Patents Assigned to Aquablok, Ltd.
  • Patent number: 11554969
    Abstract: Reactive treatment cells (RTCs) are described in combination with sediment capping systems as a means for environmental remediation. RTCs include an impermeable housing defining an interior, a permeable ceiling and floor typically including filtration materials such as geotextiles, and at least one interior compartment for treatment reagents. One RTC includes a gabion-like cage structure retaining a geomembrane-supported geosynthetic clay liner (GM-GCL) housing, while a second embodiment includes a hard, cylindrical shell as a replaceable reagent cartridge. RTCs may be employed in initial capping system installations or retrofitted into existing capping systems. RTCs may include optional baffles, flow restrictors, floating discs, sensor probes, and two or more serial reagent zones or compartments.
    Type: Grant
    Filed: August 6, 2014
    Date of Patent: January 17, 2023
    Assignee: AquaBlok Ltd.
    Inventors: Dennis Gregory Grubb, John H. Hull
  • Patent number: 11414828
    Abstract: Composite particles of a hard core coated by a layer of hydratable, swellable clay such as bentonite are useful for constructing, modifying and/or supporting lifeline structure such as dams, berms and levees, and/or pipelines or conduits for oil, gas, sewage, water, or cables or wires for transmission of electrical power or data information. The method involves placing the composite particles in a location within, below, or about the lifeline structure, and hydrating them to cause them to swell and fill and seal the voids around the structure to form a resilient support having a high damping ratio and low hydraulic conductivity that is maintained after exposure to strain forces. The composite particles are advantageous in damping seismic waves and reducing the potential damage from an earthquake, explosion, tremor, fatigue loading, or similar seismic event.
    Type: Grant
    Filed: September 1, 2017
    Date of Patent: August 16, 2022
    Assignee: Aquablok, LTD.
    Inventor: John H. Hull
  • Patent number: 11077422
    Abstract: Composite particles contain a natural stone or aggregate core and a coating of two or more sorbent layers collectively containing at least two distinct kinds of sorbent materials effective for sorbing two distinct contaminants. One or both sorbent layers may be mixed with a water-absorbent, swellable clay that, upon contact with water, causes spalling or disintegration of the coating layer to release the sorptive material into a body of water such as a pond, ditch, stream, or riverbed. Additional swellable or protective layers may also be present. The composite particles are deployed into a pond, ditch, river, or streambed where the core of natural stone remains in the riverbed. The sorptive materials of the two different sorbent layers sorb and fix a wide range of contaminants, including both the heavy and light-weight hydrocarbons, from the water, and settle as a fine sediment. The sediment with sorbed contaminants is then removed by means such as hydraulic collectors or dredging.
    Type: Grant
    Filed: June 14, 2018
    Date of Patent: August 3, 2021
    Assignee: AquaBlok, Ltd.
    Inventors: John H. Hull, Scott A. Collins
  • Patent number: 11072905
    Abstract: The invention relates to a low-permeability geotechnical barrier material including a blend of approximately equal parts of: aggregate particles, sand-size particles and manufactured composite particles that include a hydratable sealant material composed of naturally-occurring clay minerals and/or polymer-enhanced clay minerals, such that the actual percentage of clay mineral component is less than 10% by weight in the blended material. In a particular embodiment, the construction of a low-permeability geotechnical barrier using predominantly coarse grain materials by conventional compaction efforts is rarely attempted due to the difficulty of maintaining a uniform mix of well-graded sand and aggregate blends necessary to achieve low permeability. The regularly achievable permeability offered by this material blend when installed with specific proscribed techniques using conventional equipment can be 5×10?8 cm/sec or lower.
    Type: Grant
    Filed: April 3, 2017
    Date of Patent: July 27, 2021
    Assignee: AquaBlok, Ltd.
    Inventor: John H. Hull
  • Patent number: 10926309
    Abstract: Contaminated sediment is re-mediated using a self-regenerating reactive sedimentation capping system comprising a system of composite particles having a core and a coating. The coating of at least some particles further include a complexing or sorptive reactive material, such as activated carbon, appatite, a clay or organoclay, or a synthetic sorptive such as Sorbster™. The same or different particles contain a composition of dormant microbes capable of utilizing various contaminants as a food source. The same or other particles may also contain nutrients, micronutrients, vitamins, cofactors, buffers or other adjunctive compounds to sustain the microbes. The microbes feed on and degrade the contaminant compounds complexed, absorbed or adsorbed by the reactive material, thereby regenerating the reactive material for re-use.
