Patents Assigned to Air Product and Chemicals, Inc.
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Patent number: 11945721Abstract: A hydrogen feed stream comprising oxygen and one or more impurities selected from the group consisting of nitrogen, argon, methane, carbon monoxide, carbon dioxide, and water, is purified using a cryogenic temperature swing adsorption (CTSA) process with high overall recovery of hydrogen. The CTSA is regenerated using an inert gas to prevent an explosive mixture of hydrogen and oxygen from occurring.Type: GrantFiled: February 8, 2022Date of Patent: April 2, 2024Assignee: Air Products and Chemicals, Inc.Inventors: Shubhra Jyoti Bhadra, Jeffrey R. Hufton, Timothy C. Golden, Aaron Raymond Scott, Quan Min Shao, Vishrut Garg
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Patent number: 11929613Abstract: There is provided a method of determining and utilizing predicted available power resources from one or more renewable power sources for one or more industrial gas plants comprising one or more storage resources. The method is executed by at least one hardware processor and comprises: obtaining historical time-dependent environmental data associated with the one or more renewable power sources; obtaining historical time-dependent operational characteristic data associated with the one or more renewable power sources; training a machine learning model based on the historical time-dependent environmental data and the historical time-dependent operational characteristic data; executing the trained machine learning model to predict available power resources for the one or more industrial gas plants for a pre-determined future time period; and controlling the one or more industrial gas plants in response to the predicted available power resources for the pre-determined future time period.Type: GrantFiled: January 31, 2023Date of Patent: March 12, 2024Assignee: AIR PRODUCTS AND CHEMICALS, INC.Inventors: Sanjay Mehta, Pratik Misra
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Patent number: 11925894Abstract: A carbon dioxide capture system includes a first heat exchanger configured to exchange heat between an exhaust stream and a lean carbon dioxide effluent stream. The carbon dioxide capture system also includes a first turboexpander including a first compressor driven by a first turbine. The first compressor is coupled in flow communication with the first heat exchanger. The first turbine is coupled in flow communication with the first heat exchanger and configured to expand the lean carbon dioxide effluent stream. The carbon dioxide capture system further includes a carbon dioxide membrane unit coupled in flow communication with the first compressor. The carbon dioxide membrane unit is configured to separate the exhaust stream into the lean carbon dioxide effluent stream and a rich carbon dioxide effluent stream. The carbon dioxide membrane unit is further configured to channel the lean carbon dioxide effluent stream to the first heat exchanger.Type: GrantFiled: November 9, 2020Date of Patent: March 12, 2024Assignee: AIR PRODUCTS AND CHEMICALS, INC.Inventors: Douglas Carl Hofer, Joseph Philip DiPietro
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Patent number: 11926906Abstract: A process for producing compressed hydrogen gas, said process comprising electrolysing water to produce hydrogen gas and compressing said hydrogen gas in a multistage compression system to produce compressed hydrogen gas. The multistage compression system comprises at least one centrifugal compression stage, and the hydrogen gas is fed to the centrifugal compression stage at a pre-determined feed temperature and pressure and having a pre-determined relative humidity. The process further comprises adding water and heat to the hydrogen gas upstream of the centrifugal compression stage, as required, to humidify the hydrogen gas to the pre-determined relative humidity.Type: GrantFiled: March 15, 2021Date of Patent: March 12, 2024Assignee: AIR PRODUCTS AND CHEMICALS, INC.Inventors: Joseph Gerard Wehrman, Paul Higginbotham, Vincent White
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Publication number: 20240067537Abstract: A combined vessel comprises a stripping section for removing acid gases from a sour water stream and a direct contact heat exchanger section for heating a graywater stream in order to improve heat and mass transfer in the treatment and recycle of water streams for a gasification process.Type: ApplicationFiled: October 20, 2023Publication date: February 29, 2024Applicant: Air Products and Chemicals, Inc.Inventors: Yanlai Zhang, Xukun Luo
