Abstract: An adsorbent for removing CO2 from a gas mixture, the adsorbent comprising alumina and a carbonate compound where the carbonate to alumina IR absorbance intensity ratio is reduced by washing the adsorbent with water. The disclosure also describes a method of making adsorbent particles, process for removing CO2 from a gas mixture using the adsorbent, and an adsorption unit using the adsorbent.

Abstract: Described herein are methods and systems for the liquefaction of a natural gas feed stream using a refrigerant comprising methane. The methods and systems use a refrigeration circuit and cycle that employs two or more turbo-expanders to expand two or more streams of gaseous refrigerant down to different pressures to provide cold streams of at least predominantly gaseous refrigerant at different pressures that are used to provide refrigeration for precooling and liquefying the natural gas. The resulting liquefied natural gas stream is then flashed to produce an LNG product and a flash gas, the flash gas being recycled to the natural gas feed stream.

Abstract: Described herein is a method of removing refrigerant from a natural gas liquefaction system in which vaporized mixed refrigerant is withdrawn from the closed-loop refrigeration circuit and introduced into a distillation column so as to be separated into an overhead vapor enriched in methane and a bottoms liquid enriched in heavier components. Overhead vapor is withdrawn from the distillation column to form a methane enriched stream that is removed from the liquefaction system, and bottoms liquid is reintroduced from the distillation column into the closed-loop refrigeration circuit. Also described are methods of altering the rate of production in a natural gas liquefaction system in which refrigerant is removed as described above, and a natural gas liquefaction systems in which such methods can be carried out.

Abstract: A method of operating a BOF bottom stir tuyere having an inner nozzle surrounded by an annular nozzle, including during a hot metal pour phase and a blow phase, flowing an inert gas through both nozzles; during a tap phase, initiating a flow of a first reactant through the inner nozzle and a flow of a second reactant through the annular nozzle, and ceasing the flow of inert gas through the nozzles, wherein the first and second reactants includes fuel and oxidant, respectively, or vice-versa, such that a flame forms as the fuel and oxidant exit the tuyere; during a slag splash phase, continuing the flows of fuel and oxidant to maintain the flame; and after ending the slag splash phase and commencement of another hot metal pour phase, initiating a flow of inert gas through both nozzles and ceasing the flows of the first and second reactants.

Abstract: A gasification system for the oxidation of a carbonaceous feedstock to provide a synthesis gas comprising: a reactor chamber for oxidizing the carbonaceous feedstock; a quench section for holding a bath of liquid coolant; an intermediate section having a reactor outlet opening through which the synthesis gas is conducted from the reactor chamber into the bath of the quench section; at least one layer of refractory bricks arranged on the reactor chamber floor, the lower end section of the refractory bricks enclosing the reactor outlet opening and defining the inner diameter thereof; the intermediate section including a number of halved tubes for liquid coolant arranged onto at least part of the reactor chamber floor on a side thereof opposite to the lower end section of the refractory bricks; and a pump system for circulating the liquid coolant through the halved tubes on the reactor chamber floor.

Abstract: A method and apparatus for liquefying a natural gas feed stream and removing nitrogen therefrom to produce a nitrogen-depleted LNG product, in which a natural gas feed stream is fed into the warm end of a main heat exchanger, cooled and at least partially liquefied, withdrawn from an intermediate location of the main heat exchanger and separated to form a nitrogen-enriched natural gas vapor stream and a nitrogen-depleted natural gas liquid stream, the liquid and vapor streams being reintroduced into an intermediate location of the main heat exchanger and further cooled in parallel to form a first LNG stream and a first at least partially liquefied nitrogen-enriched natural gas stream, respectively.

Abstract: A gasification reactor comprises a pressure shell; a reaction zone partly bounded by a tubular membrane wall enclosed by the pressure shell; at least one burner having a burner head, said burner head protruding the membrane wall; at least one cooling device arranged in the membrane wall and enclosing the burner head of at least one burner, the at least one cooling device comprising several concentric rings of increasing diameter, forming a truncated cone shape having a largest diameter opening facing the reaction zone and a smallest diameter opening facing the burner head, each ring being a conduit having an inlet and an outlet for a cooling medium, the smallest diameter opening for the burner head being located between the pressure shell and the membrane wall; the cooling device comprising at least one part-circular outer ring having an interruption.

Abstract: A rapid cycle pressure swing adsorption (RCPSA) air purification process, apparatus, and device for the removal of at least one of water, carbon dioxide, nitrous oxide, and one or more hydrocarbons from a feed air stream prior to cryogenic air separation.

Abstract: A gasification system for the partial oxidation of a carbonaceous feedstock to at least provide a synthesis gas, comprising: a reactor chamber for receiving and partially oxidizing the carbonaceous feedstock; a quench chamber below the floor of the reactor chamber for holding a bath of liquid coolant; an intermediate section at said reactor chamber floor, the intermediate section having a reactor outlet opening through which the reactor chamber communicates with the quench chamber to conduct the synthesis gas from the reactor chamber into the bath of the quench chamber; at least one layer of refractory bricks arranged on and supported by the reactor chamber floor, the lower end section of the refractory bricks enclosing the reactor outlet opening and defining the inner diameter thereof; and a dip tube extending from the reactor outlet opening to the bath of the quench chamber, the dip tube having a widened top section.

