Patents Assigned to Air Liquide
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Patent number: 6868312Abstract: Method for real-time control of the fabrication of a thin-film structure comprising a substrate by ellipsometric measurement in which: variables directly linked to the ellipsometric ratio ?=tan? exp(i?) are measured; and the said variables are compared with reference values. The comparison relates to the length of the path traveled at a time t in the plane of the variables with respect to an initial point at time t0, for each layer participating in the thin-film structure.Type: GrantFiled: August 6, 2001Date of Patent: March 15, 2005Assignee: L'Air Liquide Societe Anonyme a Directoire et Conseil de Surveillance pour l'Etude et l'Exploitation des Procedes Georges ClaudeInventors: Bernard Drevillon, Thibaut Heitz, Jean-Christophe Rostaing
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Patent number: 6866748Abstract: The present invention provides a process for preparing polysulfide. More particularly, the process of the present invention allows one to prepare the amount of polysulfide needed using clarified white liquor, and to be used when and where it is needed during the cooking process. The process comprises reacting alkaline digesting liquor after clarification with a catalytic amount of a transition metal oxide catalyst, most preferably manganese dioxide. The reaction is conducted at a temperature of 98° C. or less, and is conducted for a short period of time, e.g., less than five minutes, with no oxygen gas or air being introduced with the catalyst and the main flow of clarified liquor.Type: GrantFiled: June 6, 2002Date of Patent: March 15, 2005Assignee: American Air Liquide, Inc.Inventors: Meenakshi V. Sundaram, Sebastien Corbeil, Michel Epiney
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Patent number: 6865448Abstract: An outfit for the construction of several complex industrial installations for the treatment of industrial fluids includes several assemblies of several functional modules, each adapted to perform an elementary operation. Each functional module includes at least one input and at least one output, as well as a local guide unit of the functional module provided with a communication interface. All the functional modules have the same assembly to carry out the same elementary operation and are standard. The functional modules are adapted to be associated functionally with each other in installations. The outfit moreover includes, for each industrial installation, a single central guide unit, adapted to guide the functional modules of the associated industrial installation.Type: GrantFiled: April 19, 2000Date of Patent: March 8, 2005Assignee: L'Air Liquide - Societe Anonyme a Directoire et Conseil de Surveillance pour l'Etude et l'Exploitation des Procedes Georges ClaudeInventors: Frédéric Rotman, Antoine Willemot, Lionel Barry, Laurent Ferenczi
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Patent number: 6865522Abstract: The invention relates to a process for producing a diagram of an installation using apparatuses, each apparatus being supplied with gas, comprising: the consultation of one or more databases (5) comprising, for each apparatus, data on the flow rate, the nature, the purity of the gas supplying the apparatus, and the supply pressure of that gas for that apparatus, the selection, for each apparatus, of a value, or of a limit value, of duration or of frequency of use, the calculation, for each apparatus, of the consumption, or of the limit consumption, according to the utilisation value and to the flow rate data, the calculation, for each gas and for each gas purity, of the total of the consumptions of all of the apparatuses, the indication of technical constraints, the consultation of a database (5) for proposing, for each gas and each gas purity, a packaging, as a function of the consumption and of the technical constraints relating to the storage of the gas and/or to their delivery.Type: GrantFiled: September 29, 2000Date of Patent: March 8, 2005Assignee: L'Air Liquide Société Anonyme a Directoire et Conseil de Surveillance pour l'Etude et l'Exploitation des Procedes Georges ClaudeInventors: Michel Gastiger, Gérard Loiseau
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Patent number: 6860920Abstract: Gas separation membranes formed from polyester-polyether block copolymers which are useful for separating gases from gas mixtures. The membranes and processes are especially suited for separating polar gases from mixtures that contain polar and non-polar species. The novel membranes exhibit good permeability and permselectivity as well as durability, making them well suited for industrial applications such as removal of acid gases from natural gas and removal of carbon dioxide from synthesis gas.Type: GrantFiled: March 13, 2003Date of Patent: March 1, 2005Assignee: L'Air Liquide-Societe Anoyme a Directoire et Conseil de Surveillance Pour l'Etude et l'Exploitation des Procedes George ClaudeInventor: John W. Simmons