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Publication number: 20240053772Abstract: An industrial gas production plant operable to produce a feedstock gas at a variable production rate for supply to the downstream process; and a gas storage resource operable to store produced feedstock gas, the method comprising: determining the pressure of feedstock gas in a supply feed line to the downstream process; selectively controlling, using a control system, a flow of feedstock gas from the supply feed line to the gas storage resource or from the gas storage resource to the supply feed line in response to the determined pressure in order to regulate the pressure of the feedstock gas in the supply feed line to the downstream process at a predetermined set point pressure; and selectively controlling, using a control system, a flow rate of feedstock gas in the supply feed line to the downstream process in dependence upon at least one operational parameter of the gas storage resource.Type: ApplicationFiled: August 12, 2022Publication date: February 15, 2024Applicant: Air Products and Chemicals, Inc.Inventors: ZHONG-XIANG ZHU, DAVID M. ESPIE, GRAEME RICHARD WILSON
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Publication number: 20240052827Abstract: Controlling a capacity of the compression system in response to the variable incoming gas feed by: i) selectively varying a capacity of a first subset of one or more of the compressor trains by continuously varying the capacity of one or more cylinders of the one or more reciprocating compressor stages of the one or more compressor trains of the first subset between a maximum capacity and a minimum capacity; and/or ii) selectively varying a capacity of a second subset of one or more of the compressor trains by fully loading or fully unloading one or more cylinders of the one or more reciprocating compressor stages of the compressor trains of the second subset, wherein the first and second subsets are mutually exclusive.Type: ApplicationFiled: August 12, 2022Publication date: February 15, 2024Applicant: Air Products and Chemicals, Inc.Inventors: ZHONG-XIANG ZHU, DAVID M. ESPIE, GRAEME RICHARD WILSON, GREGORY W. HENZLER
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Patent number: 11897769Abstract: A process for producing syngas that uses the syngas product from an oxygen-fired reformer to provide all necessary heating duties, which eliminates the need for a fired heater. Without the flue gas stream leaving a fired heater, all of the carbon dioxide produced by the reforming process is concentrated in the high-pressure syngas stream, allowing essentially complete carbon dioxide capture.Type: GrantFiled: August 20, 2021Date of Patent: February 13, 2024Assignee: Air Products and Chemicals, Inc.Inventors: Xiang-Dong Peng, Yu Zhang, Tori Dawn Courtney
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Patent number: 11897030Abstract: A method and system for providing cooling to a part formed using high-temperature additive manufacturing process. Infrared sensors or cameras are used to measure sidewall temperatures and, optionally, top layer temperature. Coolant nozzles provide cooling to the sidewalls of the finished layers and, optionally, to the top layer. The coolant intensity of the coolant nozzles is controlled in order to reduce temperature gradients between layers and/or to maintain temperatures in each layer below preferred maximum temperature.Type: GrantFiled: June 8, 2021Date of Patent: February 13, 2024Assignee: Air Products and Chemicals, Inc.Inventors: Liang He, Ranajit Ghosh, Mark Kurt Weise
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Publication number: 20240044738Abstract: Apparatuses and methods for compressed fluid vessel monitoring can permit a user to more easily order replacement vessels, monitor use, monitor inventory and return empty vessels. Embodiments can utilize a collar connectable to a vessel to help facilitate such functionality. The collar can be adapted to transmit signals to a data processing system. The data processing system can be adapted to permit a user to track the location and fill status of the vessel as well as order a replacement vessel and disposal or return of an empty vessel. Instrumented vessels can also convey sensor data to help identify a leak condition or other condition of the vessel. In some embodiments, the data processing system can be adapted for integration into a user's inventory system and/or purchasing system as well as a supplier's system to facilitate communications concerning vessel fill status, reorder, and/or vessel return.Type: ApplicationFiled: August 4, 2022Publication date: February 8, 2024Applicant: Air Products and Chemicals, Inc.Inventors: THOMAS LEE, DAVID BRYANT, THOMAS HOLBECHE, STEPHEN MELLOR, PHIL TRANTER, CSABA ALFOLDI, CRAIG HUNT, MATTHEW ISBELL
