Patents Assigned to ASK Chemicals GmbH
  • Patent number: 11858030
    Abstract: The subject matter of the invention are sizing compositions containing an aqueous carrier liquid, refractory base materials and CH-acidic compounds, as well as their use for casting molds, as well as casting molds coated with the sizing composition.
    Type: Grant
    Filed: July 19, 2019
    Date of Patent: January 2, 2024
    Assignee: ASK Chemicals GmbH
    Inventors: Christian Priebe, Markus Bung, Sarah Voss, Jörg Körschgen
  • Patent number: 11759847
    Abstract: The invention relates to a binder, which contains water glass and further a phosphate or a borate or both. The invention further relates to a method for constructing molds and cores layer by layer, the molds and cores comprising a construction material mixture, which at least comprises a refractory molding base material, and the binder. In order to produce the molds and cores layer by layer in 3-D printing, the refractory molding base material is applied layer by layer and is selectively printed with the binder layer by layer, and consequently a body corresponding to the molds or cores is constructed and the molds or cores are released after the unbonded construction material mixture has been removed.
    Type: Grant
    Filed: October 13, 2022
    Date of Patent: September 19, 2023
    Assignee: ASK Chemicals GmbH
    Inventors: Heinz Deters, Henning Zupan
  • Patent number: 11466117
    Abstract: The invention relates to a binder based on phenolic resins of the benzyl ether type and isocyanate compounds having at least two isocyanate groups, containing free phenol and free hydroxybenzyl alcohols in the polyol component. The invention further relates to mold material mixtures containing the binder and to cores, molds, or risers produced with the mold material mixtures and to the use thereof in metal casting.
    Type: Grant
    Filed: December 22, 2017
    Date of Patent: October 11, 2022
    Assignee: ASK Chemicals GmbH
    Inventors: Christian Priebe, Philipp Schneider, Mark Stancliff, Brian Weaver
  • Patent number: 11253912
    Abstract: The invention relates to a method for producing three-dimensionally layered shaped bodies by means of layer-by-layer construction using a resin component which contains at least one furane resin, and more than 5% by weight and less than 50% by weight monomer furfuryl alcohol, and an acid. The shaped bodies produced in this manner are suitable inter alia as casting molds and casting cores for metal casting.
    Type: Grant
    Filed: June 5, 2018
    Date of Patent: February 22, 2022
    Assignee: ASK CHEMICALS GMBH
    Inventors: Natascha Hurkes, Dennis Bartels, Jens Müller
  • Patent number: 11213881
    Abstract: The object of the invention is a component system for producing a binder for metal casting on the basis of phenolic resins of the benzyl ether type and isocyanates containing non-polar solvents.
    Type: Grant
    Filed: December 22, 2017
    Date of Patent: January 4, 2022
    Assignee: ASK CHEMICALS GMBH
    Inventors: Christian Priebe, Jens Müller, Heinz Deters, Philip Schneider, Frank Lenzen, Markus Dörschel
  • Patent number: 10947410
    Abstract: The present invention relates to a coated granular substance, wherein the coating comprises a resin comprising the reaction product of a polyol component and an isocyanate component and cured by the addition of a catalyst, said catalyst comprising a hydroxy group-containing amine compound. Further, the present invention relates to a process for coating a granular substance, comprising the steps of (a) providing a granular substance; (b) providing a polyol component and an isocyanate component; (c) optionally mixing the polyol component with the isocyanate component; (d) adding the mixture of step (c) or the polyol component and the isocyanate component as individual substances to the provided granular substance and producing a coating on the granular substance; (e) adding a catalyst to cure the coating; (f) optionally repeating steps (d) and (e), wherein the catalyst comprises a hydroxy group-containing amine compound.
    Type: Grant
    Filed: April 12, 2016
    Date of Patent: March 16, 2021
    Assignee: ASK CHEMICALS GMBH
    Inventors: Carolin Wallenhorst, Reinhard Winter, Jan Klesing
  • Patent number: 10919085
    Abstract: The subject matter of the invention is mold material mixtures for producing molds or cores for metal casting, consisting of at least one refractory base mold material, a binder and an additive based on factice. The invention also relates to a component system, a method for producing molds and cores using the mold material mixtures or the component system respectively, and to molds and cores produced by said method.
