Abstract: The invention relates to a molding riser for casting metals, wherein the riser has a metal riser body. The invention also relates to the use of the riser for casting metals into separable casting molds, in particular horizontally separable casting molds.
Type:
Grant
Filed:
October 12, 2022
Date of Patent:
June 24, 2025
Assignee:
ASK Chemicals GmbH
Inventors:
Stefan Fischer, Marcus Friederici, Imanol Ortiz, Udo Skerdi, Ulrich Voigt
Abstract: Benzyl ether-type phenolic resins are useful in either a phenolic resin polyurethane cold-box (PUCB) process or a phenolic resin polyurethane no-bake (PUNB) process. The benzyl ether-type phenolic resins contain at least one formaldehyde scavenger in the form of a beta-dicarbonyl compound, and an alpha-carbonyl-carboxyl compound, particularly glyoxylic acid, binders based on these phenolic resins, and isocyanate compounds having at least two isocyanate groups. The resins having the inventive concept exhibit low free formaldehyde content. The inventive concept extends to molding material blends containing the binder, and a method for producing cores, molds or risers.
Abstract: Molding material mixes that contain a polyurethane binder based on phenolic resins of the benzyl ether type and polyisocyanates are characterized by the inclusion of a polybutadiene derivative. In one case, the polybutadiene derivative has epoxide groups and hydroxyl groups. In another case, the polybutadiene derivative has succinic acid anhydride groups. Molds, cores and risers are produced using these molding material mixes. Inclusion of the polybutadiene derivatives results in a reduction of sand adhesions in the molding process.
Abstract: The subject matter of the invention are sizing compositions containing an aqueous carrier liquid, refractory base materials and CH-acidic compounds, as well as their use for casting molds, as well as casting molds coated with the sizing composition.
Type:
Grant
Filed:
July 19, 2019
Date of Patent:
January 2, 2024
Assignee:
ASK Chemicals GmbH
Inventors:
Christian Priebe, Markus Bung, Sarah Voss, Jörg Körschgen
Abstract: The invention relates to a binder, which contains water glass and further a phosphate or a borate or both. The invention further relates to a method for constructing molds and cores layer by layer, the molds and cores comprising a construction material mixture, which at least comprises a refractory molding base material, and the binder. In order to produce the molds and cores layer by layer in 3-D printing, the refractory molding base material is applied layer by layer and is selectively printed with the binder layer by layer, and consequently a body corresponding to the molds or cores is constructed and the molds or cores are released after the unbonded construction material mixture has been removed.
Abstract: The invention relates to a binder based on phenolic resins of the benzyl ether type and isocyanate compounds having at least two isocyanate groups, containing free phenol and free hydroxybenzyl alcohols in the polyol component. The invention further relates to mold material mixtures containing the binder and to cores, molds, or risers produced with the mold material mixtures and to the use thereof in metal casting.
Type:
Grant
Filed:
December 22, 2017
Date of Patent:
October 11, 2022
Assignee:
ASK Chemicals GmbH
Inventors:
Christian Priebe, Philipp Schneider, Mark Stancliff, Brian Weaver
Abstract: The subject matter of the invention is mold material mixtures for producing molds or cores for metal casting, consisting of at least one refractory base mold material, a binder and an additive based on factice. The invention also relates to a component system, a method for producing molds and cores using the mold material mixtures or the component system respectively, and to molds and cores produced by said method.
Type:
Grant
Filed:
March 28, 2018
Date of Patent:
February 16, 2021
Assignee:
ASK Chemicals GmbH
Inventors:
Ingrid Ernst, Christian Priebe, Michael Richters
Abstract: A moulding material mixture with at least one refractory material and water glass as an inorganic binding agent is used for producing casting moulds. The binding agent is cured with the aid of a carbonyl compound that has a molecular weight greater than 88 g/mol and less than 200 g/mol and a boiling point at 1013 hPa greater than 20° C. and less than 200° C. The at least one carbonyl compound is introduced into the gas phase, or carried with the gas phase. The at least one carbonyl compound has the formula R1R2C?O, where R1 is H or a C1 or C2 alkyl and R2 is a carboxyl group R—C(?O)—O— bonded via the oxygen atom, where R is a C1 to C3 hydrocarbon.
Type:
Grant
Filed:
December 19, 2014
Date of Patent:
September 15, 2020
Assignee:
ASK Chemicals GmbH
Inventors:
Heinz Deters, Hannes Lincke, Ronja Resch, Oliver Schmidt
Abstract: The invention relates to mold material mixtures containing an oxide of aluminum and an oxide of zirconium as particulate mixed metal oxide, in combination with refractory mold base materials and a water glass-based binder system. The mold material mixtures, also in the form of multicomponent systems, are used for the production of molds and cores for the foundry industry.
Type:
Grant
Filed:
December 20, 2013
Date of Patent:
May 21, 2019
Assignee:
ASK Chemicals GmbH
Inventors:
Heinz Deters, Henning Zupan, Martin Oberleiter
Abstract: The invention relates to mold material mixtures containing at least one aluminum oxide in the alpha phase and/or at least one aluminum/silicon mixed oxide, except for aluminum/silicon mixed oxides having a layered silicate structure, as a particulate metal oxide, in combination with refractory mold base materials and a water glass-based binder system. The mold material mixtures are used for the production of molds and cores for the foundry industry.
