Abstract: This invention provides a glassy metal-suction casting method capable of readily and conveniently producing a large-sized amorphous material with excellent properties as an amorphous material. Such an object of the invention is attained by filling a metal material in a mold cooled with water; melting said metal material by using a high-energy heat source which is capable of rapidly melting said metal material; and introducing the resulting molten metal instantaneously into a vertically extending water-cooled mold provided below said mold by using a difference in gas pressure or gravity to move the metal melt at a high speed and attain a high quenching rate to thereby enable the production of a glassy metal ingot of a large size.

Abstract: It is an object of the present invention to provide an amorphous hard magnetic alloy which can be produced by a casting method having a low cooling rate and has a large thickness not achieved by conventional liquid quenching methods, an amorphous hard magnetic casting alloy and a method for producing the amorphous hard magnetic cast alloy.An amorphous hard magnetic alloy in accordance with the present invention has the following general formula:A.sub.x --(Fe.sub.1-a Co.sub.a).sub.y --D.sub.zwherein A represents at least one element selected from the group consisting of Nd, Sm, Pr and Pm; D represents at least one element selected from the group consisting of Al, Ga, and Ge; suffixes x, y, and z satisfy 50.ltoreq.x.ltoreq.75, 10.ltoreq.y.ltoreq.45, and 5.ltoreq.z.ltoreq.15 atomic percent, and suffix a satisfies 0.ltoreq.a.ltoreq.0.5.

Abstract: A hard thin film having fine crystalline ceramic particles dispersed in a metallic matrix phase is disclosed. The production of the film is effected by first depositing a substantially amorphous film on a substrate and then heat-treating the deposited film. Deposition of the film on the substrate is carried out by using a source of evaporation having a composition represented by the general formula: Al.sub.a M.sub.b, wherein M stands for at least one element selected from the group consisting of Ti, Ta, V, Cr, Zr, Nb, Mo, Hf, W, Mn, Fe, Co, Ni, and Cu and "a" and "b" respectively stand for atomic % in the ranges of 60.ltoreq.a.ltoreq.98.5 and 1.5.ltoreq.b.ltoreq.40, providing a+b=100. Deposition is effected by a physical vapor deposition process in an atmosphere of an inert gas containing a reaction gas while controlling the feed rate of the reaction gas into a chamber in such a manner that the partial pressure of the react/on gas is kept constant or varied continuously or stepwise.

Abstract: A catalyst for methanol reforming which consists of an alloy represented by the general formula TM, wherein T is at least one element selected from the group consisting of Ti, Zr, Hf, Y, Nb and Zn; and M is at least one element selected from the group consisting of elements (Cu, Ag and Au) belonging to group IB of the periodic table and elements (Fe, Co, Ni, Ru, Rh, Pd, Os, Ir and Pt) belonging to group VIII of the periodic table, said alloy having a surface comprising an oxide including the element T and, dispersed therein, fine metal particles composed of the element M. The catalyst is produced by preparing an alloy having an amorphous phase and/or a microcrystalline phase from a molten composition of TM, and subsequently heating the alloy at 50.degree. to 700.degree. C. in an oxidizing atmosphere or an atmosphere like that in which methanol reforming is performed. Using the catalyst, methanol reforming can be efficiently performed at relatively low temperatures.

Abstract: A high-strength aluminum-based alloy consisting of a composition represented by the general formula: Al.sub.bal Q.sub.a M.sub.b X.sub.c, wherein Q is at least one element selected from the group consisting of Mn and Cr; M is at least one element selected from the group consisting of Co, Ni, and Cu; X is at least one of rare earth elements including Y, or Misch metal (Mm); and a, b and c are, in atomic percentages, 1.ltoreq.a.ltoreq.7, 0.5.ltoreq.b.ltoreq.5, and 0<c.ltoreq.5, the aluminum-based alloy containing quasicrystals in the structure thereof. The quasicrystals may be of an icosahedral phase (I phase), a decagonal phase (D phase), or a crystalline phase akin thereto and the structure may comprise the quasicrystalline phase and a phase formed of any one of an amorphous phase, aluminum, and a supersaturated aluminum solid solution or a composite (mixed phase) thereof.

Abstract: Alloy powder which is low in price and is unlikely to be oxidized on the surface, and a dispersion-type conductor using the alloy powder in which electromigration is not likely to occur. Melt of copper and silver is cooled at a high cooling speed of 10.sup.5 .degree.C./s or higher. Alloy powder having a composition expressed by a chemical formula Cu.sub.x Ag.sub.1-x (where 0.80.ltoreq..times..ltoreq.0.99) is obtained. Also, a dispersion-type conductor is produced by dispersing 100 parts by weight of the alloy powder in between 5-100 parts by weight of a binder. Thus, the low-priced alloy powder and the dispersion-type conductor of high quality and high reliability can be obtained.

