Abstract: A composition capable of radiation activated catalysis is provided. The composition comprises a metal compound, a mercapto compound and an olefinic compound. Radiation curable urethane compositions comprising the disclosed composition are also provided. The radiation curable urethane compositions comprise the disclosed composition, a hydroxyl compound and an isocyanate compound. Activation of the composition by radiation in a urethane formulation provides for an efficient method of curing the urethane composition. Coating and adhesive compositions comprising the radiation curable urethane compositions are also provided. In addition, methods for coating and bonding substrates are disclosed.

Abstract: A method of producing a flexible laminate and a flexible laminate produced by the method are provided. The method involves laminating flexible substrates with a urethane adhesive and allowing the urethane adhesive to cure. The urethane adhesive comprises at least one polyisocyanate, at least one polyfunctional curative, at least one metal based catalyst and a catalyst blocking agent. The catalyst blocking agent allows for improved control of the curing rate of the urethane adhesive in the flexible laminate. The curing rate of the urethane adhesive can be controlled with heat or actinic radiation or both. The method allows for faster and more economical production of flexible laminates.

Abstract: The present disclosure relates generally to resin formulations for sheet molding compounds. Particularly, but not by way of limitation, the invention relates to low-density thermosetting sheet molding compounds (SMC) comprising an organic-modified, inorganic clay, a thermosetting resin, a low profile agent, a reinforcing agent, a low-density filler, and substantially the absence of calcium carbonate. The present disclosure relates particularly to the use of alternative reactive monomers present as aromatic, multiethylenically-unsaturated compounds that aid thermosetting SMC in yielding exterior and structural thermoset articles, e.g. auto parts, panels, etc that have Class A Surface Quality.

Abstract: The present disclosure relates generally to resin formulations for sheet molding compounds. Particularly, but not by way of limitation, the disclosure relates to low-density thermosetting sheet molding compounds (SMC) comprising a treated inorganic clay, a thermosetting resin, a low profile agent, a reinforcing agent, a low-density filler, and substantially the absence of calcium carbonate. The thermosetting SMC are used to prepare exterior and structural thermoset articles, e.g. auto parts and panels, etc that have Class A Surface Quality.

Abstract: The present disclosure relates generally to resin formulations for sheet molding compounds. Particularly, but not by way of limitation, the invention relates to low-density thermosetting sheet molding compounds (SMC) comprising an organic-modified, inorganic clay, a thermosetting resin, a low profile agent, a reinforcing agent, a low-density filler, and substantially the absence of calcium carbonate. The present disclosure relates particularly to blends of isophthalate modified, maleic-glycol polyester resin -glycol and maleate-glycol polyester resins that provide low density, thermosetting SMC that yields exterior and structural thermoset articles, e.g. auto parts, panels, etc that have Class A Surface Quality.

Abstract: The invention is a composition comprising a blend of two or more epoxide containing compositions selected from epoxidized vegetable oils, epoxidized alkyl esters or cycloaliphatic epoxides. In another embodiment, the invention is a blend of one or more epoxidized vegetable oils, epoxidized alkyl esters, or cycloaliphatic epoxides with one or more aromatic epoxides or epoxy functionalized polyoxyalkylene polyols.

Abstract: This invention relates to a liquid composition for the control of pitch deposition in pulp and paper making comprising an aqueous solution of (1) a cationic guar polymer, and (2) isobutylene/maleic anhydride copolymer. The invention also relates to a process for inhibiting pitch and stickies deposition in pulp and papermaking systems.

Abstract: This invention relates to a corrosion inhibiting composition comprising (a) an aliphatic amine, (b) an azole selected from the group consisting of (1) tolyltriazole, (2) benzotriazole, and (3) mixtures thereof, and (c) a benzoate. The compositions are particularly useful in inhibiting the corrosion of metal equipment, particularly equipment made from cast iron and aluminum, and more particularly, engine blocks that have been subjected to water flushing. The invention also relates to a process for inhibiting corrosion, particularly the vapor phase corrosion of metal equipment.

Abstract: This invention relates generally to water resistant peelable protective and decorative clear or pigmented coating compositions and, more specifically, to solvent and aqueous based, polymeric coating compositions which form a protective and/or decorative coating on a variety of substrates, including automotive paints, metals, plastics, concrete, natural and synthetic elastomers, and ceramics. The coatings are be formulated for temporary or long term protection depending upon the application.

