Patents Assigned to Arkema
  • Publication number: 20220267519
    Abstract: A process for manufacturing a transparent polyamide including a step of polycondensation of a mixture of monomers including at least one dicarboxylic acid and at least one cycloaliphatic diamine, in which the cycloaliphatic diamine includes two rings linked by an alkylene group including 1 to 6 carbon atoms, each ring being substituted by an amine group and at least one alkyl group, which may be identical or different, including 1 to 6 carbon atoms, wherein the diamine decomposes into six isomer fractions when it is subjected to analysis by gas chromatography on a nonpolar column and, when the isomer fractions are named isomer fractions I to VI in their order of elution, the mass content FI of fraction I of the cycloaliphatic diamine does not exceed 35%. A transparent polyamide capable of being obtained by the process, and to articles obtained from such a polyamide or from such a formulation.
    Type: Application
    Filed: October 2, 2019
    Publication date: August 25, 2022
    Applicant: Arkema France
    Inventors: Thierry BRIFFAUD, Benjamin SAILLARD, Stefânia CASSIANO GASPAR, Joël VERGER, Fabienne OLIVIER-CHANU
  • Patent number: 11421142
    Abstract: Provided is a composition comprising at least one polymer, the repeat unit of which comprises at least one amide functional group, at least one polyetheramine with a weight-average molecular weight (Mw) of greater than 100 g.mo1?1 and exhibiting at least two secondary and/or tertiary amine functional groups, and optionally, but preferably, at least one organic solvent. Also provided is method of using of the composition for delaying, indeed even preventing, the formation of gas hydrates, in particular in a process for extracting oil and/or gas and/or condensates, and also to the process for delaying, indeed even preventing, the formation and/or the agglomeration of gas hydrates, employing a composition as defined above.
    Type: Grant
    Filed: May 3, 2018
    Date of Patent: August 23, 2022
    Assignee: Arkema France
    Inventors: Tong Eak Pou, Frédéric Moser
  • Publication number: 20220258407
    Abstract: The invention relates to an additive manufacturing process by extrusion for forming a three-dimensional part in an additive manufacturing machine having a build environment, the process comprising: i) providing a composition comprising at least one poly-aryl-ether-ketone (PAEK) having a melt viscosity from about 200 Pa·s to about 1500 Pa·s, according to ASTM D3835-16, measured at a temperature of 320° C. and at a shear rate of 100 s?1, by capillary rheology using a 1 mm diameter, 15 mm long die; ii) extruding the composition in the build environment at an extrusion temperature equal to 330° C. or less, to form an extruded part section; and, iii) cooling the extruded part section in the build environment. The invention also relates to a filament and its use in said additive manufacturing process and the corresponding object obtainable from said additive manufacturing process.
    Type: Application
    Filed: June 26, 2020
    Publication date: August 18, 2022
    Applicant: Arkema France
    Inventors: Roderick REBER, David LIU, Evan FISHER
  • Publication number: 20220258439
    Abstract: A thin-walled mold and a method for manufacturing a part made of composite material, the material including reinforcing fibers and a polymer matrix, the method including the following consecutive steps: installing, in a matrix mounted on a press, a closed thin-walled mold in which reinforcing fibers have been arranged; closing the press; injecting a polymer or a reactive composition including at least one prepolymer, at least one monomer or a mixture thereof, in the molten state, into the closed thin-walled mold; keeping the press closed during all or part of the polymerisation of the polymer matrix when a reactive composition is used; opening the press and removing the thin-walled mold from the press, while maintaining a residual pressure of between 0.7 and 10 bar, preferably between 0.7 and 5 bar, inside the mold; and cooling the mold under said residual pressure.