Abstract: Systems and methods described for increasing capacity and efficiency of natural gas liquefaction processes having a mixed refrigerant precooling system with multiple pressure levels comprising cooling the compressed mixed refrigerant stream and separating the cooled compressed mixed refrigerant stream into a vapor and liquid portion. The liquid portion provides refrigeration duty to a first precooling heat exchanger. The vapor portion is further compressed, cooled, and condensed, and used to provide refrigeration duty to a second precooling heat exchanger. A flash gas separated from the liquefied natural gas is warmed and combined with the natural gas feed stream.

Abstract: Disclosed herein are multi-bed rapid cycle pressure swing adsorption (RCPSA) processes for separating O2 from N2 and/or Ar, wherein the process utilizes at least five adsorption beds each comprising a kinetically selective adsorbent for O2 having an O2 adsorption rate (1/s) of at least 0.20 as determined by linear driving force model at 1 atma and 86° F.

Abstract: A method of operating a furnace having process tubes and multiple burners where it is desired to conform the temperatures of the process tubes to selected target temperature criterion. The present method provides a systematic and quantitative approach to determine how to adjust burner flow rates to result in desired tube wall temperatures, for example, using objective functions to decrease the probability that temperatures pertaining to the plurality of process tubes exceed their selected limit temperatures. An objective function can also be used to reduce the excess oxidant requirement for the furnace.

Abstract: Disclosed herein is a stator plate for a rotary bed PSA apparatus that has an exhaust slot that has first and second sections for receiving blowdown and purge exhaust gas streams, the sections being separated by a flow restriction that restricts but does not full prevent gas flow between the sections, or that has separate exhaust slots for separately receiving the blowdown and purge exhaust gas streams. Also disclosed is pressure swing adsorption (PSA) apparatus including such a stator plate, and a rotary bed PSA process using such an apparatus.

Abstract: Methods and systems for controlling gas atmospheres in three-dimensional laser printing and weld overlay consolidation operations using metallic powders are provided. In one or more embodiments, such systems and methods comprise a printing chamber or laser weld overlay system, a gas supply system, a feed powder system, and one or more sensors employed to control the printing or welding operation. The methods and systems of the invention employ one or more inert gases having a purity greater than or equal to 99.

Abstract: A method and an apparatus for nitriding metal articles, wherein the nitriding potential of the nitriding atmosphere is controlled as a function of the molecular weights of the inlet and outlet gases from the nitriding apparatus, as measured by molecular weight sensors located outside (external to) the furnace chamber.

Abstract: A system and method for increasing the efficiency of natural gas liquefaction processes by using a hybrid cooling system and method. More specifically, a system and method for converting a transcritical precooling refrigeration process to a subcritical process. In one embodiment, the refrigerant is cooled to sub-critical temperature using an economizer. In another embodiment, the refrigerant is cooled to a sub-critical temperature using an auxiliary heat exchanger. Optionally, the economizer or auxiliary heat exchanger can be bypassed when ambient temperatures are sufficiently low to cool the refrigerant to a sub-critical temperature. In another embodiment, the refrigerant is isentropically expanded.

Abstract: Process and apparatus for producing a hydrogen-containing product by steam-hydrocarbon reforming of multiple hydrocarbon feedstocks in a production facility utilizing a prereformer in addition to the primary reformer. The temperature of the reactant mixture introduced into the prereformer is controlled depending on the composition of the reactant mixture fed to the prereformer.

Abstract: A liquefaction system is capable of sequentially or simultaneously liquefying multiple feed streams of hydrocarbons having different normal bubble points with minimal flash. The liquefying heat exchanger has separate circuits for handling multiple feed streams. The feed stream with the lowest normal boiling point is sub-cooled sufficiently to suppress most of the flash. Feed streams with relatively high normal boiling points are cooled to substantially the same temperature, then blended with bypass streams to maintain each product near its normal bubble point. The system can also liquefy one stream at a time by using a dedicated circuit or by allocating the same feed to multiple circuits.

Abstract: A method of melting an aluminum charge having no more that 4% salt by mass, including during a melting phase, introducing fuel and oxidant via a burner operating at a first firing rate, the fuel and oxidant reacting to form a combustion zone above the aluminum charge, terminating the melting phase and commencing a transition phase when the aluminum charge is nearly completely molten, during the transition phase, reducing the firing rate of the burner to a second firing rate lower than the first firing rate, introducing a non-oxidizing gas at a first velocity to form a non-oxidizing zone between the combustion zone and the aluminum charge, and allowing the aluminum charge to become completely molten, and terminating the transition phase and commencing a tapping phase after the aluminum charge has become completely molten, and during the tapping phase, pouring the molten aluminum charge out of the furnace.

Abstract: Systems and methods described for increasing capacity and efficiency of natural gas liquefaction processes having a mixed refrigerant precooling system with multiple pressure levels comprising cooling the compressed mixed refrigerant stream and separating the cooled compressed mixed refrigerant stream into a vapor and liquid portion. The liquid portion provides refrigeration duty to a first precooling heat exchanger. The vapor portion is further compressed, cooled, and condensed, and used to provide refrigeration duty to a second precooling heat exchanger. Optionally additional precooling heat exchangers, and/or phase separators may be used.