    Type: Grant
    Filed: June 24, 2015
    Date of Patent: February 23, 2021
    Assignee: AquaBlok, Ltd.
    Inventor: John H. Hull
  • Publication number: 20200179904
    Abstract: Composite particles contain a natural stone or aggregate core and a coating of two or more sorbent layers collectively containing at least two distinct kinds of sorbent materials effective for sorbing two distinct contaminants. One or both sorbent layers may be mixed with a water-absorbent, swellable clay that, upon contact with water, causes spalling or disintegration of the coating layer to release the sorptive material into a body of water such as a pond, ditch, stream, or riverbed. Additional swellable or protective layers may also be present. The composite particles are deployed into a pond, ditch, river, or streambed where the core of natural stone remains in the riverbed. The sorptive materials of the two different sorbent layers sorb and fix a wide range of contaminants, including both the heavy and light-weight hydrocarbons, from the water, and settle as a fine sediment. The sediment with sorbed contaminants is then removed by means such as hydraulic collectors or dredging.
    Type: Application
    Filed: June 14, 2018
    Publication date: June 11, 2020
    Applicant: AquaBlok, Ltd.
    Inventors: John H. Hull, Scott A. Collins
  • Publication number: 20190330111
    Abstract: The invention relates to a low-permeability geotechnical barrier material including a blend of approximately equal parts of: aggregate particles, sand-size particles and manufactured composite particles that include a hydratable sealant material composed of naturally-occurring clay minerals and/or polymer-enhanced clay minerals, such that the actual percentage of clay mineral component is less than 10% by weight in the blended material. In a particular embodiment, the construction of a low-permeability geotechnical barrier using predominantly coarse grain materials by conventional compaction efforts is rarely attempted due to the difficulty of maintaining a uniform mix of well-graded sand and aggregate blends necessary to achieve low permeability. The regularly achievable permeability offered by this material blend when installed with specific proscribed techniques using conventional equipment can be 5×10?8 cm/sec or lower.
    Type: Application
    Filed: April 3, 2017
    Publication date: October 31, 2019
    Applicant: AquaBlok, Ltd.
    Inventor: John H. Hull
  • Publication number: 20190194069
    Abstract: Composite particles of a hard core coated by a layer of hydratable, swellable clay such as bentonite are useful for constructing, modifying and/or supporting lifeline structure such as dams, berms and levees, and/or pipelines or conduits for oil, gas, sewage, water, or cables or wires for transmission of electrical power or data information. The method involves placing the composite particles in a location within, below, or about the lifeline structure, and hydrating them to cause them to swell and fill and seal the voids around the structure to form a resilient support having a high damping ratio and low hydraulic conductivity that is maintained after exposure to strain forces. The composite particles are advantageous in damping seismic waves and reducing the potential damage from an earthquake, explosion, tremor, fatigue loading, or similar seismic event.
    Type: Application
    Filed: September 1, 2017
    Publication date: June 27, 2019
    Applicant: Aquablok, LTD.
    Inventor: John H. Hull
  • Publication number: 20170247772
    Abstract: Composite particles are used in combination with ore particles in an ore-refining or purification process, such as in a steel- or iron-making process. The composite particles comprise a core, which may be an aggregate of limestone, dolomite, or another ore particle. The core is surrounded by a coating layer of a metal dust and a binder. The metal dust may be iron oxide dust, which, along with limestone, is prevalent in the iron smelting process anyway. In this way, the composite particles help to recycle otherwise wasted and hazardous iron dust. The binder may be mineral clay such as bentonite, montmorillonite or kaolinite, and may comprise about 2-10% by weight of the particle.
    Type: Application
    Filed: September 25, 2015
    Publication date: August 31, 2017
    Applicant: AquaBlok, Ltd.