Abstract: A high strength aluminum-based alloy, which having a composition of the general formula: Al.sub.bal Q.sub.a M.sub.b X.sub.c T.sub.d, wherein Q represents at least one element selected from the group consisting of Mn, Cr, V, Mo and W; M represents at least one element selected from the group consisting of Co, Ni, Cu and Fe; X represents at least one element selected from rare earth elements including Y or Mm; T represents at least one element selected from the group consisting of Ti, Zr and Hf; and a, b, c and d represent the following atomic percentages: 1.ltoreq.a.ltoreq.7, 0>5, 0>c.ltoreq.5 and 0>d.ltoreq.2, and contains quasi-crystals in the structure thereof. The alloy of the present invention is excellent in the hardness and strength at both room temperature and a high temperature, and also in thermal resistance and ductility.

Abstract: Ultrafine amorphous metal particles which combine the properties of ultrafine particles with those of an amorphous alloy and a method for the production thereof are disclosed. The ultrafine amorphous metal particles are produced by a method which comprises discharging a plasma arc against a raw metal capable of forming a carbide in a reaction gas using an inert gas as a main component thereof and containing a hydrocarbon gas, and allowing the metal which has been consequently vaporized to contact the reaction gas which has been consequently converted into a plasma, thereby inducing formation of a solid solution of carbon atoms in the vaporized metal and quenching the solid solution in the reaction gas to confer an amorphous structure thereon. As the raw metal, at least one metal selected from the group consisting of Fe, Mo, Nb, Ta, Ti, Zr, Al, Si, and Cr is preferably used.

Abstract: Ultrafine whiskery or columnar ceramic particles, a method for producing the ultrafine particles, and a sintered article obtained by sintering the ultrafine ceramic particles are disclosed. The ultrafine ceramic particles are produced by thermally melting a matrix alloy of a composition of Al--M.sup.1, wherein M.sup.1 stands for at least one metallic element selected from the group consisting of Cr, Co, and Fe, or Al--M.sup.1 --M.sup.2, wherein M.sup.2 stands for at least one metallic element selected from the group consisting of Au, Cu, Dy, Er, Ga, Ge, Gd, Hf, Ho, Lu, Mn, Mo, Nb, Nd, Ni, Pr, Re, Sb, Sc, Si, Sn, Ta, Tb, Ti, Tm, V, W, Y, Zn, or Zr, in a nitriding atmosphere containing nitrogen and causing the vaporized raw material to react with the nitrogen in the atmosphere.

Abstract: A dispersion-strengthened aluminum alloy having a composite structure containing a matrix of .alpha.-aluminum and a precipitation deposited phase of an intermetallic compound with the intermetallic compound in a volume ratio of not more than 35 vol. %, has both high strength and high toughness. The precipitation phase of the intermetallic compound has an aspect ratio of not more than 3.0, the .alpha.-aluminum has a crystal grain size which is at least twice the grain size of the precipitation phase of the intermetallic compound, and the crystal grain size of the .alpha.-aluminum is not more than 200 nm. It is possible to obtain an aluminum alloy having the aforementioned limited structure by carrying out first and second heat treatments on gas-atomized powder containing at least 10 vol. % of an amorphous phase or a green compact thereof and thereafter carrying out hot plastic working.

Abstract: A deformed ultra fine grain is comprised of a spherical body and a tail-like projection projecting from the surface of the spherical body. The tail-like projection exhibits a separating effect on the adjacent deformed ultra fine grains and therefore, aggregation of the ultra fine grains is avoided. Bulk quantities of the deformed ultra fine grains are produced by evaporating a metal by a plasma arc in a controlled atmosphere having a gas that combines with the material of the spherical body to form the tail-like projection.

Abstract: A soft magnetic bulky alloy according to the present invention is obtained by forming under pressure a powder and granule material mainly made of a Fe-M-B based amorphous alloy containing Fe, B and M where M is at least one element selected from a group consisting of Ti, Zr, Hf, V, Nb, Ta, Mo and W. In the soft magnetic bulky alloy, an amorphous alloy phase and a bcc phase with fine grain sizes of 30 nm or below are present in a mixed state, or the bcc phase with fine grain sizes of 30 nm or below is mainly present. The present invention also discloses a method of manufacturing such a soft magnetic bulky alloy.

Abstract: Ultrafine particles of aluminum nitride having a morphologically anisotropic structure of columns, plates, or whiskers such that the ratio of thickness or width to length or the ratio of thickness to width or length of particle is not less than 1 are produced by thermally melting a binary alloy of metallic aluminum and a rare earth element in a nitriding atmosphere containing nitrogen. By this method are produced composite ultrafine particles which substantially comprise ultrafine particles of aluminum nitride having the morphologically anisotropic structure and ultrafine particles of the rare earth nitride which functions as a sintering auxiliary therefor. The composite ultrafine particles or an aggregate thereof are usable as a raw material for the production of a sintered article, a reinforcing material for various metal-based composite materials, a blast powder, and the like.

