Patents Assigned to Appvion, Inc.
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Patent number: 9534156Abstract: The invention describes a composition and method of providing an improved recording material, such as an ink receptive recording material or thermally responsive record material useful for linerless labels. The record material comprises a support having provided thereon on one surface an adhesive material, and on at least one other surface, an ink receptive coating or a heat sensitive imaging coating. The method comprises applying to a first surface a first layer of a coating of an ink receptive material or of a heat sensitive color-forming composition comprising a binder material and a substantially colorless dye precursor and an acidic developer material in substantially contiguous relationship. The adhesive is heat activated. The record material exhibits substantially no tack at 23° C., 40% relative humidity when pressure is applied, however develops high peel strength (300 grams/inch) upon application of 7 mJ/mm2 to 13 mJ/mm2 of heat energy.Type: GrantFiled: September 17, 2014Date of Patent: January 3, 2017Assignee: APPVION, INC.Inventor: Mark Robert Fisher
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Publication number: 20160207020Abstract: The invention teaches a method of efficiently dewatering a microcapsule slurry to form a water re-suspendable filter cake of microcapsules. The process comprises providing an aqueous slurry of microcapsules dispersed in an aqueous solution; adding an agglomeration agent and dispersing the agglomeration agent into the aqueous slurry; adjusting the pH to a pH level sufficient to agglomerate the dispersed microcapsules; and filtering the aqueous slurry of microcapsules by gravity, vacuum or pressure filtration to thereby form a filter cake of dewatered microcapsules. The agglomeration agent is sodium polyphosphate, sodium tetrapolyphosphate, sodium hexametaphosphate, and/or sodium tripolyphosphate; or with anionic microcapsules or coatings even alkaline earth metal salts such as magnesium chloride, calcium chloride or barium chloride, or even aluminum salt such as aluminum chloride.Type: ApplicationFiled: January 16, 2015Publication date: July 21, 2016Applicant: Appvion, Inc.Inventor: BIAO DUAN
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Publication number: 20160096105Abstract: The invention is an article and method of discretely recording confidential information especially for lottery applications and comprises: providing a substrate assembly comprising a) a substrate, b) a first layer of an acid developer material coated on the substrate, c) a meltable barrier layer applied over the acidic developer material, the meltable barrier layer being meltable in response to the applied heat of a thermal printhead or laser, d) a scratch-off layer coated over the meltable barrier layer, and e) pressure-sensitive microcapsules containing a dye precursor and solvent dispersed in any of the layers and, recording non-visible information by selective application of heat to the substrate assembly using a thermal printhead or laser, the barrier layer being “activated” by melting in discrete areas where heat is selectively applied from the thermal printhead or laser.Type: ApplicationFiled: October 2, 2014Publication date: April 7, 2016Applicant: Appvion, Inc.Inventor: Michael Gerald Cove
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Publication number: 20160075921Abstract: The invention describes a composition and method of providing an improved recording material, such as an ink receptive recording material or thermally responsive record material useful for linerless labels. The record material comprises a support having provided thereon on one surface an adhesive material, and on at least one other surface, an ink receptive coating or a heat sensitive imaging coating. The method comprises applying to a first surface a first layer of a coating of an ink receptive material or of a heat sensitive color-forming composition comprising a binder material and a substantially colorless dye precursor and an acidic developer material in substantially contiguous relationship. The adhesive is heat activated. The record material exhibits substantially no tack at 23° C., 40% relative humidity when pressure is applied, however develops high peel strength (300 grams/inch) upon application of 7 mJ/mm2 to 13 mJ/mm2 of heat energy.Type: ApplicationFiled: September 17, 2014Publication date: March 17, 2016Applicant: Appvion, Inc.Inventor: MARK ROBERT FISHER
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Patent number: 9199503Abstract: The invention describes a composition and method of providing an improved thermally responsive record material useful for linerless labels. The record material comprises a support having provided thereon on one surface an adhesive material, and on at least one other surface, a heat sensitive imaging coating. The method comprises applying to a first surface a first layer of a coating of a heat sensitive color-forming composition comprising a binder material and a substantially colorless dye precursor and an acidic developer material in substantially contiguous relationship. Over the first layer is applied a release coat overcoating the first layer. The release coat comprises a water soluble or water dispersible polymeric material, a polysiloxane release agent and excess platinum catalyst in excess of 150 ppm based on weight of the second coating. The release coat is cured at a temperature of from at or below 160° C., or even from 70° to 120° C.Type: GrantFiled: June 26, 2014Date of Patent: December 1, 2015Assignee: APPVION, INC.Inventors: Mark Robert Fisher, Yves Defrenne
