Abstract: The invention relates to a process for the co-production of alkyl mercaptan and of dialkyl disulfide, comprising the following successive steps: a) reaction of a C1-C4 alcohol in the presence of hydrogen sulfide (H2S) to form a stream (M) comprising an alkyl mercaptan, water, and possibly unreacted hydrogen sulfide, b) purification of the stream (M) to obtain a stream (N) enriched in alkyl mercaptan, c) recovery of a first portion of the stream (N) including the alkyl mercaptan purified in step b), d) oxidation with sulfur of the second portion of the stream (N) of alkyl mercaptan, to form a stream (O) comprising a dialkyl disulfide, hydrogen sulfide, and possibly unreacted alkyl mercaptan, e) purification of the stream (O) to separate, on the one hand, the enriched dialkyl disulfide and, on the other hand, the hydrogen sulfide and possibly the alkyl mercaptan that has not reacted in step d), f) recycling of the hydrogen sulfide and possibly of the alkyl mercaptan isolated in step e) into the stream (M) ob
Type:
Grant
Filed:
May 10, 2022
Date of Patent:
February 13, 2024
Assignee:
Arkema France
Inventors:
Georges Fremy, Jean-Michel Raymond, Eric Lamant
Abstract: Presented is a method of improving the incorporation of recycled bituminous products by using at least one surfactant as an alternative to the known rejuvenating oils, for the preparation of asphalt mixes containing recycled bituminous products. The use of such alternative surfactant(s) results in better mechanical properties of the asphalt mix, while using smaller amounts of fresh bitumen and greater amounts of recycled bituminous products.
Type:
Grant
Filed:
October 18, 2018
Date of Patent:
February 13, 2024
Assignee:
ARKEMA FRANCE
Inventors:
Juan Antonio Gonzalez Leon, Gilles Barreto, Vincent Luca
Abstract: The present invention relates to a process for drying methyl mercaptan, notably by azeotropic distillation, comprising the following steps: 1) a stream (A) comprising methyl mercaptan and water is introduced into a distillation column (1); 2) said stream (A) is distilled in said column (1); 3) the distillate (B) is recovered in gaseous form, preferably at the top of the column; 4) the distillate (B) is condensed, preferably in a condenser (2), so as to obtain a condensate (C) in liquid form; 5) said condensate (C) is separated, preferably using a decanter (3), so as to obtain two separate liquid phases: an aqueous phase (D); and an organic phase (E) comprising methyl mercaptan; 6) all or part of the organic phase (E) is optionally introduced into the distillation column (1) as reflux; and 7) a stream (F) comprising the dried methyl mercaptan is recovered, preferably at the bottom of column (1).
Abstract: The invention relates to a method for separation of a polymeric article comprising at least one thermoplastic polymer, and at least one other constituent, wherein said separation method comprises: —a step of contacting the polymeric article with a liquid medium suitable for propagating shock waves, and —a step of applying a pulsed field to the liquid medium, so as to generate shock waves capable of dividing the polymeric article at an interface between the thermoplastic polymer and the other constituent.
Type:
Application
Filed:
December 8, 2021
Publication date:
February 8, 2024
Applicants:
ARKEMA FRANCE, XCRUSHER
Inventors:
Jean-Luc DUBOIS, Abdelaziz BENTAJ, Nicolas COUCHOT
Abstract: The present invention relates to a process for the suspension polymerization of alkoxyamines with styrenic and (meth)acrylic monomers, to the beads and compositions thus obtained, and also to the use of these beads and compositions.
Type:
Application
Filed:
December 9, 2021
Publication date:
February 8, 2024
Applicant:
Arkema France
Inventors:
Anne-Laure Brocas, Sylvain Bourrigaud, Céline Labarthe, Patrick Saury
Abstract: A method of manufacturing a semi-crystalline article from at least one pseudo-amorphous polymer including a poly aryl ether ketone, such as PEKK, including a softening step, wherein the at least one pseudo-amorphous polymer is heated to a temperature above its glass transition temperature to soften the polymer, and a crystallization step, wherein the at least one pseudo-amorphous polymer is heated to a temperature between its glass transition temperature and melting temperature, the pseudo-amorphous polymer being placed on a mold during either the softening step or the crystallization step before at least some crystallization takes place. The method results in articles demonstrating increased opacity, increased crystallinity, increased thermal resistance, improved chemical resistance, and improved mechanical properties over articles formed by traditional thermoforming processes.
Type:
Grant
Filed:
June 8, 2022
Date of Patent:
February 6, 2024
Assignee:
Arkema Inc.
Inventors:
Bruce Clay, Timothy A. Spahr, Philippe Bussi, Richard Audry, Jason M. Lyons, Yves Deyrail
Abstract: The present invention relates to a composition for battery electrodes in which at least one solvent is a composition comprising between 80% and 95% by mass of N-methylpyrrolidone (NMP).
