Abstract: Provided in one embodiment is a cured absorbent composite comprising: liquid resistant layer of elastomer; and a layer affixed to the liquid resistant layer comprising an open foam of elastomer, wherein the moisture absorption capacity of the foam layer, normalized by the thickness of the absorptive layer, is 1.5 times that of Ansell's foam lined Household glove.

Abstract: The present disclosure provides an anti-infective protector containing at least one anti-infective agent. The anti-infective protector provides for a range of benefits not appreciated in the prior art.

Abstract: Lightweight robust flexible gloves having an 18 gauge knitted liner and a polymeric coating disposed thereon and optionally including knitted reinforcement sections at areas of high stretch and/or movement are provided. Reinforcement sections can be formed by plaiting, using yarns of the same or lighter denier, and/or forming Jacquard or transfer stitches.

Abstract: The present disclosure provides an anti-infective protector containing at least one anti-infective agent. The anti-infective protector provides for a range of benefits not appreciated in the prior art.

Abstract: Provided in one embodiment is a cured absorbent composite comprising: liquid resistant layer of elastomer; and a layer affixed to the liquid resistant layer comprising an open foam of elastomer, wherein the moisture absorption capacity of the foam layer, normalized by the thickness of the absorptive layer, is 1.5 times that of Ansell's foam lined Household glove.

Abstract: A synthetic polyisoprene latex emulsion has pre-vulcanization composition and post vulcanization composition. The pre-vulcanization composition comprises soluble sulfur with high S8 ring structure that is catalytically broken by a zinc dithiocarbamate. Surfactants present in the pre-vulcanization composition wets synthetic polyisoprene particles and permeates small sized sulfur and accelerator molecules into the interior of these particles thereby pre-vulcanizing the particles. The degree of pre-vulcanization is verified by isopropanol index test. The latex emulsion has post-vulcanization composition with accelerators that crosslink inter-particle region during post vulcanization cure cycle. The dipped synthetic polyisoprene article is substantially uniformly cured both in the inter-particle and intra-particle regions and reliably exhibits high cross link density, uniform distribution of double bonds in TEM and zinc segregation at the boundaries or original particles by electron microprobe analysis.

Abstract: A glove comprising an elastomeric coating with a particle filler and a method of making such a glove. Specifically, the glove comprises a knitted liner formed from at least one yarn; a elastomeric coating covering at least a portion of the knitted liner; and wherein the elastomeric coating comprises a filler particle having a hardness greater than the hardness of the elastomeric coating.

Abstract: A synthetic polyisoprene latex emulsion has pre-vulcanization composition and post vulcanization composition. The pre-vulcanization composition comprises soluble sulfur with high S8 ring structure that is catalytically broken by a zinc dithiocarbamate. Surfactants present in the pre-vulcanization composition wets synthetic polyisoprene particles and permeates small sized sulfur and accelerator molecules into the interior of these particles thereby pre-vulcanizing the particles. The degree of pre-vulcanization is verified by isopropanol index test. The latex emulsion has post-vulcanization composition with accelerators that crosslink inter-particle region during post vulcanization cure cycle. The dipped synthetic polyisoprene article is substantially uniformly cured both in the inter-particle and intra-particle regions and reliably exhibits high cross link density, uniform distribution of double bonds in TEM and zinc segregation at the boundaries or original particles by electron microprobe analysis.

Abstract: A synthetic polyisoprene latex emulsion has pre-vulcanization composition and post vulcanization composition. The pre-vulcanization composition comprises soluble sulfur with high S8 ring structure that is catalytically broken by a zinc dithiocarbamate. Surfactants present in the pre-vulcanization composition wets synthetic polyisoprene particles and permeates small sized sulfur and accelerator molecules into the interior of these particles thereby pre-vulcanizing the particles. The degree of pre-vulcanization is verified by isopropanol index test. The latex emulsion has post-vulcanization composition with accelerators that crosslink inter-particle region during post vulcanization cure cycle. The dipped synthetic polyisoprene article is substantially uniformly cured both in the inter-particle and intra-particle regions and reliably exhibits high cross link density, uniform distribution of double bonds in TEM and zinc segregation at the boundaries or original particles by electron microprobe analysis.

