, and most preferably at least 90% of the carbon dioxide. The present invention further provides the design for capture of at least 80%, carbon dioxide from syngas that allows for the simultaneous production of medium to high amounts of hydrogen in the syngas as a part of the production of hydrogen in a hydrogen generation plant. By using the process of the present invention, especially in terms of a hydrogen generation plant, it is possible to increase recovery of hydrogen and capture of the carbon dioxide in the syngas stream by balancing the recycle of the hydrogen rich permeate from the hydrogen membrane separation units to the process unit and/or the water gas shift as capacity allows when a carbon dioxide separation unit, a carbon dioxide membrane separation unit and two hydrogen membrane separation units are utilized.Type: ApplicationFiled: June 27, 2011Publication date: November 22, 2012Applicants: Air Liquide Large Industries U.S. LP, L'Air Liquide Societe Anonyme Pour L'Etude Et L'Exploitation Des Procedes Georges ClaudeInventors: Paul Terrien, Trapti Chaubey, Purushottam V. Shanbhag, Bhadra S. Grover, Dennis A. Vauk, Arthur Darde, Pascal Marty
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Patent number: 8255186Abstract: Techniques are disclosed for presenting users with dynamic views of process data related to the operations of an industrial system. Data obtained by a SCADA system may be stored in a real-time status database (which reflects the current process data of the industrial system) and a historian database (which archives the process data from the industrial system as it changes over time). A design canvas allows users to compose a dynamic view of the process data obtained by the SCADA system. For example, a user may compose a dynamic view of selected temperatures, pressures, and flow rates obtained by the SCADA system while monitoring the status of a pipeline.Type: GrantFiled: July 9, 2009Date of Patent: August 28, 2012Assignee: Air Liquide Large Industries U.S. LPInventors: Sultan Q. Mukhi, Jay A. Forman
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Publication number: 20120169512Abstract: Techniques are disclosed for monitoring the consumption of a plurality of metered resources. The techniques involve receiving a KYZ pulse from a first utility meter, where the first utility meter is coupled to a source of one of the metered resources, and where the first utility meter outputs the KYZ pulse based on a predefined amount of metered resource being passed through the utility meter. A first counter is incremented, where the first counter is associated with the utility meter and stored in a memory.Type: ApplicationFiled: December 21, 2011Publication date: July 5, 2012Applicant: Air Liquide Large Industries U.S. LPInventors: JOSHUA CARPMAN, CHARLES N. HARPER
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Publication number: 20120157726Abstract: A process for the production of cellulose based biofuels is provided. This process includes pyrolysing a cellulose-containing feedstock to form a slurry of bioliquids and char; hydrocracking the slurry to produce a hydrocarbon gas stream, a hydrocarbon liquid stream, an impurities stream, and a residue stream; distilling the liquid hydrocarbon stream to produce at least a naphtha stream, and a diesel stream; and gasifying the residue stream to produce at least a hydrogen and a carbon monoxide stream.Type: ApplicationFiled: December 15, 2010Publication date: June 21, 2012Applicant: Air Liquide Large Industries U.S. LPInventors: Dennis A. Vauk, Tarun D. Vakil
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Publication number: 20120121497Abstract: The present invention provides a process for recovering hydrogen and carbon dioxide from a process stream (1) of a process unit (0) wherein the process stream (1) contains at least carbon dioxide, hydrogen and methane. In the process, the process stream (1) is optionally compressing in a first compressor (2) before being cooled in a heat exchanger (3) to a temperature equal to or less than ?10° C. Next, the cooled process stream (1) is separated and purified in a carbon dioxide separation unit (4) to produce a carbon dioxide rich liquid stream (6) and a carbon dioxide lean non-condensable stream (5) with the carbon dioxide rich liquid stream (6) being withdrawn as a carbon dioxide product for further use.Type: ApplicationFiled: December 21, 2010Publication date: May 17, 2012Applicants: Air Liquide Large Industries U.S. LP, L'Air Liquide Societe Anonyme Pour L'Etude Et L'Exploitation Des Procedes Georges ClaudeInventors: Paul Terrien, Trapti Chaubey, Purushottam V. Shanbhag, Bhadra S. Grover, Dennis A. Vauk, Arthur Darde
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Publication number: 20120118011Abstract: The present invention provides a method to more efficiently recover hydrogen and carbon dioxide as well as a design for carbon dioxide capture from syngas that allows for the simultaneous production of medium to high amounts of hydrogen and the capture of at least 90% of the carbon dioxide in the syngas as a part of the production of hydrogen in a hydrogen generation plant. Through the use of a combination of hydrogen selective membranes and carbon dioxide selective membranes together with a carbon dioxide separation unit it is possible to increase recovery of hydrogen and carbon dioxide and improved process efficiency of the hydrogen generation plant.Type: ApplicationFiled: December 21, 2010Publication date: May 17, 2012Applicants: Air Liquide Large Industries U.S. LP, L'Air Liquide Societe Anonyme Pour L'Etude Et L'Exploitation Des Procedes Georges ClaudeInventors: Paul Terrien, Trapti Chaubey, Purushottam V. Shanbhag, Bhadra S. Grover, Dennis A. Vauk, Arthur Darde