    Type: Grant
    Filed: March 28, 2018
    Date of Patent: February 16, 2021
    Assignee: ASK Chemicals GmbH
    Inventors: Ingrid Ernst, Christian Priebe, Michael Richters
  • Patent number: 10773297
    Abstract: A moulding material mixture with at least one refractory material and water glass as an inorganic binding agent is used for producing casting moulds. The binding agent is cured with the aid of a carbonyl compound that has a molecular weight greater than 88 g/mol and less than 200 g/mol and a boiling point at 1013 hPa greater than 20° C. and less than 200° C. The at least one carbonyl compound is introduced into the gas phase, or carried with the gas phase. The at least one carbonyl compound has the formula R1R2C?O, where R1 is H or a C1 or C2 alkyl and R2 is a carboxyl group R—C(?O)—O— bonded via the oxygen atom, where R is a C1 to C3 hydrocarbon.
    Type: Grant
    Filed: December 19, 2014
    Date of Patent: September 15, 2020
    Assignee: ASK Chemicals GmbH
    Inventors: Heinz Deters, Hannes Lincke, Ronja Resch, Oliver Schmidt
  • Patent number: 10722938
    Abstract: The invention relates to a molding mixture for producing casting molds for metalworking, a process for producing casting molds, casting molds obtained by the process and also their use. To produce the casting molds, a refractory mold raw material and a binder based on water glass are used. A proportion of a particulate metal oxide selected from the group consisting of silicon dioxide, aluminum oxide, titanium oxide and zinc oxide is added to the binder, particular preference being given to using synthetic amorphous silicon dioxide. The molding mixture contains a phosphate as essential constituent. The use of phosphate can improve the mechanical strength of casting molds at high thermal load.
    Type: Grant
    Filed: August 31, 2017
    Date of Patent: July 28, 2020
    Assignee: ASK CHEMICALS GMBH
    Inventors: Jens Muller, Diether Koch, Marcus Frohn, Jorg Korschgen
  • Patent number: 10294161
    Abstract: The invention relates to mold material mixtures containing an oxide of aluminum and an oxide of zirconium as particulate mixed metal oxide, in combination with refractory mold base materials and a water glass-based binder system. The mold material mixtures, also in the form of multicomponent systems, are used for the production of molds and cores for the foundry industry.
    Type: Grant
    Filed: December 20, 2013
    Date of Patent: May 21, 2019
    Assignee: ASK Chemicals GmbH
    Inventors: Heinz Deters, Henning Zupan, Martin Oberleiter
  • Patent number: 10259035
    Abstract: The invention relates to mold material mixtures containing at least one aluminum oxide in the alpha phase and/or at least one aluminum/silicon mixed oxide, except for aluminum/silicon mixed oxides having a layered silicate structure, as a particulate metal oxide, in combination with refractory mold base materials and a water glass-based binder system. The mold material mixtures are used for the production of molds and cores for the foundry industry.
    Type: Grant
    Filed: December 20, 2013
    Date of Patent: April 16, 2019
    Assignee: ASK Chemicals GmbH
    Inventors: Heinz Deters, Henning Zupan, Martin Oberleiter
  • Patent number: 10232430
    Abstract: The invention relates to a mold material mixture for producing casting molds for metal processing, a process for producing casting molds, casting molds which can be obtained by the process and their use. The production of the casting molds is carried out using a refractory base molding material and a binder based on water glass. A proportion of a particulate metal oxide selected from the group consisting of silicon dioxide, aluminium oxide, titanium oxide and zinc oxide is added to the binder, with particular preference being given to using synthetic amorphous silicon dioxide. The mold material mixture contains a surface-active material as further significant constituent. The addition of the surface-active material enables the flowability of the mold material mixture to be improved, which makes it possible to produce casting molds having a very complicated geometry.
    Type: Grant
    Filed: September 14, 2015
    Date of Patent: March 19, 2019
    Assignee: ASK Chemicals GmbH
    Inventors: Jens Müller, Diether Koch, Marcus Frohn, Jörg Körschgen
  • Patent number: 10144053
    Abstract: The invention relates to a method for the layer-wise building of bodies comprising a refractory mold base material and resoles, to three-dimensional bodies manufactured according to said method, and to the use thereof in metal casting. According to the method, the refractory mold base material is contacted with at least one ester to obtain an ester-impregnated mold material mixture.
