Abstract: Chromogenic compounds of normally colorless form are disclosed having the following structural formula: ##STR1## wherein E represents a six-membered aromatic or heterocyclic ring which may have an aromatic condensed ring or a naphthalene ring and both the E ring and the condensed ring may be substituted, A represents an optionally substituted aminophenyl, indolyl, benzoindolyl, julolidinyl or kairolyl radical or the radical represented by B, and B represents a family of indolizine radicals. The compounds of this invention are eligible for use in pressure-sensitive and heat-sensitive record materials and manifold marking systems.
Type:
Grant
Filed:
September 29, 1980
Date of Patent:
June 8, 1982
Assignee:
Appleton Papers Inc.
Inventors:
William J. Becker, Sheldon Farber, Troy E. Hoover
Abstract: A pressure-sensitive record material comprising the colorless chromogenic dye Pyridyl Blue mixed with and adsorbed onto a pigment which is coated on a substrate sheet, and capsules containing an acidic resin dissolved in a suitable solvent, the capsules being coated on the same or an additional sheet. This "reverse" system (where the acidic resin rather than the dye is encapsulated) provides an improved community of properties, including improved image strength, print stability (fade resistance) and resistance to degradation. Pyridyl Blue is a mixture of the isomers 7-(1-ethyl-2-methylindol-3-yl)-7-(4-diethylamino-2-ethoxyphenyl)-5,7-dihyd rofuro[3,4-b]pyridin-5-one and 5-(1-ethyl-2-methylindol-3-yl)-5-(4-diethylamino-2-ethoxyphenyl)-5,7-dihyd rofuro[3,4-b]pyridin-7-one.
Abstract: A process for separating a collated stack of carbonless copy paper sheets into form sets, which comprises applying to the edge of the stack of sheets to be padded an adhesive composition containing borax, drying and separating the unit sets.
Abstract: A substantially colorless marking liquid, particularly for use in pressure-sensitive record material, comprising (a) a colorless chromogenic material, (b) a solvent for said chromogenic material and (c) an additive for controlling CB decline. The additive for controlling CB decline, i.e., controlling the capability of the CB sheet to produce an image of satisfactory intensity even after exposure of the CB coating to light, includes certain chromogenic materials such as Pyridyl Blue and phenol derivatives having a free reactive (ortho- or para-) position. The marking liquid helps to prevent CB decline in, for example, carbonless copy paper, a long-standing problem in the art.
Abstract: Chromogenic compounds of normally colorless form are disclosed having the following structural formula: ##STR1## wherein E represents a six-membered aromatic or heterocyclic ring which may have an aromatic ring or a naphthalene ring and both the E ring and the condensed ring may be substituted, A respresents an optionally substituted aminophenyl, indolyl, benzoindolyl, julolidinyl or kairolyl radical or the radical represented by B, and B represents a family of indolizine radicals. The compounds of this invention are eligible for use in pressure-sensitive and heat-sensitive record materials and manifold marking systems.
Type:
Grant
Filed:
January 16, 1980
Date of Patent:
June 23, 1981
Assignee:
Appleton Papers Inc.
Inventors:
William J. Becker, Sheldon Farber, Troy E. Hoover
Abstract: A thermally sensitive record material is disclosed which comprises chromogenic material which is a mixture of the isomers 7-(1-ethyl-2-methylindol-3-yl)-7-(4-dimethylamino-2-ethoxyphenyl)-5,7-dihy drofuro[3,4-b]pyridin-5-one and 5-(1-ethyl-2-methylindol-3-yl)-5-(4-diethylamino-2-ethoxyphenyl)-5,7-dihyd rofuro[3,4-b]pyridin-7-one. This record material has superior color forming efficiency and greater image stability, especially resistance to fading in incident light.
Abstract: Chromogenic compounds of normally colorless form are disclosed having the following structural formula: ##STR1## wherein E represents a six-membered aromatic or heterocyclic ring which may have an aromatic condensed ring and both the E ring and the condensed ring may be substituted, A represents an optionally substituted aminophenyl, indolyl, benzoindolyl, julolidinyl or kairolyl radical or the radical represented by B, and B represents a family of heterocyclic radicals. The compounds of this invention are eligible for use in pressure-sensitive and heat sensitive record materials and manifold marking systems.
Type:
Grant
Filed:
March 5, 1979
Date of Patent:
December 30, 1980
Assignee:
Appleton Papers Inc.
Inventors:
Troy E. Hoover, Sheldon Farber, William J. Becker
Abstract: Chromogenic compounds of normally colorless form are disclosed having the following structural formula: ##STR1## wherein E represents a six-membered aromatic or heterocyclic ring which may have an aromatic condensed ring and both the E ring and the condensed ring may be substituted, A represents an optionally substituted aminophenyl, indolyl, benzoindolyl, julolidinyl or kairolyl radical or the radical represented by B, and B represents a family of indolizine radicals. The compounds of this invention are eligible for use in pressure-sensitive and heat sensitive record materials and manifold marking systems.
Type:
Grant
Filed:
March 5, 1979
Date of Patent:
November 11, 1980
Assignee:
Appleton Papers Inc.
Inventors:
William J. Becker, Sheldon Farber, Troy E. Hoover
Abstract: A process for separating a collated stack of carbonless copy paper sheets into form sets, which comprises pretreating the edge of the stack of sheets to be padded with a non-aqueous material, drying, applying an adhesive composition, drying and separating the unit sets.
Type:
Grant
Filed:
July 26, 1978
Date of Patent:
October 28, 1980
Assignee:
Appleton Papers Inc.
Inventors:
William J. Becker, Kenneth D. Glanz, Peter L. Foris, Robert W. Brown, Jerrold L. Anderson
Abstract: A process for separating a collated stack of carbonless copy paper sheets into form sets, which comprises pretreating the edge of the stack of sheets to be padded with water or an aqueous solution or dispersion, drying, applying an adhesive composition, drying and separating the unit sets.
Type:
Grant
Filed:
July 26, 1978
Date of Patent:
August 12, 1980
Assignee:
Appleton Papers Inc.
Inventors:
Kenneth D. Glanz, William J. Becker, Robert E. Miller
Abstract: This invention relates to paper, or like sheet material, having a coating comprising minute, liquid-containing, pressure-rupturable capsules, and also larger, non-rupturable kaolin-containing stilt capsules arranged in interspersion and in close juxtaposition. In the preferred embodiment the smaller capsules contain a liquid marking agent. The capsules, large and small, are interspersed as to size, and are closely spaced on the sheet, so that an intentional impact directed on a small area of the coating will crush substantially all of the small capsules in the area and result in the release of liquid marking agent, whereas a casually applied pressure will rupture relatively few of the small capsules in the area. The marking liquid may be a colorless chromogenic color reactant. The small capsules on a sheet containing said marking liquid may be associated with other color forming materials on said sheet, or alternatively said color forming materials may be contained on another contacting sheet.
Abstract: A self-contained pressure-sensitive record material comprising a substrate and a coating thereon of an interspersed mixture of pressure-rupturable capsules of an oily solvent solution of a substantially colorless basic chromogenic material and capsules of solid co-reactant acidic resin particles, said co-reactant acidic resin being capable of producing a color upon contact with the chromogenic material. The capsule mixture is applied to the substrate in a single coating step, resulting in a greater production efficiency. The resulting record material provides better imaging characteristics with less print bleed than self-contained systems known in the prior art.