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Publication number: 20120051993Abstract: A method for volatile compound (VC) mitigation in a syngas production process is provided. This method includes providing a hydrocarbon reforming syngas production plant, this plant includes a reformer system comprising a primary fuel and oxidant stream, where part of this system is at low pressure, a steam inlet stream, and a primary combustion system for providing heat to the reformer system and producing a reformer flue gas stream, and a gaseous vent stream mainly composed of water and containing VC. This method also includes introducing at least a portion of the vent stream into one or more of the following: the primary fuel and oxidant stream; the steam inlet stream; the reformer flue gas stream.Type: ApplicationFiled: August 25, 2010Publication date: March 1, 2012Applicants: L'Air Liquide Societe Anonyme Pour L'Etude Et L'Exploitation Des Procedes Georges Claude, Air Liquide Large Industries U.S. LP, Lurgi GmbHInventors: William D. Lindberg, Alexander Rösch, Michael B. Wakim
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Patent number: 8112300Abstract: One embodiment of the invention provides a method for optimizing a supply chain management (SCM) problem. A genetic algorithm optimization technique may be used to generate a production solution for the production side of an SCM problem and an ant colony optimization technique may be used to generate a solution for the distribution side of the SCM problem. Together, the genetic algorithm optimization technique and the ant colony optimization technique operate to quickly identify high-quality solutions to an SCM problem.Type: GrantFiled: April 12, 2006Date of Patent: February 7, 2012Assignee: Air Liquide Large Industries U.S. LPInventor: Charles N. Harper
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Publication number: 20120022299Abstract: A process to integrate a first biofuels process and a second generation cellulosic biofuels process is provided. The pyrolysis means which produces the char stream and a bioliquid stream. The low pressure hydrotreating component, a high pressure hydrotreating component, the low pressure hydrotreating component which produces the hydrocarbon stream, the high pressure hydrotreating component which produces the steam stream and bioliquid stream. A distillation means, which produces a green gasoline stream and a green diesel stream from the bioliquid stream. The second biofuels process may be a first generation bio-ethanol process, which produces a bio-ethanol stream. The hydrogen production unit, which produces the hydrogen stream and the steam stream. The hydrogen production unit may be a steam reformer or partial oxidation unit.Type: ApplicationFiled: July 21, 2010Publication date: January 26, 2012Applicant: Air Liquide Large Industries U.S. LPInventor: Dennis A. Vauk
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Publication number: 20110297585Abstract: The present invention relates to a process for the reduction of CO2 emissions from the flue gas of a cracking catalyst regenerator that is part of a fluidized catalytic cracking system which cracks petroleum feedstocks such as petroleum distillates of residual or crude oil which, when catalytically cracked, provide either a gasoline or a gas oil product. This process may also be utilized with regard to the cracking of synthetic feeds having boiling points of from 400° F. to about 1000 as exemplified by oils derived from coal or shale oil. By reducing the CO2 emissions in the regeneration step of catalytic cracking, the further goal of maximizing the production of CO in the flue gas is achieved, the CO being further utilized as a fuel in the refinery or further processed to produce hydrogen.Type: ApplicationFiled: December 16, 2010Publication date: December 8, 2011Applicant: Air Liquide Large Industries U.S. LPInventor: Dennis A. Vauk
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Patent number: 8065243Abstract: Embodiments of the invention provide a computerized optimization system configured to optimize the operations of a hydrogen generation, processing, and delivery network. Such a network typically includes a complex of physical equipment, plants, and pipelines, including both production and distribution facilities. A hydrogen optimization system provides a software system that optimizes the production and distribution of hydrogen over such a hydrogen network. The hydrogen optimization system may use both a genetic algorithm configured to “evolve” a population of solutions to improve the quality of solutions over time as well as directed heuristics to identify a superior operating state for the hydrogen pipeline network.Type: GrantFiled: April 18, 2008Date of Patent: November 22, 2011Assignee: Air Liquide Large Industries U.S. LPInventor: Charles N. Harper