    Type: Grant
    Filed: April 30, 2015
    Date of Patent: December 4, 2018
    Assignee: ASK Chemicals GmbH
    Inventors: Dennis Bartels, Antoni Gieniec
  • Patent number: 10092946
    Abstract: The invention relates to mold material mixtures on the basis of inorganic binders, for producing molds and cores for metal casting. Said mixtures consist of at least one refractory mold base material, an inorganic binder and amorphous silicon dioxide as an additive. The invention also relates to a method for producing molds and cores using said mold material mixtures.
    Type: Grant
    Filed: April 20, 2015
    Date of Patent: October 9, 2018
    Assignee: ASK CHEMICALS GMBH
    Inventors: Dennis Bartels, Heinz Deters, Antoni Gieniec, Diether Koch, Hannes Lincke, Martin Oberleiter, Oliver Schmidt, Carolin Wallenhorst
  • Patent number: 9968989
    Abstract: The invention relates to lithium-containing molding material mixtures comprising a refractory main molding material, an inorganic binder, and amorphous silicon dioxide as an additive in the production of molds and cores for metal casting. The invention further relates to a method for producing molds and cores using the molding material mixtures and to molds and cores produced according to the method.
    Type: Grant
    Filed: June 17, 2014
    Date of Patent: May 15, 2018
    Assignee: ASK CHEMICALS GMBH
    Inventors: Heinz Deters, Hannes Lincke, Ronja Resch
  • Patent number: 9931690
    Abstract: The invention relates to molding material mixtures containing barium sulfate in combination with refractory basic molding materials and a waterglass-based binder system for producing casting molds and cores for the foundry industry in order to obtain cast pieces, in particular aluminum ones, which have an improved cast surface.
    Type: Grant
    Filed: June 6, 2013
    Date of Patent: April 3, 2018
    Assignee: ASK CHEMICALS GMBH
    Inventors: Heinz Deters, Jörg Körschgen, Martin Oberleiter
  • Patent number: 9901975
    Abstract: The invention relates to molding material mixtures containing a molding base material, water glass, amorphous silicon dioxide and an oxidic boron compound, and the production of molds and cores, in particular for metal casting.
    Type: Grant
    Filed: October 21, 2014
    Date of Patent: February 27, 2018
    Assignee: ASK Chemicals GmbH
    Inventors: Heinz Deters, Martin Oberleiter, Henning Zupan
  • Patent number: 9889498
    Abstract: The invention relates to mold material mixtures for producing molds and cores for metal casting, consisting of at least one refractory material, a binder based on resols and amorphous silicon dioxide. The invention also relates to a multicomponent system and methods for producing molds and cores using the mold material mixtures as well as molds and cores for metal casting produced according to this method.
    Type: Grant
    Filed: April 30, 2015
    Date of Patent: February 13, 2018
    Assignee: ASK Chemicals GmbH
    Inventors: Jörg Körschgen, Christian Priebe, Pierre-Henri Vacelet
  • Patent number: 9737927
    Abstract: The invention relates to a method for regenerating used foundry sand, which is contaminated with soluble glass, wherein: used foundry sand is provided, which is tainted with a binding agent made of the soluble glass, to which a particle-shaped metal oxide is added; and the used foundry sand is subjected to a thermal treatment, wherein the foundry sand is heated to a temperature of at least 200° C., thereby obtaining regenerated foundry sand. The invention further relates to regenerated foundry sand, as that obtained from using the method.
    Type: Grant
    Filed: February 19, 2008
    Date of Patent: August 22, 2017
    Assignee: ASK Chemicals GmbH
    Inventors: Diether Koch, Jens Müller, Marcus Frohn
  • Patent number: 9493602
    Abstract: The present invention relates to a polyurethane-based binder using isocyanates containing uretonimine and/or carbodiimide groups for producing cores and casting molds, to a mold material mixture containing the binder, and to a method using the binder for producing casting molds.
    Type: Grant
    Filed: November 17, 2011
    Date of Patent: November 15, 2016
    Assignee: ASK CHEMICALS GMBH
    Inventors: Carsten Cornelissen, Diether Koch, Christian Priebe