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Patent number: 6859766Abstract: A method for indirect gas species monitoring based on measurements of selected gas species is disclosed. In situ absorption measurements of combustion species are used for process control and optimization. The gas species accessible by near or mid-IR techniques are limited to species that absorb in this spectral region. The absorption strength is selected to be strong enough for the required sensitivity and is selected to be isolated from neighboring absorption transitions. By coupling the gas measurement with a software sensor gas, species not accessible from the near or mid-IR absorption measurement can be predicted.Type: GrantFiled: February 11, 2003Date of Patent: February 22, 2005Assignee: American Air Liquide, Inc.Inventors: William A. Von Drasek, Victor M. Saucedo
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Patent number: 6843829Abstract: Gas separation membranes formed from polyether-urethane or polyether-urea block copolymers are useful for separating gases from gas mixtures. The membranes and processes are especially suited for separating polar gases from mixtures that contain polar and non-polar species. The novel membranes exhibit good permeability and permselectivity, as well as durability, making them well suited for industrial applications such as removal of acid gases from natural gas and removal of carbon dioxide from synthesis gas.Type: GrantFiled: March 13, 2003Date of Patent: January 18, 2005Assignee: L'Air Liquide-Societe Anonyme a'Directoire et Conseil de Surveillance pour l'Etude et l'Exploitation des Procedures Georges ClaudeInventor: John W. Simmons
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Patent number: 6831248Abstract: Process for welding together the two longitudinal edges of a sheet of austenitic, ferritic or martensitic stainless steel so as to obtain a welded pipe, employing at least one laser beam having a power ranging up to 12 kW, and in which a gas mixture is used that consists of 30% to 80% nitrogen by volume and of helium for the remainder (up to 100%). The stainless steel sheet has a thickness of 0.5 to 4 mm and the pipe obtained has a diameter of 5 mm to 50 cm. The welding is full-penetration welding.Type: GrantFiled: June 9, 2003Date of Patent: December 14, 2004Assignee: L'Air Liquide, S.A.Inventors: Francis Briand, Karim Chouf, Philippe Lefebvre, Eric Verna
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Patent number: 6821316Abstract: A method comprising two adsorbers which follow each a phase-shifted cycle successively consisting in an adsorption phase, at high pressure of the cycle, and a regeneration phase, ending in repressurizing of the adsorber.Type: GrantFiled: June 27, 2003Date of Patent: November 23, 2004Assignee: L'Air Liquide, Societe Anonyme pour l'Etude et, l'Exploitation des Procedes Georges ClaudeInventors: Alain Guillard, Jan-Marc Peyron
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Patent number: 6820432Abstract: The heat recovery boiler (1) is operated, at least temporarily, by feeding its combustion system with air (13) and with a stream (15) of flue gases (4) recycled to a level of at least 45%, typically between 50 and 65%, so as to allow the efficiency of the boiler to be increased and to decouple it, at least temporarily, from the combustion engine (8) driving a generator (9), the exhaust gases from which are burnt in post-combustion mode in the boiler in cogeneration mode.Type: GrantFiled: March 3, 2003Date of Patent: November 23, 2004Assignee: L'Air Liquide, S.A.Inventors: Jacques Labasque, Jacques Segret
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Patent number: 6820659Abstract: A multicomponent, ground based system for reducing the hazard of explosion of aircraft fuel in the on board tanks of aircraft. The system is adapted to provide a supply of scrubbed fuel having a low concentration of dissolved oxygen. The scrubbed fuel can be supplied from bulk storage tanks to dispensing stations nearby the aircraft loading and boarding positions at an airport. The system also includes equipment adapted to wash the ullage of the aircraft fuel tanks to remove excess oxygen above the fuel in the tanks. The system further includes a gas cleaning unit to strip excessive amounts of volatile organic compounds from gas exhausted during operation of the system thereby producing environmentally benign atmospheric emissions. The system also includes redundant sources of inert gas so that the system can continue to operate in the contingency that one of the inert gas sources temporarily ceases to operate.Type: GrantFiled: July 30, 2003Date of Patent: November 23, 2004Assignee: L'Air Liquide, S.A.Inventor: Richard A. Sauer