Abstract: The invention detailed herein comprises a family of novel multifunctional acrylate ionomeric resins, which are water-dispersible, and have built-in photoinitiator. The inventive resins are made self-photoinitiating by their reaction with ?-keto esters (e.g., acetoacetates), ?-diketones (e.g., 2,4-pentanedione), ?-keto amides (e.g., acetoacetanilide, acetoacetamide), and/or other ?-dicarbonyl compounds that can participate in the Michael addition reaction as “Michael donors.” These water-dispersible resins cure under standard ultraviolet (UV) cure conditions to give tack-free coatings without the addition of traditional photoinitiators. The present invention further relates to the use of these resins in coatings.

Abstract: The invention detailed herein comprises a family of radiation-curable coating formulations specifically for wood substrates. These coating formulations are based on multifunctional acrylate resins formed by the reaction of acrylate monomers and oligomers with ?-keto esters (e.g., acetoacetates), ?-diketones (e.g., 2,4-pentanedione), ?-keto amides (e.g., acetoacetanilide, acetoacetamide), and/or other ?-dicarbonyl compounds that can participate in the Michael addition reaction. These coating resins will cure under standard UV-cure conditions without the addition of traditional photo initiators.

Abstract: The present invention relates to radiation-curable coating formulations specifically for plastic substrates. The present invention specifically relates to resinous Michael addition products of ?-dicarbonyl compounds and Lewis-functional multifunctional acrylate esters. The present invention father relates to methods of fabricating and using the inventive compounds.

Abstract: The present invention relates generally to radiation-curable ink formulations, and particularly, but not by way of limitation, to a family of radiation-curable ink formulations specifically for lithographic printing applications. The inventive ink formulations are based on multifunctional acrylate resins formed by the reaction of acrylate monomers and oligomers with ?-keto esters (e.g., acetoacetates), ?-diketones (e.g., 2,4-pentanedione), ?-keto amides (e.g., acetoacetanilide, acetoacetamide), and/or other ?-dicarbonyl compounds that can participate in Michael addition reactions.

Abstract: A protective lubricating composition is provided which will penetrate readily to closely fitting frictional parts and form a protective non-migrating lubricating film improving lubrication between the moving parts reducing friction and wear and preventing corrosion. The lubricant composition may be combined with solvents and propellants to make a sprayable lubricant composition.

Abstract: Thiolene-curing adhesive formulations, methods of preparation, and uses thereof are provided.

Abstract: This invention relates to thermosetting inorganic clay nanodispersions comprising an inorganic clay treated in situ with an intercalation agent and a non-aqueous, chemically reactive, organic intercalation facilitating agent, wherein the amount of intercalation facilitating agent is sufficient to facilitate intercalation and to disperse said inorganic clay. The thermosetting inorganic clay nanodispersions comprise an inorganic clay dispersed in an intercalating agent and an intercalation facilitating agent. Thermosetting inorganic clay nanodispersions are used to prepare thermosetting nanocomposite articles.

Abstract: This invention relates to polyisocyanate compositions comprising (a) polyisocyanate, and (b) a monomeric carbodiimide. The polyisocyanate compositions are particularly useful in phenolic urethane foundry binder systems. The invention also relates to foundry mixes prepared with (a) a phenolic urethane binder containing the polyisocyanate composition, and (b) a foundry aggregate, as well as foundry shapes prepared by the no-bake and cold-box processes, which are used to make metal castings.

Abstract: The invention detailed herein comprises a family of multifunctional acrylate oligomers which are useful as pigment grinding vehicles for use in radiation-curable coating formulations. The multifunctional acrylate resins are formed by the reaction of acrylate monomers and oligomers with ?-keto esters (e.g., acetoacetates), ?-diketones (e.g., 2,4-pentanedione), ?-keto amides (e.g., acetoacetanilide, acetoacetamide), and/or other ?-dicarbonyl compounds or Michael “donors” that can participate in the Michael addition reaction. These resin vehicles have a built-in chromophore that enables ink formulations made from their dispersions to cure under standard UV-cure conditions with significantly less photoinitiator than commercial formulations. The resins also exhibit excellent pigment wetting characteristics and can be designed to function as a single dispersion vehicle for different pigments and different ink applications such as screen, flexographic, and lithographic printing.

Abstract: The present invention relates generally to radiation-curable ink formulations, and particularly, but not by way of limitation, to a family of radiation-curable ink formulations specifically for flexographic and screen printing applications. The inventive ink formulations are based on multifunctional acrylate resins formed by the reaction of acrylate monomers and oligomers with ?-keto esters (e.g., acetoacetates), ?-diketones (e.g., 2,4-pentanedione), ?-keto amides (e.g., acetoacetanilide, acetoacetamide), and/or other ?-dicarbonyl compounds that can participate in Michael addition reactions.

Abstract: Oligomers from multifunctional acrylates and organonitro compounds are provided. Films obtained from crosslinked oligomers of the present invention are useful as protective or decorative coatings as well as components in adhesives and composites.