    Type: Application
    Filed: July 22, 2020
    Publication date: August 18, 2022
    Applicant: Arkema France
    Inventor: Gilles HOCHSTETTER
  • Publication number: 20220258446
    Abstract: A multilayer structure selected from a reservoir, a pipe or a tube, for transporting, distributing or storing hydrogen, including, from the inside to the outside, at least one sealing layer and at least one composite reinforcing layer, the innermost composite reinforcing layer being welded to the outermost adjacent sealing layer, the sealing layers including at least one semi-crystalline thermoplastic polymer, the Tm of which is less than 280° C., wherein the at least one thermoplastic polymer of each sealing layer may be the same or different, and at least one of the composite reinforcing layers being of a fibrous material in the form of continuous fibers impregnated with a composition of at least one thermoplastic polymer P2j, the thermoplastic polymer P2j having a Tg greater than the maximum temperature of use of said structure (Tu), with Tg?Tu+20° C., Tu being greater than 50° C.
    Type: Application
    Filed: July 28, 2020
    Publication date: August 18, 2022
    Applicant: Arkema France
    Inventors: Gilles HOCHSTETTER, Patrick DANG, Thibaut SAVART
  • Publication number: 20220259624
    Abstract: The present invention relates to a selective process for preparing sulfoxides from sulfides by enzymatic catalysis, and to a composition comprising a symmetrical sulfide, an oxidoreductase enzyme catalyzing the oxidation of said symmetrical sulfide to symmetrical sulfoxide; optionally at least one cofactor C of said enzyme E; and an oxidant, which allows in particular the implementation of said process.
    Type: Application
    Filed: June 12, 2020
    Publication date: August 18, 2022
    Applicants: Arkema France, Centre National de la Recherche Scientifique (CNRS), Universite d'Aix-Marseille
    Inventors: Georges Fremy, Hugo Brasselet, Véronique Alphand, Katia Duquesne
  • Patent number: 11417929
    Abstract: The Invention Relates To A Battery Compartment For An Electric Or Hybrid Vehicle, Characterised In That It Consists Of A Composition Comprising: —20 To 80 Wt % Of Reinforcement Fibres Relative To The Total Weight Of The Composition; —0 To 20 Wt % Of At Least One Impact Modifier Relative To The Total Weight Of The Composition; —0 To 20 Wt % Of Additives Relative To The Total Weight Of The Composition; —The Remainder Being A Matrix Comprising: —Mainly At Least One Polyamide And—At Least One Flame Retardant.
    Type: Grant
    Filed: October 1, 2018
    Date of Patent: August 16, 2022
    Assignee: ARKEMA FRANCE
    Inventors: Wissam Rached, Nicolas Dufaure
  • Patent number: 11413832
    Abstract: The invention relates to a process for manufacturing a preimpregnated fibrous material containing a fibrous material made of continuous fibers and at least one thermoplastic polymer matrix, wherein the preimpregnated fibrous material is produced as a single unidirectional tape or of a plurality of parallel unidirectional tapes and wherein the process includes a step of impregnating, in particular fully and homogeneously, the fibrous material that is in the form of a roving or of several parallel rovings with the at least one thermoplastic polymer matrix that is in powder form, the impregnating step being carried out by a dry route in a tank and the control of the amount of the at least one thermoplastic polymer matrix in said fibrous material being achieved by control of the residence time of said fibrous material in the powder, with the exclusion of any electrostatic process with intentional charging.
    Type: Grant
    Filed: December 20, 2017
    Date of Patent: August 16, 2022
    Assignee: Arkema France
    Inventors: Gilles Hochstetter, Arthur Pierre Babeau, Thibaut Savart, François Tanguy, Denis Huze, Mathieu Capelot, Patrice Gaillard
  • Patent number: 11407906
    Abstract: A method for producing a surface coated with a coating having an improved coalescence, the method including: providing a composition comprising from 99.6% to 99.99% by weight of at least one powder of at least one polyarylene ether ketone and 0.01 to 0.4% by weight of a hydrophilic flow agent, the hydrophilic flow agent being hydrophilic silica; depositing the composition onto a surface forming a coated surface; and baking the coated surface to form a film on the surface.