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Patent number: 6821662Abstract: The device comprises two separators (20, 30) in series in the outlet portion of the hydrogen circuit each defining at least one inlet chamber (21, 31) separated, by a hydrophilic filter (22, 32), from an outlet chamber (23, 33) connected to the hydric circuit (24) of the cell. Application to air-hydrogen fuel cells.Type: GrantFiled: August 20, 2002Date of Patent: November 23, 2004Assignee: L'Air Liquide - Societe Anonyme a Directoire et Conseil de Surveillance pour l'Etude et l'Exploitation des Procedes Georges ClaudeInventors: Pierre Charlat, Gérard Boudiere
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Patent number: 6816812Abstract: Disclosed are methods and apparatus to measure specific mass increases (due to the absorption of moisture) that occur in materials and for predicting moisture absorption in materials. In one method, pre-dried plastic encapsulated microchip packages (PEMs) are exposed to moist air over a period of time and moisture absorption is determined over a period of time resulting in prediction of moisture absorption of a particular material and determination of methods of care and storage of material to prevent excessive moisture absorption.Type: GrantFiled: December 14, 2001Date of Patent: November 9, 2004Assignee: American Air Liquide, Inc.Inventors: Frederick W. Giacobbe, Michael G. Pizzo
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Patent number: 6815635Abstract: Method of welding tailored blanks consisting of a material mostly containing steel and a proportion greater than 0.015% aluminium by weight, using at least one laser beam, in which at least one weld joint of the full-penetration type is made using a gas mixture consisting of 30% to 80% nitrogen by volume, the rest being helium (up to 100%) in order to assist the said laser beam. The method of the invention is particularly recommended for welding motor vehicle elements, especially bodywork, doors, bonnets or the like.Type: GrantFiled: June 10, 2003Date of Patent: November 9, 2004Assignee: L'Air Liquide, Societe Anonyme pour l'etude et, l'Exploitation des Procedes Georges ClaudeInventors: Francis Briand, Karim Chouf, Philippe Lefebvre, Eric Verna
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Patent number: 6814780Abstract: A hollow fiber membrane gas separation apparatus of a compact design suitable for separation and purification of gases is disclosed. The apparatus comprises an outer housing that consists of a detachable bowl and a head closure, and a removable hollow fiber membrane cartridge positioned therein. The cartridge contains a concentric tubular inner core member and is surrounded by a shell and at least one end closure. The cartridge is attached by its first axial end in a sealed and removable manner to a gas flow conduit positioned coaxially in the housing closure wherein the conduit is in fluid communication with a gas inlet or product gas outlet port formed in the housing head closure and by its second axial end to a waste gas exit port in the bowl. The feed gas inlet port and the product gas outlet port in the head closure are spaced in a straight line for a short overall distance providing for a linear connection with other components of a gas separation system, which is a preferred system component packaging.Type: GrantFiled: May 2, 2001Date of Patent: November 9, 2004Assignee: L'Air Liquide, Societe Anonyme A Directoire et Conseil de Surveillance Pour L'Etude et L'Exploitation des Procedes Georges ClaudeInventors: Benjamin Bikson, Scott Andrew Bartholomew, Salvatore Giglia, Bradley Quinn Johnson
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Patent number: 6813902Abstract: A retrofit technology for air-fuel fired, vertical glass furnace for oxygen firing or boosting to provide additional heat to the process to increase furnace production capacity. The additional firing using oxygen is strategically controlled to enable enhanced radiation from oxygen flame for the spheroidizing process without negative effects on the overall process. With proper implementation, an increased production from 50% to 200%, depending on the size of the spheres, can be achieved while maintaining acceptable product quality. Processes in accordance with the present invention can be performed using one of a number of methods of oxygen boosting.Type: GrantFiled: October 19, 2001Date of Patent: November 9, 2004Assignees: American Air Liquide, Inc., Air Liquide America, L.P., L'Air Liquide S.A.Inventors: Eric Streicher, John Foss, Mahendra L. Joshi, Harley A. Borders