Abstract: A high-strength aluminum alloy consisting of an amorphous phase containing quasicrystals constituted of aluminum as the principal element, a first additive element consisting of at least one rare earth element and a second additive element consisting of at least one element other than aluminum and rare earth elements, and a crystalline phase consisting of the principal element and the first additive element and the second additive element contained in a supersaturated solid solution form, the amorphous phase containing quasicrystals being contained in a volume percentage of 60 to 90%. The contents of the additive elements preferably fall within a hatched range in the figure, still preferably within a range covered with dot-dash lines in the figure.

Abstract: Alloy powder which is low in price and is unlikely to be oxidized on the surface, and a dispersion-type conductor using the alloy powder in which electromigration is not likely to occur. Melt of copper and silver is cooled at a high cooling speed of 10.sup.5 .degree. C./s or higher. Alloy powder having a composition expressed by a chemical formula Cu.sub.x Ag.sub.1-x (where 0.80.ltoreq.X.ltoreq.0.99) is obtained. Also, a dispersion-type conductor is produced by dispersing 100 parts by weight of the alloy powder in between 5-100 parts by weight of a binder. Thus, the low-priced alloy powder and the dispersion-type conductor of high quality and high reliability can be obtained.

Abstract: A structural member is produced using starting powder consisting of composite particulates each containing AlN grain within its surface covered by an Al layer of a single crystal structure, and Al alloy particulates of a single crystal structure, and then by sintering the Al layers of the composite particulates with the Al alloy particulates. The Al layers and the Al alloy particulates of the single crystal structure have no dislocation fault, crystal grain boundary. etc., produced therein, and for this reason, they have a low chemical activity. Therefore, the Al layers and the like have a characteristic that they are extremely difficult to oxidize. This ensures that the Al layers and the Al alloy particulates can be reliably sintered to achieve the densification of the resulting structural member.

Abstract: Deposition of a hard film of Ti-Si-N composite material on a substrate is carried out by using a source of evaporation possessing a composition of Ti.sub.a Si.sub.b (wherein "a" and "b" stand for atomic percentages respectively falling in the ranges of 75 at % .ltoreq.a.ltoreq.85 at % and 15 at %.ltoreq.b.ltoreq.25 at %, providing a+b=100 at %). Deposition is effected by a sputtering process or ion plating process in an atmosphere of an inert gas containing a nitrogen-containing reaction gas while controlling the feed rate of the reaction gas into a chamber in such a manner that the partial pressure of nitrogen is kept constant or varied continuously or stepwise. By this method there can be obtained a film having fine TiN crystalline particles uniformly dispersed in the matrix phase of Ti-Si amorphous metal or a film of functionally gradient structure in which the ratio of fine TiN crystalline particles dispersed in the matrix phase increases continuously or stepwise in the direction of thickness of the film.

Abstract: Deposition of a hard film of Ti--Si--N composite material on a substrate is carried out by using a source of evaporation possessing a composition of Ti.sub.a Si.sub.b (wherein "a" and "b" stand for atomic percentages respectively falling in the ranges of 75 at %.ltoreq.a.ltoreq.85 at % and 15 at %.ltoreq.b.ltoreq.25 at %, providing a+b=100 at %). Deposition is effected by a sputtering process or ion plating process in an atmosphere of an inert gas containing a nitrogen-containing reaction gas while controlling the feed rate of the reaction gas into a chamber in such a manner that the partial pressure of nitrogen is kept constant or varied continuously or stepwise.

Abstract: A superplastic aluminum-based alloy material consisting of a matrix formed of aluminum or a supersaturated aluminum solid solution, whose average crystal grain size is 0.005 to 1 .mu.m, and particles made of a stable or metastable phase of various intermetallic compounds formed of the main alloying element (i.e., the matrix element) and the other alloying elements and/or of various intermetallic compounds formed of the other alloying elements and distributed evenly in the matrix, the particles having a mean particle size of 0.001 to 0.1 .mu.m. The superplastic aluminum-based alloy material is produced from a rapidly solidified material consisting of an amorphous phase, a microcrystalline phase or a mixed phase thereof by optionally heat treating at a prescribed temperature for a prescribed period of time and then subjecting to a single or combined thermo-mechanical treatment. The superplastic aluminum-based alloy material of the present invention is suited for to superplastic working.

Abstract: A magnetic material consisting essentially of A1 and 10 to 50 at. % of at least one capable of alloying with A1 to form quasicrystals (for example, 5 to 25 at. % of at least one member selected between Cu and Pd and 5 to 35 at. % of Mn) and up to 25 at. % of at least one element having a smaller atomic radius than those of the above elements (for example, B). The magnetic material is produced by adding, to a mixture consisting of A1 and at least one element capable of alloying with A1 to form quasicrystals and including at least one transition metal, at least one element having a smaller atomic radius than those of A1 and the above elements to dissolve the element having a smaller atomic radius in a solid solution form in a quasicrystalline phase. The thus obtained magnetic crystal is useful in various applications, such as magnetic recording heads, and a process for producing the same.