Abstract: A multi-layer article of manufacture includes an intermediate layer of a water-swellable colloidal clay, such as bentonite, sandwiched between two layers of flexible sheet or fabric material wherein the two flexible layers of sheet or fabric material are structurally interconnected through the intermediate clay layer, such as by needle punching, after lubrication of the clay surface with a liquid, such as water, to interconnect fibers of one fabric layer to the other fabric layer at spaced locations over essentially the entire inner surface areas of both sheet or fabric material layers. In a preferred embodiment, a water-insoluble adhesive is applied to at least one of the fabric layers to lock the interconnecting fibers in place and substantially increase the structural integrity, particularly the shear strength, of the article.

Abstract: A multi-layer article of manufacture includes an intermediate layer of a water-swellable colloidal clay, such as bentonite, sandwiched between two layers of flexible sheet or fabric material wherein the two flexible layers of sheet or fabric material are structurally interconnected through the intermediate clay layer, such as by needle punching, after lubrication of the clay with a liquid, such as water, to interconnect fibers of one fabric layer to the other fabric layer at spaced locations over essentially the entire inner surface areas of both sheet or fabric material layers.

Abstract: A shaped, water-expandable water-sealing article used for sealing an area between a first section of at least partially cured concrete and a second, adjacent section of substantially uncured concrete. The clay water sealing article is in the shape of a quadrilateral, preferably a trapezoid, and is disposed to bridge an area between the two sections of concrete. Upon hydration of the clay contained within the shaped water sealing article, expansion of the clay creates expansion forces extending from a corner of the article that is surrounded by the uncured concrete, wherein the corner has an included angle greater than 90.degree., preferably at least 100.degree.. The expansion force developed by the expansion of the shaped water sealing article are absorbed by a substantially increased area of the uncured concrete as compared to expansion forces resulting from a clay-based water seal having a 90.degree. included angle at the corner(s) surrounded by the uncured concrete.

Abstract: Molten metal is cast into a mold cavity formed of sand held in a predetermined mold configuration by a binder comprising a plurality of sodium bentonite clays. A blend of two or more sodium bentonite clays obtained from different areas as a foundry sand binder synergistically and unexpectedly improves the foundry sand used as a mold cavity for casting metal objects by unexpectedly improving one or more of the following foundry sand properties beyond the level of either of the blended sodium bentonites alone: green compressive strength; hot compressive strength; dry compressive strength; wet tensile strength; flowability; surface finish; activation speed and shakeout.

Abstract: A bentonite clay-based polymerization catalyst is manufactured by adhering together a plurality of smaller acid-activated bentonite clay particles, using a strong mineral acid, such as H.sub.2 SO.sub.4, as a binder. An acid-activated bentonite clay having a particle size below about 60 mesh, U.S. Sieve Series, preferably calcium bentonite, having calcium as a predominant exchangeable action, is mixed with a strong mineral acid, preferably H.sub.2 SO.sub.4, and water to form the catalyst. The mixture is subjected to intensive mixing, curing and drying to form strong particles capable of grinding to a desired particle size distribution, e.g., -6 mesh to +60 mesh, U.S. Sieve Series, to form the catalyst. Fines resulting from the grinding step are completely recycled to the intensive mixing stage of the process to achieve 100% yield. Some adjustment of acid content of the mix may be needed to take into account the acid carried into the mix by recycled fines.

Abstract: A composition and method of absorbing animal dross. In one embodiment, the composition comprises discrete particles (about 50 microns to about 3350 microns, preferably about 600 microns to about 3350 microns in size) of a non-compacted water-swellable bentonite clay that effectively absorbs animal dross and simultaneously agglomerates into a sufficiently large and stable mass, thereby permitting physical separation of the soiled and wetted water-swellable bentonite clay particles from discrete particles of the unsoiled and unwetted water-swellable bentonite clay even after partial drying of about 1 to about 24 hours at room temperature, without substantial sticking to animal paws and fur.