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Patent number: 9126451Abstract: A thermal recording material having a heat-sensitive color-forming layer that contains a phosphate modifier in addition to an activator and lueco dye can provide good imaging. The phosphate modifier such as unsubstituted dibenzyl phosphate can be paired with an activator such 3-(4-hydroxyphenyl)propionic acid to provide an environmentally friendly thermal recording material.Type: GrantFiled: December 18, 2013Date of Patent: September 8, 2015Assignee: APPVION, INC.Inventors: Fadi Chakar, John Charles Warner, Justin Robert Whitfield, Michelle Wanchi Li Lugus, Deboshri Banerjee
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Patent number: 9097620Abstract: A method, and apparatus, for determining bend resistance of a sample includes applying a weight to a sample and measuring an amount of deflection of the sample caused by applying the weight. The sample is provided on a sample holder and an initial position of the sample is measured with respect to the sample holder. A weight is applied to the sample and a change in position from the initial position to a deflection position of the sample due to the weight applied to the sample is measured. An amount of deflection of the sample is determined by dividing the change in position by the basis weight.Type: GrantFiled: February 14, 2013Date of Patent: August 4, 2015Assignee: APPVION, INC.Inventors: Kelly John Caron, Ruth Monica Prasetio
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Publication number: 20150165806Abstract: A thermal recording material having a heat-sensitive color-forming layer that contains a phosphate modifier in addition to an activator and lueco dye can provide good imaging. The phosphate modifier such as unsubstituted dibenzyl phosphate can be paired with an activator such 3-(4-hydroxyphenyl)propionic acid to provide an environmentally friendly thermal recording material.Type: ApplicationFiled: December 18, 2013Publication date: June 18, 2015Applicant: Appvion, Inc.Inventors: Fadi CHAKER, John Charles WARNER, Justin Robert WHITFIELD, Michelle Wanchi LI LUGUS, Deboshri BANERJEE
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Patent number: 9034790Abstract: The invention describes a thermally-responsive record material substantially free of aromatic isocyanate. The record material comprises a support having provided thereon a heat-sensitive composition comprising a substantially colorless dye precursor comprising a fluoran; and a developer material selected from the group consisting of 4,4?-diaminodiphenylsulfone and 3,3?-diaminodiphenylsulfone, which upon being heated react with said dye precursor to develop color, and including a binder material. Optionally, a modifier compound is included in the heat-sensitive composition. The modifier compound can be selected from the group consisting of a fatty acid amide, preferably a saturated fatty acid amide such as an alkyl amide, a bis methylene alkyl amide, or a bis ethylene alkyl amide, or any of 1,2-diphenoxy ethane, dimethyl diphenoxy ethane, and dimethyl phthalate.Type: GrantFiled: March 14, 2013Date of Patent: May 19, 2015Assignee: Appvion, Inc.Inventors: Fadi Selim Chakar, Mark Robert Fisher
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Publication number: 20150125617Abstract: An activator means for use in activating or re-activating adhesive and sealant compositions that have been pre-applied to a bonding surface prior to mating said bonding surface said means having a plurality of features for directly acting upon the pre-applied composition.Type: ApplicationFiled: November 22, 2014Publication date: May 7, 2015Applicant: Appvion, Inc.Inventors: John MacKay Lazar, Todd Arlin Schwantes, Frederick Edward Charles Lidington
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Patent number: 8974547Abstract: The present application relates to encapsulated benefit agents, compositions comprising such encapsulated benefit agents and processes for making and using compositions comprising such encapsulated benefit agents that do not require or require a reduced amount of scavenger materials. Such encapsulated benefit agents, compositions comprising such encapsulated benefit agents are processed such that no or lower levels of scavenger materials are required.Type: GrantFiled: July 23, 2009Date of Patent: March 10, 2015Assignee: Appvion, Inc.Inventors: Jiten Odhavji Dihora, Walter Franciscus Joanna Vanderveken, Sanford Theodore Kirksey, Jr., John Charles DeBraal, Robert Stanley Bobnock, Adam Keith Druckrey, Gary Thomas Hart
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Patent number: 8916496Abstract: The invention describes an improved thermally-responsive record material substantially free of aromatic isocyanate yielding an image of high intensity and useful for bar codes. The record material comprises a support having provided thereon a heat-sensitive composition comprising a substantially colorless color former comprising a fluoran; and a developer material selected from the group consisting of 4,4?-diaminodiphenylsulfone and 3,3?-diaminodiphenylsulfone, and an organic acid which upon being heated reacts with said color former to develop color, and including a binder material. Optionally, a modifier compound is included in the heat-sensitive composition. The compound can be selected from the group consisting of a fatty acid amide, such as stearmide. Optionally, magnesium state is included.Type: GrantFiled: October 11, 2013Date of Patent: December 23, 2014Assignee: Appvion, Inc.Inventors: Fadi Selim Chakar, Mark Robert Fisher
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Patent number: 8916497Abstract: The invention describes a thermally-responsive record material substantially free of aromatic isocyanate. The record material comprises a support having provided thereon a heat-sensitive composition comprising a substantially colorless dye precursor comprising a fluoran; and a developer material selected from the group consisting of 4,4?-diaminodiphenylsulfone and 3,3?-diaminodiphenylsulfone in combination with N-[(butylamino)carbonyl]-4-methylbenzene sulfonamide, which upon being heated react with said dye precursor to develop color, and including a binder material.Type: GrantFiled: April 29, 2014Date of Patent: December 23, 2014Assignee: Appvion, Inc.Inventors: Mark Robert Fisher, Fadi Selim Chakar, Yves Defrenne