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Publication number: 20240035743Abstract: A process for recovering at least one fluid (e.g. argon gas and/or nitrogen gas, etc.) from a feed gas (e.g. air) can provide an improved recovery of argon and/or nitrogen as well as an improvement in operational efficiency. Some embodiments can be adapted so that at least a portion of a mixed nitrogen-oxygen fluid is at least partially vaporized and fed to a low pressure column.Type: ApplicationFiled: August 1, 2022Publication date: February 1, 2024Applicant: Air Products and Chemicals, Inc.Inventors: DONN MICHAEL HERRON, QIAO ZHAO
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Publication number: 20240019123Abstract: A hydrogen injection scheme can be employed via use of one or more injectors for injecting hydrogen to help entrain local mass while also generating local turbulence that can enhance mixing with a mixture of air and fuel to facilitate enhanced lean combustion, lower peak flame temperatures of combustion, and reduce nitrous oxide (NOx) emissions from the combustion of fuel. In some embodiments, the hydrogen can be injected to help transport heat released during combustion away from the injector to help avoid injector overheating as well. Different injectors can be utilized to provide a desired hydrogen injection scheme for a particular set of design and operational criteria for a gas turbine system or at least one combustion system that can be utilized in a gas turbine system.Type: ApplicationFiled: August 2, 2023Publication date: January 18, 2024Applicant: Air Products and Chemicals, Inc.Inventors: Mark Daniel D'Agostini, Anup Vasant Sane
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Publication number: 20240019118Abstract: A burner including a first pulverized coal entrained fluid flow conduit; an inner hydrogen conduit; and a hydrogen oxidant conduit positioned between the first pulverized coal entrained fluid flow conduit and the inner hydrogen conduit; an outlet of the inner hydrogen conduit positioned a first distance from an outlet of the hydrogen oxidant conduit such that hydrogen output from the outlet of the inner hydrogen conduit passes through a portion of the hydrogen oxidant conduit to the outlet of the hydrogen oxidant conduit; and the outlet of the hydrogen oxidant conduit being a second distance from an outlet of the first pulverized coal entrained fluid flow conduit such that the hydrogen and the hydrogen oxidant output from the outlet of the hydrogen oxidant conduit passes through a portion of the first pulverized coal entrained fluid flow conduit for being output from the burner.Type: ApplicationFiled: July 12, 2022Publication date: January 18, 2024Applicant: Air Products and Chemicals, Inc.Inventor: Mark Daniel D'Agostini
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Publication number: 20240009618Abstract: An apparatus and process for use of an alkaline reagent (e.g. sodium hydroxide, NaOH, potassium hydroxide, KOH, etc.) to facilitate removal of carbon dioxide (CO2) from flue gas output from a glass melting operation. The CO2 removed from the flue gas can be in carbonates formed in the reaction of the reagent with the flue gas, which can be used in glass melting operations. A portion of the flue gas can also be liquefied in some embodiments to produce a liquefied CO2 stream for other uses. In some embodiments, a portion of the carbonate generated from the CO2 removal process can be heated (e.g. in an indirect heat exchange process) to liberate the CO2 for feeding the liberated CO2 to a liquefaction process while a resultant oxide formed via the CO2 liberation can be hydrolyzed to regenerate the alkaline reagent for subsequent use in the CO2 removal process.Type: ApplicationFiled: May 19, 2023Publication date: January 11, 2024Applicant: Air Products and Chemicals, Inc.Inventors: Ranajit Ghosh, Mark Daniel D'Agostini
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Publication number: 20240003618Abstract: Systems and methods are described for increasing capacity and efficiency of a nitrogen refrigerant boil-off gas recovery system for a natural gas storage tank. Boil-off gas is condensed against two-phase nitrogen in a condensing heat exchanger having an inner vessel through which the boil-off gas flows and an outer vessel through which the two phase nitrogen flows. Logic controls maintain storage tank pressure and power consumption within preferred levels by adjusting the pressure of the two-phase nitrogen in the heat exchanger. Additional logic controls maintain the temperature difference between the nitrogen streams entering into and returning from the cold end of a second heat exchanger by controlling the position of an expansion valve on the return circuit.Type: ApplicationFiled: July 10, 2023Publication date: January 4, 2024Applicant: Air Products and Chemicals, Inc.Inventors: Mark Julian Roberts, Fei Chen