Abstract: A method of treating a water-swellable clay, initially having a Fe.sup.+3 /Fe.sup.+2 ratio of at least 1.0, preferably at least 3.0, and most preferably in the range of about 5.0 to about 15.0, after the clay has been mined and dried. After the common initial drying of the clay to a moisture content of 12% or less, the clay is re-wetted to a moisture content of more than 12% by weight, preferably at least about 15% or more, based on the dry weight of the clay, then re-dried to a moisture content of 12% by weight or less, based on the dry weight of the clay.

Abstract: A method of treating a water-swellable clay after the clay has been mined and dried to improve its properties when in contact with salt-contaminated water. After the common initial drying of the clay to a moisture content of 12% by weight or less, the clay is rewetted to a moisture content of more than 12% by weight, preferably at least about 15% or more, based on the dry weight of the clay, then redried to a moisture content of 12% by weight or less, based on the dry weight of the clay.

Abstract: A foundry sand binder composition and method of manufacturing cast metal objects by casting molten metal into a mold cavity formed of sand held in a predetermined mold configuration by a binder comprising a plurality of sodium bentonite clays. A blend of two or more sodium bentonite clays obtained from different areas as a foundry sand binder synergistically and unexpectedly improves the foundry sand used as a mold cavity for casting metal objects by unexpectedly improving one or more of the following foundry sand properties beyond the level of either of the blended sodium bentonites alone: green compressive strength; hot compressive strength; dry compressive strength; wet tensile strength; flowability; surface finish; activation speed and shakeout.

Abstract: A pH-indicating material capable of undergoing a clearly visually detectable color transition at a desired pH, e.g., at a pH at or below about 5.6 and/or at a pH at or above about 7.6. When the pH-indicating material is wetted on its surface with liquid animal dross, particularly animal urine, such as cat urine, the pH-indicating material will undergo a clearly visible color transition at a urine-problematic pH, e.g., acidic or alkaline. The pH-indicating material is maintained on an inert carrier, separate from the cat litter material itself, so that the cat litter material does not chemically interfere with the urine pH-induced color transition provided by the dye(s) in the coating material, and so that the color transition is an exclusive result of the pH of the contacting animal urine, without pH interference from the litter material.

Abstract: A method of manufacturing a water barrier fabric, in flexible or rigid form, and article manufactured thereby, formed by dispersing a water-absorbent material, in powdered or granular form, among a mass of fibers during the formation of a loose mat of said fibers, to homogeneously disperse the powdered or granular water-absorbent material above, below and on each side of the fibers forming the mat, and thereafter densifying and structurally consolidating the mat, to secure the fibers in position surrounding and entrapping the water-absorbent material, such as by sewing, quilting, needle punching or otherwise bonding the fibers into a consolidated, structurally secure fabric at least partially filled with the powdered or granular water-absorbent material.

Abstract: A combustible carbonaceous briquette and method of making the briquette wherein a finely divided carbonaceous material is formed into a desired briquette shape under high pressure whereby carbonaceous particles are bound together by a pre-cooked mixture of an organic binder and a water-swellable clay. The combustible carbonaceous material is present in the briquette composition in an amount of about 85% to about 96% by weight; the organic binder is present in an amount of about 2% to about 8% by weight; and the water-swellable clay is present in an amount of about 1% to about 5% by weight. The weight ratio of organic binder to water-swellable clay, dry weight basis, is in the range of from about 1.5 to about 3.0 to 1.

Abstract: A new and improved, non-porous carbon foundry sand and a method of treating a fluid coke, having a spherical or ovoid particle shape and a size suitable for a coating surface, or a core or mold surface in the foundry industry, wherein the carbon sand is processed by heating the carbon particles at a controlled rate to a temperature in the range of about 1900.degree. F. to about 2300.degree. F. during a period of time preferably of more than about 30 minutes, and preferably for a period of about 1 to 2 hours, particularly to about 2000.degree. F. to about 2200.degree. F., and a method of casting molten metal against the heat treated carbon particles wherein the non-porous carbon foundry sand is combined with a suitable binder with which mixture a mold is formed to cast metal parts. The non-porous carbon sand also is useful in forming molds, cores, shell molds and shell cores and otherwise in using the carbon sand to replace other molding an core-making sands used in the foundry industry.