Abstract: A transparent molding composition including, by weight (with a total of 100%): (A) 35 to 84% of a polyamide mixture including: 10 to 95% by weight of at least one semi-crystalline aliphatic polyamide, whose average number of carbon atoms relative to nitrogen atoms is greater than or equal to 8; 90 to 5% by weight of at least one amorphous polyamide; (B) from over 10 to 30% of at least one impact modifier; (C) from 6 to 20% of short glass fibers; (D) 0 to 10% of at least one prepolymer; and (E) 0 to 5% of at least one additive selected from stabilizers, dyes, plasticizers, processing aids or a mixture thereof, the index of refraction of each constituent (A), (B), (C) and (D) being included between 1.500 and 1.540, and wherein said composition has no PEBA and has a dry-measured modulus at 23° C. over 1700 MPa.
Type:
Application
Filed:
November 16, 2021
Publication date:
January 25, 2024
Applicant:
ARKEMA FRANCE
Inventors:
Thomas PRENVEILLE, Mathieu SABARD, Fabrice GLASSON, Olivier MASSOT
Abstract: The present invention concerns a method for sulfhydrolysis from dialkyl sulfides and hydrogen sulfide, in the presence of a specific catalyst based on titanium dioxide and/or zirconium dioxide, as well as the corresponding use of such a catalyst. The present invention also concerns a method for preparing mercaptans, in particular methyl mercaptan, from at least one alcohol and hydrogen sulfide, comprising said sulfhydrolysis method.
Type:
Application
Filed:
September 28, 2020
Publication date:
January 25, 2024
Applicant:
Arkema France
Inventors:
Georges Fremy, Hélori Salembier, Guillaume Laudumiey
Abstract: The present invention relates to a liquid composition comprising a monomer, a (meth)acrylic polymer and at least three initiators. In particular the present invention relates to a liquid composition comprising a monomer, a (meth)acrylic polymer and at least three initiators that have a different half life time. That liquid composition can be used as a syrup and especially as a syrup for impregnation of fibres or fibrous material. Also concerned is a thermoplastic material obtained after polymerization of the liquid composition. The invention also relates to a process for manufacturing such a liquid composition. The invention also relates to a process for impregnating a fibrous substrate of long fibres with said liquid composition. The invention also relates to a fibrous substrate impregnated with said liquid composition which is useful for manufacturing composite parts.
Type:
Grant
Filed:
June 19, 2019
Date of Patent:
January 23, 2024
Assignee:
ARKEMA FRANCE
Inventors:
Alexander Zoller, Pierre Gerard, Pierre Escale
Abstract: The present invention relates to a non-crosslinked block copolymer foam composition, characterised in that it is in the form of a polymer matrix comprising closed cells containing gas, said matrix comprising: from 90 to 99.9% by weight of said block copolymer; and from 0.01 to 10% by weight of metal carbonate, for the total weight of the foam composition. The present invention also relates to a foamable composition and a method for manufacturing said foam, as well as the use of the foam in sports shoe soles, balloons or balls, gloves, personal protection equipment, rail soles, automobile parts, construction parts, electrical and electronic equipment parts, audio equipment, sound- and/or heat-proofing, and parts used to damp vibrations.
Type:
Application
Filed:
July 21, 2023
Publication date:
January 18, 2024
Applicant:
Arkema France
Inventors:
Clio COCQUET, Helena CHEMINET, François FERNAGUT, Yves DEYRAIL, Quentin PINEAU
Abstract: The present invention relates to a process for producing methyl mercaptan, comprising the following steps: A) methanol is reacted with hydrogen sulfide to form a stream (M), preferably in gaseous form, comprising methyl mercaptan, unreacted H2S and possibly sulfur byproducts; B) optionally, said stream (M) is condensed; C) at least one step of purification of said stream (M) is performed to obtain a stream enriched in methyl mercaptan; D) the gaseous vents resulting from said at least one purification step are recovered, said gaseous vents comprising at least one sulfur compound, preferably H2S; E) a gas-liquid extraction of said at least one sulfur compound, preferably H2S, is performed with liquid methanol so as to obtain a liquid methanol enriched in sulfur compound(s), preferably in H2S; and F) optionally, said enriched methanol is used as reagent for the reaction of step A).
Type:
Application
Filed:
December 16, 2021
Publication date:
January 18, 2024
Applicant:
ARKEMA FRANCE
Inventors:
Georges FREMY, Jean-Michel RAYMOND, Eric LAMANT
Abstract: Curable resin compositions having extended open times at ambient temperatures and short cure times at elevated temperatures are prepared using a curable resin, a combination of room-temperature-stable liquid peroxides (including at least one perketal), a promoter salt, a thiol-functionalized organic accelerator and a free radical trap. The curable resin compositions are useful in pultrusion, cure-in-place pipe and resin transfer molding applications, among others.
