Abstract: A lithium extraction composite comprising: (i) a porous support and (ii) particles of a lithium-selective sorbent material coated on at least one surface of the support, wherein the support has a planar membrane, fiber (or rod), or tubular shape. A method for extracting and recovering a lithium salt from an aqueous solution by use of the above-described composition is also described, the method comprising (a) flowing the aqueous source solution through a first zone or over a first surface of the lithium extraction composite to result in selective lithium intercalation in the lithium-selective sorbent material in the first zone or first surface; and (b) simultaneously recovering lithium salt extracted in step (a) from said lithium-selective sorbent material by flowing an aqueous stripping solution through a second zone or over a second surface of the lithium extraction composite in which lithium ions from the first zone or first surface diffuse.
Type:
Application
Filed:
January 11, 2022
Publication date:
May 5, 2022
Applicants:
UT-Battelle, LLC, All American Lithium LLC
Inventors:
Ramesh R. Bhave, Stephen Harrison, Bruce A. Moyer, M. Parans Paranthaman
Abstract: A lithium extraction composite comprising: (i) a porous support and (ii) particles of a lithium-selective sorbent material coated on at least one surface of the support, wherein the support has a planar membrane, fiber (or rod), or tubular shape. A method for extracting and recovering a lithium salt from an aqueous solution by use of the above-described composition is also described, the method comprising (a) flowing the aqueous source solution through a first zone or over a first surface of the lithium extraction composite to result in selective lithium intercalation in the lithium-selective sorbent material in the first zone or first surface; and (b) simultaneously recovering lithium salt extracted in step (a) from said lithium-selective sorbent material by flowing an aqueous stripping solution through a second zone or over a second surface of the lithium extraction composite in which lithium ions from the first zone or first surface diffuse.
Type:
Grant
Filed:
March 8, 2019
Date of Patent:
February 22, 2022
Assignees:
UT-Battelle, LLC, All American Lithium LLC
Inventors:
Ramesh R. Bhave, Stephen Harrison, Bruce A. Moyer, M. Parans Paranthaman
Abstract: Systems, methods and apparatuses to concentrate lithium containing solutions using forward osmosis units are provided, which, for example, can include providing at least one forward osmosis unit having at least one lithium containing solution chamber having at least one first inlet and at least one first outlet, at least one brine chamber having at least one second inlet and at least one second outlet, and at least one selectively permeable membrane positioned between the at least one lithium containing solution chamber and the at least one brine chamber, and conveying a lithium containing solution through the at least one lithium containing solution chamber and a concentrated brine solution through the at least one brine chamber, said conveying causing water from the lithium containing solution to be drawn through the at least one selectively permeable membrane and into the concentrated brine solution, such that a concentrated lithium containing solution exits through the first outlet and a less concentrated
Type:
Application
Filed:
November 19, 2019
Publication date:
March 19, 2020
Applicant:
All American Lithium LLC
Inventors:
Stephen Harrison, Dennis L. Howe, Brian J. Dougherty
Abstract: This invention relates to a method for preparing a lithium activated alumina intercalate solid by contacting a three-dimensional activated alumina with a lithium salt under conditions sufficient to infuse lithium salts into activated alumina for the selective extraction and recovery of lithium from lithium containing solutions, including brines.
Type:
Grant
Filed:
September 12, 2017
Date of Patent:
June 25, 2019
Assignee:
All American Lithium LLC
Inventors:
Stephen Harrison, C. V. Krishnamohan Sharma, M. Scott Conley