    Type: Grant
    Filed: July 25, 2018
    Date of Patent: August 9, 2022
    Assignee: ARKEMA FRANCE
    Inventors: Benoît Brule, Hervé Ster, Cyrille Mathieu, Nadine Decraemer
  • Publication number: 20220243843
    Abstract: A multilayer structure for transporting or storing gas or for exploiting oil or gas deposits under the sea, including, from the inside to the outside, at least one sealing layer and at least one composite reinforcing layer, the innermost composite reinforcing layer being welded to the outermost adjacent sealing layer, the sealing layers of a composition including at least one semi-crystalline thermoplastic polymer, the Tm of which is less than 280° C., wherein at least one of the composite reinforcing layers of a fibrous material in the form of continuous fibers impregnated with a composition including at least one thermoplastic polymer, the thermoplastic polymer having a Tg greater than the maximum temperature of use of the structure (Tu), with Tg?Tu+20° C., Tu being greater than 50° C., and a multilayer structure selected from a reservoir, a pipe or a tube for transporting or storing hydrogen being excluded.
    Type: Application
    Filed: July 28, 2020
    Publication date: August 4, 2022
    Applicant: Arkema France
    Inventor: Gilles HOCHSTETTER
  • Publication number: 20220242994
    Abstract: The present invention concerns the use of PCL in preparing a block copolymer comprising at least one rigid block and at least one flexible block, for enhancing the sebum resistance of said block copolymer. The present invention also provides a sebum-resistant block copolymer, characterized in that it comprises rigid blocks and flexible blocks comprising at least 50% by weight of PCL, based on the total weight of flexible blocks, which represents 100%; a process for synthesizing said copolymer; and also compositions and articles comprising a sebum-resistant copolymer of this kind.
    Type: Application
    Filed: May 27, 2020
    Publication date: August 4, 2022
    Applicant: Arkema France
    Inventors: Blandine TESTUD, Quentin PINEAU
  • Patent number: 11401378
    Abstract: A process for synthesizing polyamide PA 6-6, including a first step of reacting, in the presence of water, a compound of R0COO—(CH2)4—COOR?0 in which R0 and R?0, which may be identical or different, represent H or a linear or branched alkyl radical comprising from 1 to 4 carbon atoms, with hexamethylenediamine (HMDA), at a temperature of less than or equal to 160° C., to form a reaction medium, and then a second step of heating the reaction medium to a temperature of greater than or equal to 200° C.; the reaction medium also including a compound of R1—COO—(CH2)n—CH?CH—(CH2)n—COO—R2 and/or a compound of R3—(CH2)m—CH?CH—(CH2)n—COO—R4.
    Type: Grant
    Filed: July 25, 2017
    Date of Patent: August 2, 2022
    Assignee: ARKEMA FRANCE
    Inventor: Jean-Luc Dubois
  • Publication number: 20220234892
    Abstract: The present invention relates to an improved process for preparing hydrazine hydrate from the azine of methyl ethyl ketone obtained from methyl ethyl ketone by oxidizing ammonia with hydrogen peroxide in the presence of an activator, characterized in that it comprises a step of recycling the methyl ethyl ketone oxime purge.
    Type: Application
    Filed: May 12, 2020
    Publication date: July 28, 2022
    Applicant: Arkema France
    Inventor: Jean-Marc Sage
  • Publication number: 20220235239
    Abstract: ABTRACT The present invention relates to a liquid, thermoplastic acrylic gel cap composition that can impart UV resistance, higher impact, and aesthetic effects to a composite material. Additionally, the post processing of the material when combined with a thermoplastic composite can allow for thermoformability, weldability and recyclability, unlike seen with traditional thermoset based gel coats.
    Type: Application
    Filed: June 3, 2020
    Publication date: July 28, 2022
    Applicants: ARKEMA INC., GLIMA INNOVATION LTDA
    Inventors: Gilmar DA COSTA LIMA, Robert J. BARSOTTI, Dana L. SWAN
  • Patent number: 11396600
    Abstract: The invention relates to the use of at least one impact modifier having a refractive index IR1 in a polyamide matrix consisting of a mixture of amorphous polyamide and semicrystalline polyamide, said matrix having a refractive index IR2, the difference in absolute value of IR1-IR2 not exceeding 0.006, to produce a transparent composition having a fatigue strength, under the fatigue test referred to as notched “Ross-Flex”, greater than 50 000 at ?10° C.
