Patents Assigned to Apollo Environmental Systems Corp.
  • Patent number: 6627110
    Abstract: Hydrogen sulfide is removed from gas streams by reaction with sulfur dioxide to produce sulfur. The reaction is effected in a reaction medium comprising a non-aqueous Lewis base with a pKb value of about 6 to about 11.
    Type: Grant
    Filed: November 12, 1999
    Date of Patent: September 30, 2003
    Assignee: Apollo Environmental Systems Corp.
    Inventors: James W. Smith, Silvano Meffe, Peter S. Walton, David T. R. Ellenor
  • Patent number: 6096280
    Abstract: Hydrogen sulfide is removed from gas streams by reaction with sulfur dioxide in an autogeneously-formed aqueous acid medium according to the equation: SO.sub.2 +2H.sub.2 S.fwdarw.2H.sub.2 O+3S the sulfur being removed from the aqueous phase. Carbonyl sulfide and/or carbon disulfide is removed from gas streams by hydrolysis to hydrogen sulfide in the presence of a weak organic base catalyst, such as quinoline, with the hydrogen sulfide reacting with sulfur dioxide to form sulfur.
    Type: Grant
    Filed: July 15, 1998
    Date of Patent: August 1, 2000
    Assignee: Apollo Environmental Systems Corp.
    Inventors: David T. R. Ellenor, Silvano Meffe, James W. Smith, Peter S. Walton
  • Patent number: 5730784
    Abstract: Hydrogen Sulfide is substantially completely removed from a gas stream in a two-stage operation. Hydrogen Sulfide is first partially oxidized to sulfur dioxide and the sulfur dioxide reacted with part of the remaining hydrogen sulfide while the hydrogen sulfide not so reacted is subsequently oxidized, thereby removing all of the hydrogen sulfide from the gas stream.
    Type: Grant
    Filed: June 5, 1995
    Date of Patent: March 24, 1998
    Assignees: The University of Toronto Innovations Foundation, Apollo Environmental Systems Corp.
    Inventors: James W. Smith, David Todd R. Ellenor, John N. Harbinson
  • Patent number: 5585005
    Abstract: Components, usually but not exclusively gaseous components, are removed in a liquid medium from gas streams and chemically converted into an insoluble phase or physically removed. Specifically, hydrogen sulfide may be removed from gas streams by oxidation in aqueous chelated transition metal solution in a agitated flotation cell. The same principal may be employed with other procedures in which a gaseous phase is dispersed in a liquid phase to effect an interaction between components present in such phases, for example, to treat or strip or react a component of the liquid phase.
    Type: Grant
    Filed: June 5, 1995
    Date of Patent: December 17, 1996
    Assignees: University of Toronto Innovations Foundation, Apollo Environmental Systems Corp.
    Inventors: James W. Smith, David T. R. Ellenor, John N. Harbinson
  • Patent number: 5568736
    Abstract: The invention comprises a non-restrictive, constant pressure refrigerant recycling and cooling unit that interrupts the normal refrigerant cycle to permit a lower temperature liquid to enter the expansion device, and thus provide a lower temperature, and therefore a lower pressure gas for delivery to the inlet side of the compressor, which acts to reduce the energy requirement and cost to operate the compressor. This reduction in pressure and temperature also results in lower operating costs and lower maintenance costs and utilizes less refrigerant quantity requirements.
    Type: Grant
    Filed: October 27, 1994
    Date of Patent: October 29, 1996
    Assignee: Apollo Environmental Systems Corp.
    Inventor: Jerry W. Nivens
  • Patent number: 5520818
    Abstract: Components, usually but not exclusively gaseous components, are removed in a liquid medium from gas streams and chemically converted into an insoluble phase or physically removed. Specifically, hydrogen sulfide may be removed from gas streams by oxidation in aqueous chelated transition metal solution in a modified agitated flotation cell. The same principal may be employed in other procedures in which a gaseous phase is dispersed in a liquid phase to effect an interaction between components present in such phases. A gas-liquid contact apparatus, generally a combined chemical reactor and solid product separation device, comprising such modified agitated flotation cell is also described. In order to effect mass transfer and rapid reaction gas bubbles containing hydrogen sulfide and oxygen are formed by rotating an impeller at a blade tip velocity of at least about 350 in/sec. to achieve the required shear.