Abstract: A method of improving the yield of a germinating sod crop and a method of promoting the root formation and the vegetative growth of transplanted sod utilizing an aqueous gel including a highly-absorbent, crosslinked, mixed salt of homopolymerized or copolymerized acrylic acid. The aqueous gel utilized in the method of the present invention demonstrates an improved sod crop yield and improved sod growth even in the absence of plant nutrients.

Abstract: A container having four vertical sides, a top side and a bottom side, the six sides being connected to form a cube. The six sides are joined at the edges of the cube, and the juncture of one vertical edge with two upper edges forms a slanted surface. A pouring spout is mounted on the slanted surface and is inset from the planes of the adjacent sides so that it does not interfere with nesting and stacking. A handle is attached to the top side, at approximately its center, for carrying purposes, the handle being foldable to a flat position to facilitate stacking. The container is formed by cutting a blank from a flat sheet of relatively stiff material, and folding the blank along creases to form a closed container. The top and four sides are folded and sealed first, the pouring spout is installed, the container is filled through the open bottom side, and then the bottom side is folded and sealed.

Abstract: A flexible or rigid panel, and method of making the panel, useful as a water barrier including an intermediate layer of a water-swellable colloidal clay, such as pentonite, sandwiched between two layers of sheet material, such as woven or non-woven fabric, or paperboard, wherein at least one of the sheet material layers has a water-soluble coating material covering substantially the entire outer surface of the sheet material layer. The water-soluble coating is a material that dissolves upon a predetermnined water contact period, having a controlled, predetermined water-solubility so that the intermediate water-swellable clay layer is protected against hydration during installation.

Abstract: A multi-layer article of manufacture includes an intermediate layer of a water-swellable colloidal clay, such as bentonite, sandwiched between two layers of flexible sheet or fabric material wherein the two flexible layers of sheet or fabric material are structurally interconnected through the intermediate clay layer, such as by needle punching, after lubrication of the clay with a liquid, such as water, to interconnect fibers of one fabric layer to the other fabric layer at spaced locations over essentially the entire inner surface areas of both sheet or fabric material layers.

Abstract: An article of manufacture including an elongate confined mass of a water-swellable clay for sealing joints or seams between adjacent water-barrier materials or for plugging defects or other unsealed areas adjacent to a water-barrier layer. The elongate, confined mass of water-swellable clay is manufactured in any desired cross-sectional shape or configuration e.g. circular, eliptical, rectangular, square, and the like and can be manufactured in roll form for dispensing individual confined masses of water-swellable clay individually. The water-swellable clay is confined within a layer of material that permits the entrance of water to contact the water-swellable clay for hydration of the clay, such as by being water-porous or water-soluble and such that upon sufficient hydration of the confined mass of water-swellable clay, the confining layer will dissolve sufficiently, burst or tear to permit relatively free movement of the hydrating and expanding water-swellable clay.

Abstract: A method of increasing the nutritional value of mycotoxin-contaminated animal feed ingested by an animal by feeding the animal a montmorillonite clay simultaneously with the mycotoxin-contaminated animal feed. The montmorillonite clay can be fed to the animal in any form, e.g. granular, powder, pellets and the like or can be admixed with other animal food or feed supplements, so long as the clay is present in the animal's stomach (digestive tract) at the same time as the mycotoxin-contaminated animal feed in an amount sufficient to absorb or adsorb mycotoxin from the digestive tract of the animal and thereby aid the animal in metabolic absorbtion of nutrients from the contaminated animal feed.

Abstract: An article of manufacture and method for holding and treating water contaminated with one or more water-soluble contaminants to substantially prevent the contaminants from seeping into ground water supplies disposed below a water hold area. The article of manufacture and method include the use of a water-holding material, e.g., a water-swellable clay, such as bentonite, for reducing the permeation of the contaminated water into the soil, and a treatment layer, disposed beneath the water-holding material, containing a material capable of adsorbing, absorbing, ion-exchanging, neutralizing or reacting with one or more water-soluble contaminants within the water for removing a substantial portion of the contaminants from the water so that the portion of the held water that permeates the water-holding layer, will be rendered substantially less contaminated.