Type:
Grant
Filed:
December 20, 2013
Date of Patent:
April 16, 2019
Assignee:
ASK Chemicals GmbH
Inventors:
Heinz Deters, Henning Zupan, Martin Oberleiter
Abstract: The invention relates to a mold material mixture for producing casting molds for metal processing, a process for producing casting molds, casting molds which can be obtained by the process and their use. The production of the casting molds is carried out using a refractory base molding material and a binder based on water glass. A proportion of a particulate metal oxide selected from the group consisting of silicon dioxide, aluminium oxide, titanium oxide and zinc oxide is added to the binder, with particular preference being given to using synthetic amorphous silicon dioxide. The mold material mixture contains a surface-active material as further significant constituent. The addition of the surface-active material enables the flowability of the mold material mixture to be improved, which makes it possible to produce casting molds having a very complicated geometry.
Type:
Grant
Filed:
September 14, 2015
Date of Patent:
March 19, 2019
Assignee:
ASK Chemicals GmbH
Inventors:
Jens Müller, Diether Koch, Marcus Frohn, Jörg Körschgen
Abstract: The invention relates to a method for the layer-wise building of bodies comprising a refractory mold base material and resoles, to three-dimensional bodies manufactured according to said method, and to the use thereof in metal casting. According to the method, the refractory mold base material is contacted with at least one ester to obtain an ester-impregnated mold material mixture.
Abstract: The invention relates to molding material mixtures containing a molding base material, water glass, amorphous silicon dioxide and an oxidic boron compound, and the production of molds and cores, in particular for metal casting.
Type:
Grant
Filed:
October 21, 2014
Date of Patent:
February 27, 2018
Assignee:
ASK Chemicals GmbH
Inventors:
Heinz Deters, Martin Oberleiter, Henning Zupan
Abstract: The invention relates to mold material mixtures for producing molds and cores for metal casting, consisting of at least one refractory material, a binder based on resols and amorphous silicon dioxide. The invention also relates to a multicomponent system and methods for producing molds and cores using the mold material mixtures as well as molds and cores for metal casting produced according to this method.
Type:
Grant
Filed:
April 30, 2015
Date of Patent:
February 13, 2018
Assignee:
ASK Chemicals GmbH
Inventors:
Jörg Körschgen, Christian Priebe, Pierre-Henri Vacelet
Abstract: The invention relates to a method for regenerating used foundry sand, which is contaminated with soluble glass, wherein: used foundry sand is provided, which is tainted with a binding agent made of the soluble glass, to which a particle-shaped metal oxide is added; and the used foundry sand is subjected to a thermal treatment, wherein the foundry sand is heated to a temperature of at least 200° C., thereby obtaining regenerated foundry sand. The invention further relates to regenerated foundry sand, as that obtained from using the method.
Type:
Grant
Filed:
February 19, 2008
Date of Patent:
August 22, 2017
Assignee:
ASK Chemicals GmbH
Inventors:
Diether Koch, Jens Müller, Marcus Frohn
Abstract: The invention relates to a method for producing casting moulds and cores, according to which a moulding material mixture consisting of at least one refractory material and water glass as an inorganic binding agent is cured with the aid of a carbonyl compound introduced into the gas phase, or carried with the gas phase. The invention also relates to a corresponding moulding material mixture, to a multi-component system and to moulds and cores produced according to the method.
Type:
Application
Filed:
December 19, 2014
Publication date:
October 27, 2016
Applicant:
ASK Chemicals GmbH
Inventors:
Heinz DETERS, Hannes LINCKE, Ronja RESCH, Oliver SCHMIDT
Abstract: The invention relates to a size composition (coating composition) for casting moulds and cores, comprising at least one metal additive which contains a metal or a compound of a metal, wherein the metal is selected from one of groups 7 or 9 to 12 of the Periodic Table of the Elements. The invention also relates to a process for producing a casting mould, which comprises a mould coating of the size (coating) according to the invention, and to the use of said mould for the casting of metals.
Type:
Application
Filed:
December 23, 2015
Publication date:
May 12, 2016
Applicant:
ASK Chemicals GmbH
Inventors:
Reinhard Stötzel, Matthias Schrod, Michael Kloskowski
Abstract: The invention relates to a mould material mixture for producing casting moulds for metal processing, a process for producing casting moulds, casting moulds which can be obtained by the process and their use. The production of the casting moulds is carried out using a refractory base moulding material and a binder based on water glass. A proportion of a particulate metal oxide selected from the group consisting of silicon dioxide, aluminium oxide, titanium oxide and zinc oxide is added to the binder, with particular preference being given to using synthetic amorphous silicon dioxide. The mould material mixture contains a surface-active material as further significant constituent. The addition of the surface-active material enables the flowability of the mould material mixture to be improved, which makes it possible to produce casting moulds having a very complicated geometry.
Type:
Application
Filed:
September 14, 2015
Publication date:
March 3, 2016
Applicant:
ASK Chemicals GmbH
Inventors:
Jens Müller, Diether Koch, Marcus Frohn, Jörg Korschgen
Abstract: The present invention relates to a coating and a method for producing a casting mold. The method provides for castings whereby gas defects are largely or completely suppressed.
Type:
Application
Filed:
April 21, 2014
Publication date:
October 22, 2015
Applicant:
ASK Chemicals GmbH
Inventors:
Reinhard Stötzel, Klemens Eising, Karl Smarzoch
Abstract: A binder for mold material mixtures is a four-component material. It contains at least one phenolic resin component, at least one isocyanate component, at least one alkyl/alkenyl benzene and at least one dialkylated and/or dialkenylated naphthalene. The phenolic resin component acts as the polyol component and contains phenolic resin obtainable from the reaction between a phenol compound and an aldehyde compound. The isocyanate component contains at least one polyisocyanate with at least two NCO groups per molecule. The alkyl/alkenyl benzene has a boiling point above 250° C. The dialkylated and/or dialkenylated naphthalene has a boiling point above 270° C.