Abstract: Modified polysaccharides, acrylamide copolymers, water-soluble amino acid copolymers, and combinations thereof are described for uses including flocculation of solids, particularly flocculation of soil in an agricultural settings and clarification of process waters from oil-sands mining operations. Also described are methods of preparing selected amino acid copolymers and modified polysaccharides.
Type:
Application
Filed:
June 11, 2018
Publication date:
July 4, 2019
Applicant:
Aquero Company, LLC
Inventors:
C. Steven Sikes, Mark A. Hochwalt, T. Daniel Sikes
Abstract: Modified polysaccharides, acrylamide copolymers, water-soluble amino acid copolymers, and combinations thereof are described for uses including flocculation of solids, particularly flocculation of soil in an agricultural settings and clarification of process waters from oil-sands mining operations. Also described are methods of preparing selected amino acid copolymers and modified polysaccharides.
Type:
Grant
Filed:
October 12, 2006
Date of Patent:
June 12, 2018
Assignee:
Aquero Company, LLC
Inventors:
C. Steven Sikes, Mark A. Hochwalt, T. Daniel Sikes
Abstract: A chemical treatment process and separation module are described for removal of soluble organic compounds and suspended or emulsified oils and/or solids from produced waters that accompany operations for oil and gas recovery. The process occurs in its entirety within an interval of several minutes. The solubility of organic compounds is first reduced, in an optional step, by pH reduction, followed by treatment with coagulants and flocculants, the latter in conjunction with microbubble flotation. The organic compounds that are rendered insoluble, along with other oily solids, are captured in the floe created by the coagulant and flocculant treatment, and simultaneously made buoyant by the concurrent addition of microbubbles. The water and floe is passed over an array of sloped strainers that separates and diverts the floe from the effluent water, which contains significantly reduced soluble organic content. The separated stream of oily solids can be dewatered for disposal as waste.
Type:
Grant
Filed:
July 22, 2013
Date of Patent:
March 13, 2018
Assignees:
Aquero Company, LLC, 1257 122 Alberta Ltd.
Inventors:
Timothy J. Webber, T. Daniel Sikes, C. Steven Sikes
Abstract: Lysine-based polymers, particularly copolymers of lysine and maleic acid, are useful as coagulants for clarification of wastewaters, including produced waters from oils sands mining operations. They can be advantageously used in combination with commercial coagulants, and in combination with flocculants. Such combinations may include dry blends. Also described are methods of preparation of lysine homopolymers and copolymers.
Abstract: Oily and/or solids-containing water is clarified by chemical treatment to form flocculated and agglomerated solid phases and a clear water phase. In the clarification process, microbubbles of air or other gas are introduced at atmospheric pressure, via an eductor or other suitable device, together with a flocculant. During the subsequent formation of floes and their agglomeration into larger masses, microbubbles become entrained within and adhered to the solid flocculated materials. The resulting masses are very buoyant and easily separated from the water via a variety of approaches that include skimming, decanting, filtration, and screening. This process results in a solids phase that may be disposed of as waste, if desired, and a highly clarified water phase.
Type:
Grant
Filed:
July 23, 2009
Date of Patent:
April 26, 2016
Assignee:
Aquero Company, LLC
Inventors:
C. Steven Sikes, T. Daniel Sikes, Mark A. Hochwalt
Abstract: Water-soluble amino acid copolymers, modified polysaccharides, acrylamide polymers, and combinations thereof, are described, for uses including flocculation of solids, particularly flocculation of soil, such as in an agricultural setting. Also described are methods of preparing selected amino acid copolymers and modified polysaccharides.
Type:
Grant
Filed:
June 22, 2006
Date of Patent:
September 29, 2009
Assignees:
Aquero Company, ValuGen LLC
Inventors:
C. Steven Sikes, Mark A. Hochwalt, T. Daniel Sikes
Abstract: Water-soluble amino acid copolymers, modified polysaccharides, acrylamide polymers, and combinations thereof are described for use in flocculation of solids, particularly flocculation of soil, preferably in agricultural settings.
Type:
Grant
Filed:
June 22, 2006
Date of Patent:
September 29, 2009
Assignees:
Aquero Company, Valugen, LLC
Inventors:
C. Steven Sikes, Mark A. Hochwalt, T. Daniel Sikes
Abstract: Disclosed are copolymers based on aspartic acid or its precursor molecules and methods of their production. The copolymers are water-soluble over a wide range of composition and molecular weight. Their preparation involves conversion of a polysuccinimide to copolymers of defined composition, containing aspartate and succinimide residues and/or residues of asparagine. In particular, the copolymers include water-soluble terpolymers of aspartate, asparagine, and succinimide.
Abstract: Described are methods of production of polysuccinimides having molecular weights up to 200,000 daltons and higher. The polysuccinimides of the invention are essentially unbranched and uncrosslinked. They can be modified by crosslinking, ring-opening, and/or other functionalization, if desired, to form gelling materials of superior performance. The high Mw polysuccinimides are also particularly useful as thickening agents, viscosity modifiers, emollients, humectants and in other applications that are known in the art to be serviced most effectively by molecules of higher molecular weight.
Abstract: Disclosed are copolymers based on aspartic acid or its precursor molecules and methods of their production. The copolymers are water-soluble over a wide range of composition and molecular weight. Their preparation involves conversion of a polysuccinimide to copolymers of defined composition, containing aspartate and succinimide residues and/or residues of asparagine. In particular, the copolymers include water-soluble terpolymers of aspartate, asparagine, and succinimide.