    Type: Grant
    Filed: November 29, 1994
    Date of Patent: May 28, 1996
    Assignees: The University of Toronto Innovations Foundation, Apollo Environmental Systems Corp.
    Inventors: James W. Smith, David T. R. Ellenor, John N. Harbinson
  • Patent number: 5500130
    Abstract: Components, usually but not exclusively gaseous components, are removed in a liquid medium from gas streams and chemically converted into an insoluble phase or physically removed. Specifically, hydrogen sulfide may be removed from gas streams by oxidation in aqueous chelated transition metal solution in a modified agitated flotation cell. The same principal may be employed in other procedures in which a gaseous phase is dispersed in a liquid phase to effect an interaction between components present in such phases. A gas-liquid contact apparatus, generally a combined chemical reactor and solid product separation device, comprising such modified agitated flotation cell is also described. In order to effect mass transfer and rapid reaction gas bubbles containing hydrogen sulfide and oxygen are formed by rotating an impeller at a blade tip velocity of at least about 350 in/sec. to achieve the required shear.
    Type: Grant
    Filed: June 5, 1995
    Date of Patent: March 19, 1996
    Assignee: The University of Toronto Innovations Foundation and Apollo Environmental Systems Corp.
    Inventors: James W. Smith, David T. R. Ellenor, John N. Harbinson
  • Patent number: 5500135
    Abstract: Components, usually but not exclusively gaseous components, are removed in a liquid medium from gas streams and chemically converted into an insoluble phase or physically removed. Specifically, hydrogen sulfide may be removed from gas streams by oxidation in aqueous chelated transition metal solution in a modified agitated flotation cell. The same principal may be employed in other procedures in which a gaseous phase is dispersed in a liquid phase to effect an interaction between components present in such phases. A gas-liquid contact apparatus, generally a combined chemical reactor and solid product separation device, comprising such modified agitated flotation cell is also described. In order to effect mass transfer and rapid reaction gas bubbles containing hydrogen sulfide and oxygen are formed by rotating an impeller at a blade tip velocity of at least about 350 in/sec. to achieve the required shear.
    Type: Grant
    Filed: June 5, 1995
    Date of Patent: March 19, 1996
    Assignees: The University of Toronto Innovations Foundation, Apollo Environmental Systems Corp.
    Inventors: James W. Smith, David T. R. Ellenor, John N. Harbinson
  • Patent number: 5413765
    Abstract: Components, usually but not exclusively gaseous components, are removed in a liquid medium from gas streams and chemically converted into an insoluble phase or physically removed. Specifically, hydrogen sulfide may be removed from gas streams by oxidation in aqueous chelated transition metal solution in a modified agitated flotation cell. The same principle may be employed with other procedures in which a gaseous phase is dispersed in a liquid phase to effect an interaction between components present in such phases. A gas-liquid contact apparatus, generally a combined chemical reactor and solid product separation device, comprising such modified agitated flotation cell also is described. In order to effect efficient mass transfer and rapid reaction, gas bubbles containing hydrogen sulfide and oxygen are formed by rotating an impeller at a blade tip velocity of at least about 350 in/sec. to achieve the required shear.
    Type: Grant
    Filed: April 20, 1994
    Date of Patent: May 9, 1995
    Assignees: Apollo Environmental Systems Corp., University of Toronto Innovations Foundation
    Inventors: James W. Smith, David T. R. Ellenor, John N. Harbinson
  • Patent number: 5352421
    Abstract: Components, usually but not exclusively gaseous components, are removed in a liquid medium from gas streams and chemically converted into an insoluble phase or physically removed. Specifically, hydrogen sulfide may be removed from gas streams by oxidation in aqueous chelated transition metal solution in a modified agitated flotation cell. The same principle may be employed with other procedures in which a gaseous phase is dispersed in a liquid phase to effect an interaction between components present in such phases. A gas-liquid contact apparatus, generally a combined chemical reactor and solid product separation device, comprising such modified agitated flotation cell also is described. In order to effect efficient mass transfer and rapid reaction, gas bubbles containing hydrogen sulfide and oxygen are formed by rotating an impeller at a blade tip velocity of at least about 350 in/sec. to achieve the required shear.
    Type: Grant
    Filed: April 3, 1992
    Date of Patent: October 4, 1994
    Assignees: University of Toronto Innovations Foundation, Apollo Environmental Systems Corp.
    Inventors: James W. Smith, David T. R. Ellenor, John N. Harbinson