Abstract: The present invention relates to a method for continuously preparing a polyamide prepolymer, the viscosity in solution of which is comprised between 0.25 dL/g and 0.70 dL/g, as measured according to ISO 307:2007 in m-cresol at 20° C., the method being characterized in that it comprises a step of polycondensation on the basis of one or more polyamide precursor monomers, said polycondensation step being carried out in a extruder comprising at least two co-rotating conveying screws, the at least one monomer being previously added therein in solid or liquid form without being dissolved in a solvent or in water, and said polycondensation step being carried out without extracting the water formed during said polycondensation.
Abstract: Disclosed are voided latex particles, useful as opacifying agents for coating compositions containing organic solvents. The particles have a hollow interior, which substantially maintains its integrity after the particles are placed in contact with an organic solvent at 25° C. for 30 days. The particles also have a hydrophilic polymeric interior shell surrounding the hollow interior that is swellable with an aqueous swelling solution. The particles have first and second polymeric intermediate shells, surrounding the interior shell, formed from polymers that are different from each other and different from the interior shell polymer. Finally, the particles have an outer polymeric shell, surrounding the interior shells, which is formed from up to 100% by weight, as polymerized units, of methyl methacrylate. The interior shells and the outer shell each have a Tg greater than 60° C. Also disclosed is a multi-stage emulsion process for making the particles.
Abstract: The invention relates to a composition comprising a blend of fluorinated electroactive polymers and having a dielectric permittivity that exhibits greater stability over the operating temperature range with respect to each polymer employed on its own. The invention also relates to formulations and films produced on the basis of said composition. The invention also relates to a field-effect transistor, at least part of the dielectric layer of which is composed of a blend of fluorinated electroactive polymers.
Type:
Grant
Filed:
August 7, 2018
Date of Patent:
January 9, 2024
Assignees:
ARKEMA FRANCE, UNIVERSITE DE BORDEAUX, INSTITUT POLYTECHNIQUE DE BORDEAUX, CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE
Inventors:
Fabrice Domingues Dos Santos, Thibaut Soulestin, Damien Thuau, Georges Hadziioannou
Abstract: The invention relates to a crosslinkable prepolymer composition for use as a contrast layer. It also relates to a method for structuring an interface material. This method is characterized in particular by the following steps: depositing, on a block copolymer film, a prepolymer composition layer comprising a plurality of functional monomers and at least one crosslinkable functional group within its polymer chain and, on the other hand, two chemically different crosslinking agents, each agent being capable of initiating the crosslinking of said prepolymer in response to a stimulation specific thereto, subjecting the stack to a first stimulation localized on first areas, so as to cause a crosslinking reaction of the molecular chains of said prepolymer, and subjecting the stack to a second stimulation, so as to cause crosslinking of the molecular chains of said prepolymer by the action of said second crosslinking agent in secondary areas.
Abstract: A transparent molding composition, including by weight: (a) from 30 to 90% of at least one (co)polyamide of formula PACMY/Z, (b) from 10 to 70% by weight of at least one semi-crystalline copolyamide of formula A/WS, (c) from 0 to 10% of at least one impact modifier chosen from the polyether block amides (PEBA) and the core-shell polymers, (d) from 0 to 2% by weight of at least one additive, (e) from 0 to 5% by weight of a prepolymer; the sum of the proportions of each constituent of said composition being equal to 100%, the composition having good alcohol resistance as determined by an ethanol resistance test.
Type:
Application
Filed:
November 15, 2021
Publication date:
January 4, 2024
Applicant:
ARKEMA FRANCE
Inventors:
Stefania CASSIANO GASPAR, Benoît BRULE, Mathieu SABARD, Regis CIPRIANI
Abstract: The present invention relates to a process for synthesizing a functionalized mercaptan, comprising the reaction between a compound of formula R2—X—C*H(NR1R7)—(CH2)n-G (II) and H2S in the presence of at least one enzyme chosen from sulfhydrylases; said reaction being performed in a reactor with a partial pressure of H2S in the gas headspace of said reactor of between 0.01 and 4 bar, preferably between 0.1 and 3 bar, for example between 0.1 and 2.5 bar, and more preferentially between 0.25 and 2 bar, at the reaction temperature.
Type:
Application
Filed:
December 1, 2021
Publication date:
January 4, 2024
Applicant:
ARKEMA FRANCE
Inventors:
Jean-Christophe LEC, Georges FREMY, Arnaud DESSOMMES