Patents Assigned to Apollo Environmental Systems Corp.
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Patent number: 6627110Abstract: Hydrogen sulfide is removed from gas streams by reaction with sulfur dioxide to produce sulfur. The reaction is effected in a reaction medium comprising a non-aqueous Lewis base with a pKb value of about 6 to about 11.Type: GrantFiled: November 12, 1999Date of Patent: September 30, 2003Assignee: Apollo Environmental Systems Corp.Inventors: James W. Smith, Silvano Meffe, Peter S. Walton, David T. R. Ellenor
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Patent number: 6096280Abstract: Hydrogen sulfide is removed from gas streams by reaction with sulfur dioxide in an autogeneously-formed aqueous acid medium according to the equation: SO.sub.2 +2H.sub.2 S.fwdarw.2H.sub.2 O+3S the sulfur being removed from the aqueous phase. Carbonyl sulfide and/or carbon disulfide is removed from gas streams by hydrolysis to hydrogen sulfide in the presence of a weak organic base catalyst, such as quinoline, with the hydrogen sulfide reacting with sulfur dioxide to form sulfur.Type: GrantFiled: July 15, 1998Date of Patent: August 1, 2000Assignee: Apollo Environmental Systems Corp.Inventors: David T. R. Ellenor, Silvano Meffe, James W. Smith, Peter S. Walton
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Patent number: 5730784Abstract: Hydrogen Sulfide is substantially completely removed from a gas stream in a two-stage operation. Hydrogen Sulfide is first partially oxidized to sulfur dioxide and the sulfur dioxide reacted with part of the remaining hydrogen sulfide while the hydrogen sulfide not so reacted is subsequently oxidized, thereby removing all of the hydrogen sulfide from the gas stream.Type: GrantFiled: June 5, 1995Date of Patent: March 24, 1998Assignees: The University of Toronto Innovations Foundation, Apollo Environmental Systems Corp.Inventors: James W. Smith, David Todd R. Ellenor, John N. Harbinson
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Patent number: 5585005Abstract: Components, usually but not exclusively gaseous components, are removed in a liquid medium from gas streams and chemically converted into an insoluble phase or physically removed. Specifically, hydrogen sulfide may be removed from gas streams by oxidation in aqueous chelated transition metal solution in a agitated flotation cell. The same principal may be employed with other procedures in which a gaseous phase is dispersed in a liquid phase to effect an interaction between components present in such phases, for example, to treat or strip or react a component of the liquid phase.Type: GrantFiled: June 5, 1995Date of Patent: December 17, 1996Assignees: University of Toronto Innovations Foundation, Apollo Environmental Systems Corp.Inventors: James W. Smith, David T. R. Ellenor, John N. Harbinson
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Patent number: 5568736Abstract: The invention comprises a non-restrictive, constant pressure refrigerant recycling and cooling unit that interrupts the normal refrigerant cycle to permit a lower temperature liquid to enter the expansion device, and thus provide a lower temperature, and therefore a lower pressure gas for delivery to the inlet side of the compressor, which acts to reduce the energy requirement and cost to operate the compressor. This reduction in pressure and temperature also results in lower operating costs and lower maintenance costs and utilizes less refrigerant quantity requirements.Type: GrantFiled: October 27, 1994Date of Patent: October 29, 1996Assignee: Apollo Environmental Systems Corp.Inventor: Jerry W. Nivens
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Patent number: 5520818Abstract: Components, usually but not exclusively gaseous components, are removed in a liquid medium from gas streams and chemically converted into an insoluble phase or physically removed. Specifically, hydrogen sulfide may be removed from gas streams by oxidation in aqueous chelated transition metal solution in a modified agitated flotation cell. The same principal may be employed in other procedures in which a gaseous phase is dispersed in a liquid phase to effect an interaction between components present in such phases. A gas-liquid contact apparatus, generally a combined chemical reactor and solid product separation device, comprising such modified agitated flotation cell is also described. In order to effect mass transfer and rapid reaction gas bubbles containing hydrogen sulfide and oxygen are formed by rotating an impeller at a blade tip velocity of at least about 350 in/sec. to achieve the required shear.Type: GrantFiled: November 29, 1994Date of Patent: May 28, 1996Assignees: The University of Toronto Innovations Foundation, Apollo Environmental Systems Corp.Inventors: James W. Smith, David T. R. Ellenor, John N. Harbinson