Abstract: Provided among other things is a fabric comprising: a HPPE base fabric; coated thereon a primer polymer; and coated on the primer polymer a liquid-resistant polymer layer. The primer polymer can be a polyurethane. The base fabric can comprise an adhesion promoter that can be a plasticizer. The adhesion promoter can be a sulfonic acid plasticizer. The adhesion promoter can contain an active hydrogen, carboxy, carboxyloxy or acid group. The fabric can comprise, coated on the liquid-resistant polymer layer, an additional polymer layer. The additional polymer layer can comprise carnauba wax in an amount from about 1 to 3% Phr. The liquid-resistant polymer layer can be a NBR layer. In certain embodiments, the fabric shows no delamination of the liquid-resistant polymer layer after an adherence test. The primer layer can be a polyurethane layer. These features can be present in any combination.

Abstract: A synthetic polyisoprene latex emulsion has pre-vulcanization composition and post vulcanization composition. The pre-vulcanization composition comprises soluble sulfur with high S8 ring structure that is catalytically broken by a zinc dithiocarbamate. Surfactants present in the pre-vulcanization composition wets synthetic polyisoprene particles and permeates small sized sulfur and accelerator molecules into the interior of these particles thereby pre-vulcanizing the particles. The degree of pre-vulcanization is verified by isopropanol index test. The latex emulsion has post-vulcanization composition with accelerators that crosslink inter-particle region during post vulcanization cure cycle. The dipped synthetic polyisoprene article is substantially uniformly cured both in the inter-particle and intra-particle regions and reliably exhibits high cross link density, uniform distribution of double bonds in TEM and zinc segregation at the boundaries or original particles by electron microprobe analysis.

Abstract: Lightweight robust flexible gloves having an 18 gauge knitted liner and a polymeric coating disposed thereon and optionally including knitted reinforcement sections at areas of high stretch and/or movement are provided. Reinforcement sections can be formed by plaiting, using yarns of the same or lighter denier, and/or forming Jacquard or transfer stitches.

Abstract: A latex glove article with a fibrous coating bonded to the skin-contacting surface. Long length soft moisture absorbing fibers are attached to latex layer of a glove with a thin layer of polymeric latex adhesive forming a fibrous lining. The long length fibers extend or project from the polymeric latex adhesive coating. The fibers penetrate the polymeric latex adhesive layer at one end or both end of the fiber to a depth of about 60% to about 100% of the adhesive thickness, leaving a substantial portion of the fiber available for soft contact with skin and sweat absorption. Due to the substantial thickness of the fibrous lining, which is between about 4 and about 100 times the thickness of the thin layer of polymeric latex adhesive, an air gap is created between skin and the impervious latex layer establishing continual evaporation of absorbed sweat and evaporative cooling.

Abstract: A glove comprising an elastomeric coating with a particle filler and a method of making such a glove. Specifically, the glove comprises a knitted liner formed from at least one yarn; a elastomeric coating covering at least a portion of the knitted liner; and wherein the elastomeric coating comprises a filler particle having a hardness greater than the hardness of the elastomeric coating.

Abstract: A cut resistant chemical handling glove that is flexible and lightweight comprises a cured, liquid-impervious polymeric latex shell. A tacky acrylic adhesive with low shear strength can be used. A cut resistant liner is slipped on the tacky adhesive coating and is infiltrated with a polymeric latex coating and cured to integrally attach the cut resistant liner with the cured polymeric coating. When the latex glove is worn on a hand and a cutting edge, such as a knife edge, contacts the glove, a crease is formed due to slip at the tacky adhesive-cut resistant liner interface creating a geometry that reduces cut stress intensity at the knife-edge thereby increasing the cut resistance of the glove. Processes for making and using these gloves are also described.