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Patent number: 6810897Abstract: To provide a process gas supply mechanism for ALCVD systems that enables the high speed switching of process gases without accompanying particulate contamination of the treatment substrate. The ALCVD system is provided with a CVD treatment section and a process gas supply section. The process gas supply section contains a reactant gas line and a carrier gas line; these are combined to form a joint flow line. A vent line is connected to the reactant gas line upstream from the joint flow position. A stop valve SV and a needle valve NV are disposed in the vent line. This needle valve NV functions as a setting means in order to set the flow rate of the gas flowing in the vent line. The stop valve SV is driven through repetitive switching operations by a drive control element, thereby effecting supply and nonsupply of the reactant gas.Type: GrantFiled: May 17, 2002Date of Patent: November 2, 2004Assignee: L'Air Liquide, Societe Anonyme a Directoire et Conseil de Surveillance pour l'Etude et l'Exploitation des Procedes Georges ClaudeInventors: Jean-Marc Girard, Takako Kimura
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Patent number: 6799526Abstract: Methods of increasing the throughput of recovery boilers equipped with at least three levels of injection of air with oxygen enrichment of the air in at least one air level. In one method, a black liquor recovery boiler has three levels of air injection, and oxygen enrichment is applied to at least the secondary and the tertiary air injection levels. In another method, a black liquor recovery boiler has four levels of air injection, and oxygen enrichment is applied to one or more of the tertiary or quaternary air injection levels. In another method, a black liquor boiler has three levels of air injection, with oxygen enrichment applied to at least two air injection levels. After combustion, the oxygen concentration in the resultant flue gas is sensed. The oxygen injection is then adjusted in order to maintain the sensed oxygen concentration at the previously selected oxygen set point.Type: GrantFiled: December 6, 2001Date of Patent: October 5, 2004Assignees: American Air Liquide, Inc., Air Liquide America, L.P., Jansen Combustion and Boiler Technologies, Inc.Inventors: Louis C. Philippe, Eric L. Duchateau, David R. Scheeff, Arie Verloop, Edward C. Dye
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Patent number: 6799883Abstract: Provided are a method and apparatus for continuously blending a chemical solution for use in semiconductor processing. The method involves the step of: mixing a first chemical stream with a second chemical stream in a controlled manner, to form a stream of a solution having a predetermined formulation. The apparatus allows one to practice the above method. The method and apparatus can accurately provide chemical solutions of desired concentration in a continuous manner. The invention has particular applicability in semiconductor device fabrication.Type: GrantFiled: December 20, 1999Date of Patent: October 5, 2004Assignee: Air Liquide America L.P.Inventors: Karl J. Urquhart, John B. Thompson, Joe G. Hoffman
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Patent number: 6799960Abstract: The invention provides a spinnerette assembly for forming hollow fibers. The spinnerette assembly contains an extrusion orifice and a fiber-forming material passage in communication with the extrusion orifice. A hollow needle extends through the extrusion orifice in a concentric manner to define an annular passage surrounding the needle. The fiber-forming material passage includes a fiber-forming material inlet port extending from a surface of the spinnerette assembly to an interior of the assembly and a transverse passage extending from the fiber-forming material port to the annular passage surrounding the needle. A bore forming fluid passage communicates with the interior of the needle.Type: GrantFiled: December 8, 2000Date of Patent: October 5, 2004Assignee: L'Air Liquide - Societe Anonyme a Directoire et Consiel de Surveillance pour l'Etude et l'Exploitation des Procedes Georges ClaudeInventor: Samuel Earl Moore