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Patent number: 5500130Abstract: Components, usually but not exclusively gaseous components, are removed in a liquid medium from gas streams and chemically converted into an insoluble phase or physically removed. Specifically, hydrogen sulfide may be removed from gas streams by oxidation in aqueous chelated transition metal solution in a modified agitated flotation cell. The same principal may be employed in other procedures in which a gaseous phase is dispersed in a liquid phase to effect an interaction between components present in such phases. A gas-liquid contact apparatus, generally a combined chemical reactor and solid product separation device, comprising such modified agitated flotation cell is also described. In order to effect mass transfer and rapid reaction gas bubbles containing hydrogen sulfide and oxygen are formed by rotating an impeller at a blade tip velocity of at least about 350 in/sec. to achieve the required shear.Type: GrantFiled: June 5, 1995Date of Patent: March 19, 1996Assignee: The University of Toronto Innovations Foundation and Apollo Environmental Systems Corp.Inventors: James W. Smith, David T. R. Ellenor, John N. Harbinson
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Patent number: 5500135Abstract: Components, usually but not exclusively gaseous components, are removed in a liquid medium from gas streams and chemically converted into an insoluble phase or physically removed. Specifically, hydrogen sulfide may be removed from gas streams by oxidation in aqueous chelated transition metal solution in a modified agitated flotation cell. The same principal may be employed in other procedures in which a gaseous phase is dispersed in a liquid phase to effect an interaction between components present in such phases. A gas-liquid contact apparatus, generally a combined chemical reactor and solid product separation device, comprising such modified agitated flotation cell is also described. In order to effect mass transfer and rapid reaction gas bubbles containing hydrogen sulfide and oxygen are formed by rotating an impeller at a blade tip velocity of at least about 350 in/sec. to achieve the required shear.Type: GrantFiled: June 5, 1995Date of Patent: March 19, 1996Assignees: The University of Toronto Innovations Foundation, Apollo Environmental Systems Corp.Inventors: James W. Smith, David T. R. Ellenor, John N. Harbinson
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Patent number: 5413765Abstract: Components, usually but not exclusively gaseous components, are removed in a liquid medium from gas streams and chemically converted into an insoluble phase or physically removed. Specifically, hydrogen sulfide may be removed from gas streams by oxidation in aqueous chelated transition metal solution in a modified agitated flotation cell. The same principle may be employed with other procedures in which a gaseous phase is dispersed in a liquid phase to effect an interaction between components present in such phases. A gas-liquid contact apparatus, generally a combined chemical reactor and solid product separation device, comprising such modified agitated flotation cell also is described. In order to effect efficient mass transfer and rapid reaction, gas bubbles containing hydrogen sulfide and oxygen are formed by rotating an impeller at a blade tip velocity of at least about 350 in/sec. to achieve the required shear.Type: GrantFiled: April 20, 1994Date of Patent: May 9, 1995Assignees: Apollo Environmental Systems Corp., University of Toronto Innovations FoundationInventors: James W. Smith, David T. R. Ellenor, John N. Harbinson
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Patent number: 5352421Abstract: Components, usually but not exclusively gaseous components, are removed in a liquid medium from gas streams and chemically converted into an insoluble phase or physically removed. Specifically, hydrogen sulfide may be removed from gas streams by oxidation in aqueous chelated transition metal solution in a modified agitated flotation cell. The same principle may be employed with other procedures in which a gaseous phase is dispersed in a liquid phase to effect an interaction between components present in such phases. A gas-liquid contact apparatus, generally a combined chemical reactor and solid product separation device, comprising such modified agitated flotation cell also is described. In order to effect efficient mass transfer and rapid reaction, gas bubbles containing hydrogen sulfide and oxygen are formed by rotating an impeller at a blade tip velocity of at least about 350 in/sec. to achieve the required shear.Type: GrantFiled: April 3, 1992Date of Patent: October 4, 1994Assignees: University of Toronto Innovations Foundation, Apollo Environmental Systems Corp.Inventors: James W. Smith, David T. R. Ellenor, John N. Harbinson