    Type: Grant
    Filed: July 6, 2018
    Date of Patent: July 26, 2022
    Assignee: ARKEMA FRANCE
    Inventors: Mathieu Sabard, Benoit Brule, Benjamin Saillard, Regis Cipriani
  • Patent number: 11396491
    Abstract: An acrylated and/or methacrylated urethane oligomer obtained by reaction of a specific polyamine with a cyclic carbonate compound carrying m cyclic carbonate groups, giving an intermediate product carrying m formed urethane groups which carry residual reactive amine —NH— groups, and subsequently an addition reaction of each of the residual reactive amine groups of the intermediate product with an acrylate group of a compound carrying, in addition to the acrylate group, p additional acrylate and/or methacrylate groups, with each residual reactive amine —NH— group of the intermediate product being thus converted into a carbon-nitrogen bond carrying the acrylate and/or methacrylate groups, and thus production of the urethane oligomer, with the urethane oligomer carrying m urethane groups and m hydroxyl groups and having a functionality in acrylates and/or methacrylates ranging from m*p(n?1) to m*p(2n?2).
    Type: Grant
    Filed: October 13, 2015
    Date of Patent: July 26, 2022
    Assignee: Arkema France
    Inventors: Guillaume P. Monnier, Catherine M. Leroy
  • Publication number: 20220227627
    Abstract: The present invention relates to an improved process for preparing hydrazine hydrate from the azine of methyl ethyl ketone obtained from methyl ethyl ketone by oxidizing ammonia with hydrogen peroxide in the presence of an activator, characterized in that it comprises a step of recycling the pyrazoline-class heterocycles purge.
    Type: Application
    Filed: May 12, 2020
    Publication date: July 21, 2022
    Applicant: Arkema France
    Inventor: Jean-Marc Sage
  • Patent number: 11390008
    Abstract: A method of manufacturing a semi-crystalline article from at least one pseudo-amorphous polymer including a poly aryl ether ketone, such as PEKK, including a softening step, wherein the at least one pseudo-amorphous polymer is heated to a temperature above its glass transition temperature to soften the polymer, and a crystallization step, wherein the at least one pseudo-amorphous polymer is heated to a temperature between its glass transition temperature and melting temperature, the pseudo-amorphous polymer being placed on a mold during either the softening step or the crystallization step before at least some crystallization takes place. The method results in articles demonstrating increased opacity, increased crystallinity, increased thermal resistance, improved chemical resistance, and improved mechanical properties over articles formed by traditional thermoforming processes.
    Type: Grant
    Filed: December 11, 2019
    Date of Patent: July 19, 2022
    Assignee: Arkema Inc.
    Inventors: Bruce Clay, Timothy A. Spahr, Philippe Bussi, Richard Audry, Jason M. Lyons, Yves Deyrail
  • Patent number: 11390776
    Abstract: The present invention relates to a composition suitable as (meth)acrylic adhesive composition comprising a multistage polymer in form of polymeric particles and a (meth)acrylic polymer, its process of preparation, and its use. In particular the present invention relates to a structural (meth)acrylic adhesive composition comprising a multistage polymer in form of polymeric particles made by a multistage process and a (meth)acrylic polymer, its process of preparation and its use. More particularly the present invention relates to structural (meth)acrylic adhesive composition made from a two part composition comprising a multistage polymer in form of polymeric particles made by a multistage process and a (meth)acrylic polymer, its process of preparation, and its use.
    Type: Grant
    Filed: July 12, 2018
    Date of Patent: July 19, 2022
    Assignee: Arkema France
    Inventors: Philippe Hajji, Rosangela Pirri, Rabi Inoubli, Guillaume Michaud
  • Publication number: 20220220257
    Abstract: The invention relates to a self-retardant copolyesteramide, characterised in that it is obtained by means of polycondensation of at least one polyamide monomer with at least one phosphorus-containing diol. The invention also relates to the use of such a copolyesteramide according to the invention for the manufacture of electrical and/or electrotechnical objects, tubes, cables, electrical safety objects, moulded objects, and/or objects obtained by 3D printing.
    Type: Application
    Filed: May 27, 2020
    Publication date: July 14, 2022
    Applicant: Arkema France
    Inventors: Quentin PINEAU, Jean-Jacques FLAT, Marie-Ange LEMAITRE