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Publication number: 20140370271Abstract: A coated paper with enhanced properties and/or lower cost can be obtained by using a coating that contains a binder and stanchion-encapsulated titanium dioxide. The stanchion-encapsulated titanium dioxide can provide the same or similar brightness, gloss, and/or opacity while using less titanium dioxide.Type: ApplicationFiled: December 20, 2013Publication date: December 18, 2014Applicant: Appvion, Inc.Inventors: Nianxi Yan, John Charles Debraal
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Patent number: 8893760Abstract: An apparatus for use in activating or re-activating adhesive and sealant compositions that have been pre-applied to a bonding surface prior to mating said bonding surface, said apparatus having a plurality of features for directly acting upon the pre-applied composition.Type: GrantFiled: September 19, 2011Date of Patent: November 25, 2014Assignee: Appvion, IncInventors: John MacKay Lazar, Todd Arlin Schwantes, Frederick Edward Charles Lidington
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Publication number: 20140263673Abstract: The invention describes an improved thermally-responsive record material substantially free of aromatic isocyanate yielding an image of high intensity and useful for bar codes. The record material comprises a support having provided thereon a heat-sensitive composition comprising a substantially colorless color former comprising a fluoran; and a developer material selected from the group consisting of 4,4?-diaminodiphenylsulfone and 3,3?-diaminodiphenylsulfone, and an organic acid which upon being heated reacts with said color former to develop color, and including a binder material. Optionally, a modifier compound is included in the heat-sensitive composition. The compound can be selected from the group consisting of a fatty acid amide, such as stearmide. Optionally, magnesium state is included.Type: ApplicationFiled: October 11, 2013Publication date: September 18, 2014Applicant: Appvion, Inc.Inventors: Fadi Selim Chakar, Mark Robert Fisher
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Publication number: 20140231529Abstract: The invention describes a thermally-responsive record material substantially free of aromatic isocyanate. The record material comprises a support having provided thereon a heat-sensitive composition comprising a substantially colorless dye precursor comprising a fluoran; and a developer material selected from the group consisting of 4,4?-diaminodiphenylsulfone and 3,3?-diaminodiphenylsulfone in combination with N-[(butylamino)carbonyl]-4-methylbenzene sulfonamide, which upon being heated react with said dye precursor to develop color, and including a binder material.Type: ApplicationFiled: April 29, 2014Publication date: August 21, 2014Applicant: Appvion, Inc.Inventors: Mark Robert Fisher, Fadi Selim Chakar, Yves Defrenne
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Patent number: 8796381Abstract: Encapsulated cure systems are provided wherein a curative is incorporated into a solid or semi-solid carrier material whereby mere fracturing or failure of the capsule wall encapsulating such cure systems will not provide for or allow sufficient release of the curative. Also provided are adhesive systems incorporating said encapsulated cure systems.Type: GrantFiled: September 17, 2011Date of Patent: August 5, 2014Assignee: Appvion, Inc.Inventors: Todd Arlin Schwantes, Michael Curley Krzoska, Gregory Stephen Kulibert, Adam Gregg Malofsky, Bernard Miles Malofsky, Nagib Maurice Ward
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Publication number: 20140186630Abstract: The present invention teaches microcapsule particles comprising an oil soluble or dispersible core material; and a wall material at least partially surrounding the core material, the microcapsule wall material consisting of the reaction product of a first composition in the presence of a second composition; the first composition comprising a water phase: the water phase comprising a water soluble or dispersible initiator having at least one —COOH or amine functional group and a nonionic emulsifier, the emulsifier comprising a water soluble or dispersible material at a pH from 4 to 12, the water soluble or dispersible initiator is selected from initiators having a C—N?N—C type structure and of formulas I, II or III (set forth in the specification) having amine or carboxyl functionality. The second composition comprises an oil phase.Type: ApplicationFiled: December 12, 2013Publication date: July 3, 2014Applicant: Appvion, Inc.Inventor: Todd Arlin Schwantes
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Patent number: 8715544Abstract: A process of forming a population of microcapsules is described comprising a liquid hydrophilic core material and a wall material at least partially surrounding the core material. The liquid hydrophilic core material can be anionic, cationic, or neutral but polar. The microcapsule population is formed by providing liquid hydrophilic core material; providing an oil continuous phase which is low boiling and preferably nonflammable, the oil continuous phase comprising preferably one or more organic oil materials such as esters with chain length up to about 42 carbons. A mixture is formed by dispersing the liquid hydrophilic material in the oil continuous phase. Either an oil soluble or dispersible monofunctional amine acrylate or monofunctional amine methacrylate, along with acid; or alternatively monofunctional acid acrylate or monofunctional acid methacrylate along with base; or alternatively, monofunctional amine acrylate or monofunctional amine methacrylate along with acid acrylate or methacrylate; is added.Type: GrantFiled: December 20, 2010Date of Patent: May 6, 2014Assignee: Appvion, Inc.Inventor: Todd Arlin Schwantes