    Inventor: John H. Hull
  • Publication number: 20170203346
    Abstract: Contaminated sediment is re-mediated using a self-regenerating reactive sedimentation capping system comprising a system of composite particles having a core and a coating. The coating of at least some particles further include a complexing or sorptive reactive material, such as activated carbon, appatite, a clay or organoclay, or a synthetic sorptive such as Sorbster™. The same or different particles contain a composition of dormant microbes capable of utilizing various contaminants as a food source. The same or other particles may also contain nutrients, micronutrients, vitamins, cofactors, buffers or other adjunctive compounds to sustain the microbes. The microbes feed on and degrade the contaminant compounds complexed, absorbed or adsorbed by the reactive material, thereby regenerating the reactive material for re-use.
    Type: Application
    Filed: June 24, 2015
    Publication date: July 20, 2017
    Applicant: AquaBlok, Ltd.
    Inventor: John H. Hull
  • Publication number: 20170189948
    Abstract: Contaminated sediment is remediated using a sedimentation capping system comprising composite particles having a core and a coating containing a statin composition. The statins are useful for inhibiting the growth of methanogens, known anaerobes that produce methane from organic materials found in sediments. The reduction in methane production avoids several problems in capping systems, including reduced ebullition that may breach the barrier cap, reduced mobilization and bioavailability of methylated toxins to aquatic life above the cap.
    Type: Application
    Filed: June 24, 2015
    Publication date: July 6, 2017
    Applicant: AquaBlok, Ltd.
    Inventors: John H. Hull, James G. Mueller
  • Publication number: 20150041409
    Abstract: Reactive treatment cells (RTCs) are described in combination with sediment capping systems as a means for environmental remediation. RTCs include an impermeable housing defining an interior, a permeable ceiling and floor typically including filtration materials such as geotextiles, and at least one interior compartment for treatment reagents. One RTC includes a gabion-like cage structure retaining a geomembrane-supported geosynthetic clay liner (GM-GCL) housing, while a second embodiment includes a hard, cylindrical shell as a replaceable reagent cartridge. RTCs may be employed in initial capping system installations or retrofitted into existing capping systems. RTCs may include optional baffles, flow restrictors, floating discs, sensor probes, and two or more serial reagent zones or compartments.
    Type: Application
    Filed: August 6, 2014
    Publication date: February 12, 2015
    Applicant: AQUABLOK, LTD.
    Inventors: Dennis Gregory Grubb, John H. Hull
  • Publication number: 20130196061
    Abstract: Fiber-containing composite particles and fiber-reinforced barrier matrix compositions made from them are disclosed. The composite particles include a core, a hydratable clay mineral layer, an optional protective coating, and a reinforcing fiber. The fiber may be present in any or all of several locations: adhered to the core, dispersed in the hydratable layer or in the protective coating. Upon hydration, the hydratable clay mineral layer swells and forms a matrix that cohesively holds the fibers and the core in a fiber-reinforced barrier matrix composition.
    Type: Application
    Filed: October 7, 2011
    Publication date: August 1, 2013
    Applicant: AQUABLOK, LTD.
    Inventor: John H. Hull
  • Patent number: 7472661
    Abstract: A method for delivering plant seed material to a target placement surface is described. The method comprises utilizing a core material and combining plant seed material with the core material to create a vector. A plurality of vectors are delivered to a target placement surface but a barrier layer of vectors is not created.
    Type: Grant
    Filed: June 21, 2005
    Date of Patent: January 6, 2009
    Assignee: Aquablok, Ltd
    Inventors: John Harrison Hull, Eric Lawrence Kraus
  • Patent number: 7011766
    Abstract: A method of treating a metal-contaminated sediment includes capping the sediment with a capping product containing sulfur and at least one component selected from the group consisting of clays, clay-sized materials, bulking agents, sand, sand-sized materials, aggregate, and binding agents. A capping product includes a plurality of manufactured composite particles, each composite particle comprising a relatively dense core and a sealant layer at least partially encapsulating the core, the sealant layer including sulfur and at least one of the above components.
    Type: Grant
    Filed: March 24, 2004
    Date of Patent: March 14, 2006
    Assignee: Aquablok, Ltd.
    Inventor: John H. Hull