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Publication number: 20110251938Abstract: Techniques are disclosed for managing certain aspects of a large industrial operation (such as a pipeline). A commodity materials invoice system may allow a user to model a commodity invoice as a template and subsequently use that template to model commodity usage for different periods of time. Costs for a given billing period may be estimated based on actual commodity consumption. For example, data from a SCADA system monitoring different aspects of a pipeline may be used to estimate invoice costs for retail commodity consumption. The commodity materials invoice system may be configured to present both estimated and actualized invoice data side-by-side, allowing users to make a direct comparison of the estimated and actualized invoice data.Type: ApplicationFiled: December 16, 2010Publication date: October 13, 2011Applicant: Air Liquide Large Industries U.S. LPInventors: Elias Margonis, Charles Neely Harper
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Publication number: 20110137777Abstract: A billing system for supply contrasts in an industrial network is disclosed. In the case of a pipeline, a process flow computer installed at each customer site may each receive instantaneous flow readings from a flow meter. The process flow computer may be configured to accumulate product volumes in different volume groups, where each volume group corresponds to a range of instantaneous flow rates. Different volume groups may be associated with different rates ultimately charged to a customer. The volume groups may be assigned by a computing system running a billing application at a pipeline operations control center. Volume groups may be set for individual customers based on a contract summary of an agreement between a given customer and the operator of an industrial network.Type: ApplicationFiled: October 12, 2010Publication date: June 9, 2011Applicant: Air Liquide Large Industries U.S.LPInventors: Elias Margonis, Charles N. Harper
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Patent number: 7894460Abstract: A programmable logic controller (PLC) protocol converter is disclosed that allows a supervisory control and data acquisition (SCADA) system to effectively communicate with a PLC device using a desired communications protocol, particularly in cases where the PLC device does not “speak” the desired communications protocol. A first thread may be configured to continually read PLC addresses, one at a time, using a communications protocol understood by the PLC device. The first thread may store the data values in the shared data array within program memory. Thus, the first thread exposes data from the PLC device, as specified in the configuration file. At the same time, a second thread may be configured to serve the data in the shared data array according to a second communications protocol, e.g., to the SCADA system.Type: GrantFiled: July 25, 2008Date of Patent: February 22, 2011Assignee: Air Liquide Large Industries U.S. LPInventors: Joshua Carpman, Travis R. Cummings, Hamid J. Rabat-Torki
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Patent number: 7853568Abstract: Techniques for operating an archival database, referred to as a historian, are disclosed. The historian may be used to archive values from a real-time database. Data values to be archived in the historian are first written to a short-term, high-availability repository, such as a memory-mapped database. As data values “fill” the short-term repository, an archival processor application may be configured to “drain” them from the short-term repository and store them in a high-capacity, long-term archive, such as a disk-based database. Thus, the short-term repository may be used to provide fast access to the recent operational history of a monitored system, (e.g., a complex pipeline network), where long-term archive may be used to provide access to a comprehensive operational history of the monitored system.Type: GrantFiled: March 1, 2007Date of Patent: December 14, 2010Assignee: Air Liquide Large Industries U.S. LPInventor: Sulton Q. Mukhi
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Patent number: 7853569Abstract: Techniques for operating an archival database, referred to as a historian, are disclosed. Embodiments of the invention provide techniques for synchronizing historical archive files and/or archival data between a primary and a secondary historian used to archive data values from a real-time database. The real-time database may be used to monitor the current operational state of a large industrial system, such as a pipeline. In turn, the historian may be used to archive the data stored by the real-time database. In the event that either the primary or the secondary system (or both) goes down and then comes back online at a later time, embodiments of the invention may be used to synchronize data between the primary and secondary historian systems.Type: GrantFiled: June 29, 2007Date of Patent: December 14, 2010Assignee: Air Liquide Large Industries U.S. LPInventors: Sultan Q. Mukhi, Emtiaz A. Momin, Prabhakara R. Vinta