Abstract: Cellulose composites of cellulose and a hydrophilic gum, the cellulose composite giving a 1-mass % aqueous dispersion thereof, which has a storage modulus (G?) of 0.06 Pa or more when the pH thereof is 4.
Abstract: An object of the present invention is to provide a method for, when stopping an ammoxidation reaction of propane, stopping the ammoxidation reaction safely and quickly, without causing a deterioration in catalytic activity or acrylonitrile yield. The method for stopping an ammoxidation reaction includes a supply stopping step of stopping a supply of propane, an oxygen-containing gas, and ammonia to a reactor where an ammoxidation reaction of propane is being carried out using a catalyst, and a reaction stopping step of supplying an inert gas to the reactor in an amount 10 to 300 times the catalyst volume per hour until the catalyst temperature reaches 380° C. or less, wherein after the supply stopping step, a time required until the catalyst temperature decreases to 360° C. or less is within 10 hours.
Abstract: An oxide catalyst for use in an oxidation reaction of an olefin and/or an alcohol, the oxide catalyst comprising: the oxide catalyst contains molybdenum, bismuth, iron, cobalt, and cerium; an atomic ratio a of bismuth to 12 atoms of molybdenum is 2?a?6, an atomic ratio b of iron to 12 atoms of molybdenum is 2.5<b?5, an atomic ratio c of cobalt to 12 atoms of molybdenum is 2?c?8, an atomic ratio d of cerium to 12 atoms of molybdenum is 0.5?d?6, and an atomic ratio of iron/cobalt is 0.4?b/c?2.5; wherein when a spacing d of a complex oxide of cerium and molybdenum showing a peak at 33.50° in a X-ray diffraction is taken as a reference, a change rate of d is 5000 to 9000 ppm.
Type:
Grant
Filed:
June 13, 2012
Date of Patent:
May 24, 2016
Assignee:
ASAHI KASEI CHEMICALS CORPORATION
Inventors:
Jun Yoshida, Tatsuo Yamaguchi, Kenji Izumiyama
Abstract: The present invention provides a polyolefin powder including a homopolymer of ethylene or a copolymer of ethylene and an ?-olefin having 3 to 15 carbon atoms.
Abstract: It is an object of the present invention to provide a hydrogenated block copolymer pellet, which has the ability to become a molded product that is excellent in transparency, flexibility, bleeding resistance, and low combustion ash content, without causing blocking among pellets. A hydrogenated block copolymer pellet having 100 parts by mass of a pellet molded product of hydrogenated block copolymer A and 0.01 to 1.
Type:
Grant
Filed:
June 25, 2013
Date of Patent:
May 17, 2016
Assignee:
Asahi Kasei Chemicals Corporation
Inventors:
Yasuhiro Kusanose, Mika Horiuchi, Noriko Yagi
Abstract: The present invention relates to a cation exchange membrane comprising a fluorine-containing polymer containing a tetrafluoroethylene unit and a perfluoroethylene unit having a carboxylic acid-type ion exchange group, wherein a melt index a of the fluorine-containing polymer from methyl esterifying the carboxylic acid-type ion exchange group measured under the condition at 270° C., a load of 2.16 kg and an orifice inner diameter of 2.09 mm is 3 to 50 g/10 min, and the melt index a and a melt index b of the fluorine-containing polymer from methyl esterifying the carboxylic acid-type ion exchange group measured under the condition at 260° C., a load of 2.16 kg and an orifice inner diameter of 2.09 mm satisfy the relation represented by the following expression (1): (a?b)/(270?260)?0.027×a+0.19??(1).
Abstract: Disclosed is a composition comprising (A) at least one compound selected from the group consisting of an ether compound having two or more ether groups, a trivalent phosphorus compound, and a ketone compound, (B) a boron trihalide, and (C) an episulfide compound.
Abstract: The present invention relates to a curable resin composition comprising (A) an epoxy compound having three or more epoxy groups in one molecule and (B) an active hydrogen compound.
Abstract: A thermoplastic resin composition containing a graft copolymer (A) and a thermoplastic resin (B), in which the thermoplastic resin (B) contains a polymer having a vinyl cyanide monomer unit, the graft copolymer (A) and the thermoplastic resin (B) are contained in predetermined proportions based on the total amount of the graft copolymer (A) and the thermoplastic resin (B), the graft copolymer (A) has a main-chain polymer formed of a rubbery polymer and a graft chain, the graft chain has a vinyl cyanide monomer unit and at least one monomer unit copolymerizable with the vinyl cyanide monomer, the distribution of the content of the vinyl cyanide monomer unit in components derived from a graft chain has peak 1 having a peak top within a content range from 0 mass % or more to less than 10 mass %, and peak 2 having a peak top within a content range from 10 mass % or more to less than 55 mass %, and the difference between a representative value of the content represented by peak 1 and a representative value of the
Abstract: A method for producing a condensation polymerization reaction polymer, comprising a guide polymerization step in which a molten prepolymer is supplied to the top edge of a wire guide to obtain the condensation polymerization reaction polymer, the wire guide comprising a vertical wire group consisting of a plurality of vertical wires extending in the vertical direction, which are mutually spaced in alignment at an arrangement pitch L1 (mm). In the guide polymerization step, the molten prepolymer aggregates so that a molten prepolymer mass is formed on the vertical wire, and a molten prepolymer mass is formed wherein, the width of the molten prepolymer mass measured in an alignment direction of the vertical wires at a position 200 mm below the top edge being represented as L2 (mm), the width L2 of at least a portion of the molten prepolymer mass satisfies the inequality (1).