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Publication number: 20240003539Abstract: A burner including a first burner element having a first annular oxidant nozzle surrounding a first inner fuel nozzle; a second burner element having a second annular oxidant nozzle surrounding a second inner fuel nozzle, the second burner element being positioned adjacent to and spaced apart from the first burner element; a staging nozzle configured to flow secondary oxidant and being positioned adjacent to and spaced apart from the second burner element and separated from the first burner element by the second burner element; wherein the first inner nozzle and the second inner nozzle each have a major axis defined by a length L and a minor axis defined by a height hf; wherein 5<=L/hf<=15; wherein the staging nozzle has a major axis; and wherein the major axes of the first and second inner nozzles and the staging nozzle are substantially parallel with each other.Type: ApplicationFiled: June 30, 2022Publication date: January 4, 2024Applicant: Air Products and Chemicals, Inc.Inventors: Anandkumar Makwana, Anup Vasant Sane, Michael David Buzinski, Xiaoyi He
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Publication number: 20240001288Abstract: Sulfur-containing compounds are removed from crude CO2 by conversion to elemental sulfur in a Claus process and subsequently by hydrogenation of the Claus tail gas to convert residual sulfur-containing compounds into H2S which, after cooling to knock out water and then compressing, is removed, together with any other sulfur-containing impurities, either by physical separation or by chemical reaction with a solid metal oxide to form solid metal sulfide with subsequent oxidative regeneration to produce purified CO2 and a recycle gas comprising at least one sulfur-containing compound which is recycled to the Claus process. Some H2S in the Claus tail gas may be removed initially by selective and/or non-selective amine absorption(s) in a tail gas treatment unit prior to removal of residual H2S and any other residual sulfur-containing impurities by the physical separation or the chemical reaction steps.Type: ApplicationFiled: July 1, 2022Publication date: January 4, 2024Applicant: Air Products and Chemicals, Inc.Inventors: Kamlesh Ghodasara, Paul Higginbotham, Jeffrey R. Hufton, Shubhra Jyoti Bhadra, Maulik R. Shelat
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Publication number: 20240001282Abstract: A method and system for purifying a carbon dioxide feed stream in which the carbon dioxide feed stream is cooled and partially condensed to remove water upstream of an adsorber to produce a dry carbon dioxide stream. The dry carbon dioxide stream is further cooled and partially condensed in a carbon dioxide purification unit to form a carbon dioxide product stream. Excess refrigeration duty from the carbon dioxide purification unit is used to cool the carbon dioxide feed stream.Type: ApplicationFiled: July 1, 2022Publication date: January 4, 2024Applicant: Air Products and Chemicals, Inc.Inventors: Paul Higginbotham, Dingjun Wu, Gowri Krishnamurthy, Todd M. Moyle, Michelle Roaf, Mozhgan Alimohammadi Zanjani
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Publication number: 20240001283Abstract: A method for capturing carbon dioxide from a carbon dioxide feed stream in which the carbon dioxide feed stream is dehydrated, cooled, and partially condensed. The partially condensed carbon dioxide stream is separated to form the carbon dioxide product stream. The carbon dioxide feed stream is produced by combusting a fuel stream with an oxygen-enriched gas stream with less than 92% purity.Type: ApplicationFiled: July 1, 2022Publication date: January 4, 2024Applicant: Air Products and Chemicals, Inc.Inventors: Todd M. Moyle, Paul Higginbotham, Dingjun Wu, Gowri Krishnamurthy, Michelle Roaf, Christer Haugland
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Patent number: 11859903Abstract: A method of constructing a coil wound heat exchange module and transporting and installing the coil wound heat exchange module at a plant site, such as an natural gas liquefaction plant. A module frame is constructed and attached to a heat exchanger shell prior to telescoping of a coil wound mandrel into the shell. The module frame includes a lug and two saddles that remain attached to the shell throughout the process and when the heat exchanger is operated. The lug and saddles are constructed and located to stabilize the shell during construction, telescoping and transport (when in a horizontal orientation), and when the shell is installed at the plant site (in a vertical orientation). The lugs and saddles are adapted to allow for thermal expansion and contraction of the shell when it is transitioned from ambient to operating temperature and vice versa.Type: GrantFiled: June 9, 2022Date of Patent: January 2, 2024Assignee: Air Products and Chemicals, Inc.Inventors: Joseph E. Voda, Adam R. Garcia, Kevin E. Tiemann, Christopher J. Ranella, Paul I. Debrah, John A. Dally