Abstract: A glove including a knitted liner having a thickness of about 0.70 mm to about 0.90 mm and a plurality of stitches made from a first yarn having a denier of 221 or less, the knitted liner comprising a plurality of finger components, a thumb component, and a palm component, at least one reinforcement section located at a base of at least one finger component, at a base of the thumb component, or in the palm component, or combinations thereof, and a foamed polymeric latex coating adhered to the knitted liner, the foamed polymeric latex coating penetrating half way or more for at least a portion of the knitted liner, the foamed polymeric latex coating not penetrating the entire thickness of the knitted liner.

Abstract: Latex articles with geometrically defined surface structure providing enhanced grip characteristics in dry, wet or oily environment; and a method of making same comprising applying a polymeric coagulant coating to a smooth former surface, wherein the coating becomes tacky during drying, applying discrete coagulant particles of selected size, shape and distribution to the tacky coating to attach and protrude from the former surface with the polymeric coagulant coating, dipping the former into an aqueous latex emulsion, wherein the polymeric coagulant coating and the discrete coagulating particles destabilize the latex, thereby developing a latex layer, vulcanizing and stripping the latex article inside out, and dissolving the discrete coagulant particles in water or suitable solvents to reveal the geometrically designed texture with pre-selected size, shape and distribution of impressions providing improved dry, wet and oily surface grip by removal of a fluid boundary layer.

Abstract: Provided among other things is a fabric comprising: a HPPE base fabric; coated thereon a primer polymer; and coated on the primer polymer a liquid-resistant polymer layer. The primer polymer can be a polyurethane. The base fabric can comprise an adhesion promoter that can be a plasticizer. The adhesion promoter can be a sulfonic acid plasticizer. The adhesion promoter can contain an active hydrogen, carboxy, carboxyloxy or acid group. The fabric can comprise, coated on the liquid-resistant polymer layer, an additional polymer layer. The additional polymer layer can comprise carnauba wax in an amount from about 1 to 3% Phr. The liquid-resistant polymer layer can be a NBR layer. In certain embodiments, the fabric shows no delamination of the liquid-resistant polymer layer after an adherence test. The primer layer can be a polyurethane layer. These features can be present in any combination.

Abstract: A synthetic polyisoprene latex emulsion has pre-vulcanization composition and post vulcanization composition. The pre-vulcanization composition comprises soluble sulfur with high S8 ring structure that is catalytically broken by a zinc dithiocarbamate. Surfactants present in the pre-vulcanization composition wets synthetic polyisoprene particles and permeates small sized sulfur and accelerator molecules into the interior of these particles thereby pre-vulcanizing the particles. The degree of pre-vulcanization is verified by isopropanol index test. The latex emulsion has post-vulcanization composition with accelerators that crosslink inter-particle region during post vulcanization cure cycle. The dipped synthetic polyisoprene article is substantially uniformly cured both in the inter-particle and intra-particle regions and reliably exhibits high cross link density, uniform distribution of double bonds in TEM and zinc segregation at the boundaries or original particles by electron microprobe analysis.

Abstract: An article comprising at least one cured, liquid-impervious polymeric shell substantially free from defects, at least one liner, and a non-tacky, thermoplastic adhesive layer between the shell and the liner, wherein the adhesive layer is melted and solidified to create a non-tacky bond between the shell and the liner, which can be moisture-absorbing or cut-resistant, whereby the liner supports and limits stretch ability of the shell, thereby preventing adhesive delamination between the adhesive layer and either of the shell and/or the liner; a method for the manufacture of an article comprising a supported, polymeric shell, such as a glove, a gauntlet, an apron, or a boot, comprising providing a cured, liquid-impervious, polymeric shell, providing a knitted/woven liner, incorporating a non-tacky, thermoplastic adhesive layer between the shell and the liner, such as by hot-melt spraying, dry-powder spraying or fiber-coating, creating intimate contact between the shell, the adhesive layer, and the liner, subjec