Abstract: A polyamide resin composition including a polyamide resin (A), a copper compound (B), a bromide of an alkali metal and/or a bromide of an alkaline earth metal (C), and at least one fatty acid compound (D) selected from the group consisting of fatty acid esters, fatty acid amides, and fatty acid metal salts, wherein the fatty acid compound (D) has an acid value of 5 mg/g or less.
Abstract: A polyamide resin composition including a polyamide resin (A), a copper compound (B), a bromide of an alkali metal and/or a bromide of an alkaline earth metal (C), and an amphoteric compound and/or a basic compound (D).
Abstract: A method for producing a modified conjugated diene polymer comprising a polymerization step of obtaining a conjugated diene polymer containing a nitrogen atom in a polymer chain and an active end by copolymerizing a conjugated diene compound and a nitrogen atom-containing vinyl compound, or a conjugated diene compound, an aromatic vinyl compound and a nitrogen atom-containing vinyl compound by use of an alkali metal compound and/or an alkaline earth metal compound as a polymerization initiator, and a modification step of reacting a modifier.
Abstract: The present invention provides a process for producing olefin having 3 or more carbon atoms from ethane stably in a simpler process. The present invention provides a method for producing olefin having a step of obtaining a cold fraction by cooling an ethane-cracked gas, which is obtained by thermal cracking of ethane in the presence of steam, to 600° C. or less; and a step of obtaining a catalytic cracking gas containing olefin having 3 or more carbon atoms by bringing the cold fraction into contact with a catalyst containing a medium pore diameter zeolite.
Abstract: A method for producing a modified conjugated diene-based polymer having a good balance between the hysteresis loss properties and the wet skid resistance, practically sufficient abrasion resistance and breaking strength, and high processability when formed into a vulcanized product is provided. A method for producing a modified conjugated diene-based polymer, comprising: a polymerization step of polymerizing a conjugated diene compound, copolymerizing conjugated diene compounds, or copolymerizing a conjugated diene compound with an aromatic vinyl compound using an alkali metal compound or an alkaline earth metal compound as a polymerization initiator to obtain a conjugated diene-based polymer having an active end, and a modifying step of reacting a compound represented by following formula (1) with the active end of the conjugated diene-based copolymer.
Abstract: Disclosed is a metallic pigment composition which can provide, when used in a coating composition, an ink composition or the like, in particular, a water-based coating, a water-based ink or the like, a coating film having a high storage stability, a good adhesiveness, a good chemical resistance and a good color tone. Specifically disclosed is a metallic pigment composition which comprises at least one kind of compound selected from a heteropolyanion compound and a mixed-ligand heteropolyanion compound, an organic oligomer or polymer, and metal grains.
Abstract: To provide a connection structure for a photovoltaic power generation module which is excellent in long-term heat resistance and which is excellent in low-temperature impact resistance even if the structure is reduced in wall thickness and size. There is provided a connection structure (1) for a photovoltaic power generation module which at least joins a photovoltaic power generation module to a cable for connecting to the photovoltaic power generation module, the connection structure for the photovoltaic power generation module comprising a thermoplastic resin composition having, as an index of long-term heat resistance, a relative thermal index (RTI) of tensile impact strength at a thickness of 1.5 mm of 115° C. or higher, and a Charpy impact strength at ?40° C. of 6.5 kJ/m2 or more.
Abstract: A composition containing an oxide of titanium contains a conjugated dienic polymer and the oxide of titanium, wherein the content of the oxide of titanium is 0.10 to 75 ppm by mass in terms of titanium atom, and the average particle diameter of the oxide of titanium is 1.0 to 100 ?m.
Abstract: An uncoated, highly reflective, impact-resistant injection-molded article which comprises a rubber ingredient (A) and a thermoplastic resin (B), characterized in that (1) the rubber ingredient (A) has been dispersed in the thermoplastic resin (B), (2) the rubber ingredient (A) has a coefficient of linear expansion of 12.5×10?5 to 19×10?5/° C., (3) the surface of the injection-molded article has a reflected-image clarity of 60-100%, and (4) the injection-molded article has a notched Charpy impact strength of 5-60 kJ/m2.
Abstract: A method for producing an isocyanate, comprising: a carbamation step of generating an N-substituted carbamate from an organic primary amine, urea and an organic hydroxy compound according to a carbamation reaction, and then recovering a first gaseous phase component containing the urea and/or a compound having a carbonyl group derived from the urea, the organic hydroxy compound, and ammonia; a condensation step of condensing the first gaseous phase component with a condenser; an isocyanate production step of producing an isocyanate by subjecting the N-substituted carbamate to pyrolysis; an ammonia absorption step of allowing a second gaseous phase component containing ammonia recovered as a gaseous phase component from the condenser as a main component, to be absorbed by absorption water, and generating gas-absorbed water; and an ammonia stripping step of heating the gas-absorbed water to separate ammonia from the gas-absorbed water.