Abstract: Nanoporous carbon-based scaffolds or structures, and specifically carbon aerogels and their manufacture and use thereof. Embodiments include a sulfur-doped cathode material within a lithium-sulfur battery, where the cathode is collector-less and is formed of a binder-free, monolithic, polyimide-derived carbon aerogel. The carbon aerogel includes pores that surround elemental sulfur and accommodate expansion of the sulfur during conversion to lithium sulfide. The cathode and underlying carbon aerogel provide optimal properties for use within the lithium-sulfur battery.

Abstract: The present invention relates to a thermal insulation board (IB) comprising at least two insulating layers (A) bonded together. At least one of the at least two insulating layers (A) comprises at least one aerogel composite material, wherein the aerogel composite material comprises at least one silica aerogel (a1), at least one polymer foam (a2) and at least one flame retardant (a3). The present invention also relates to a thermal insulation system (IS) comprising the thermal insulation board (IB). Further, it relates to a process for the production of the thermal insulation board (IB) and to the use of the thermal insulation board (IB) and of the thermal insulation system (IS) for the thermal insulation of buildings, parts and/or elements of buildings.

Abstract: The present disclosure relates to materials and systems to manage thermal runaway issues in battery modules. In exemplary embodiments, a battery module includes battery cells separated by spacer elements. To mitigate thermal runaway issues, spacer elements may be extended to the interior surface of the enclosure. A seal is formed between the spacer elements and the interior wall to form a thermal barrier between adjacent battery cells.

Abstract: The present disclosure relates to methods and systems to manage thermal runaway issues in energy storage systems. Exemplary embodiments include methods and systems having a compressible thermal barrier. The compressible thermal barrier is tailored in size (e.g., thickness, volume, etc.) to prevent thermal propagation between adjacent cells, modules and/or packs when a portion of an energy source has experienced a thermal event. The methods and systems mitigate thermal propagation such that a cell adjacent to a compromised cell (e.g., actively combusting cell) does not experience thermal runaway as it is shielded from dissipating heat and does not surpass a critical temperature. The present disclosure further relates to a battery module or pack with one or more battery cells and the compressible thermal barrier placed between adjacent cells.

Abstract: The present disclosure is directed to methods of forming polyamic acid, polyamic acid metal salt, and polyimide gels under aqueous conditions, the methods utilizing water-soluble carbonate or bicarbonate salts. These gels may be converted to aerogels or xerogels, which may further be converted to carbon aerogels or xerogels. Such carbon aerogels or xerogels have the same physical properties as carbon aerogels or xerogels prepared from polyimide aerogels obtained according to conventional methods, i.e., organic solvent-based methods.

Abstract: The present disclosure is directed to lithium-ion battery anodes and components thereof. Further provided are processes for the preparation of lithium-ion battery anodes. Such processes generally include preparation of a slurry including an anode material, a binder material, a conductive material, and a solvent. The anode material includes a carbon-silicon composite, and optionally, graphite.

Abstract: Provided herein are composite materials for use in electrical energy storage systems (e.g., high-capacity batteries) and methods for preparing the same. The composite materials of the present disclosure include a plurality of covalently functionalized silicon particles and a polymer network. Individual silicon particles within the plurality of silicon particles are dispersed throughout the polymer network. Covalently attached functional groups to a surface of the plurality of the silicon particles enable dispersion of the silicon particles throughout the polymer network.

Abstract: Provided herein are composite materials for use in an electrical energy storage system (e.g., a high-capacity battery) and methods for preparing the same. The composite materials provided herein are also useful as substrates for chemical vapor deposition of silicon. The composite materials of the present disclosure include a three-dimensional carbon network and optional silicon particles. The composite materials further include mega pores, at least some of which are formed by carbonizing sacrificial particles dispersed throughout a three-dimensional network. The mega pores advantageously provide a space to accommodate the strain and stress in the electrode structure due to volume changes of silicon (particles) during charge and discharge of the electrical energy storage system.

Abstract: Provided herein are composite materials for use in an electrical energy storage system (e.g. high capacity batteries) and methods for preparing the same. The composite materials of the present disclosure include silicon particles and a three-dimensional carbon network. The composite materials further include void space between an exterior surface of each silicon particles and the three-dimensional carbon network. The void space advantageously provides a space to accommodate volume changes of silicon particles during charging and discharging of the electrical energy storage systems.

Abstract: Nanoporous carbon-based scaffolds or structures, and specifically carbon aerogels and their manufacture and use thereof are provided. Embodiments include a silicon-doped anode material for a lithium-ion battery, where the anode material includes beads of a polyimide-derived carbon aerogel. The carbon aerogel may further include silicon particles and accommodates expansion of the silicon particles during lithiation. The anode material provides optimal properties for use within the lithium-ion battery.

Abstract: This disclosure relates generally to aerogel technology. The disclosure relates more particularly, in various embodiments, to improved methods for producing aerogels and improved aerogel composites having a low compression set.

Abstract: Aerogel materials, aerogel composites, and the like may be improved by the addition of opacifiers to reduce the radiative component of heat transfer. Such aerogel materials, aerogel composites, and the like may also be treated to impart or improve hydrophobicity. Such aerogel materials and methods of manufacturing the same are described.

Abstract: The present invention discloses novel porous polymeric compositions comprising random copolymers of amides, imides, ureas, and carbamic-anhydrides, useful for the synthesis of monolithic bimodal microporous/macroporous carbon aerogels. It also discloses methods for producing said microporous/macroporous carbon aerogels by the reaction of a polyisocyanate compound and a polycarboxylic acid compound, followed by pyrolytic carbonization, and by reactive etching with CO2 at elevated temperatures. Also disclosed are methods for using the microporous/macroporous carbon aerogels in the selective capture and sequestration of carbon dioxide.

Abstract: The present disclosure is directed to methods of forming polyamic acid and polyimide gels in water. The resulting polyamic acid and polyimide gels may be converted to aerogels, which may further be converted to carbon aerogels. Such carbon aerogels have the same physical properties as carbon aerogels prepared from polyimide aerogels obtained according to conventional methods, i.e., organic solvent-based. The disclosed methods are advantageous in reducing or avoiding costs associated with use and disposal of potentially toxic solvents and byproducts. Gel materials prepared according to the disclosed methods are suitable for use in environments involving electrochemical reactions, for example as an electrode material within a lithium-ion battery.

Abstract: Heating and processing a polymeric material is achieved using a microwave absorbing structure that defines a processing chamber to receive the polymeric material (e.g., one or more precursors to form a polymer). A microwave radiation source directs microwave radiation to the microwave absorbing structure, which absorbs the radiation and can process the material.

Abstract: The present disclosure can provide an aerogel composite. The aerogel composite comprises at least one base layer having a top surface and a bottom surface, the base layer comprising a reinforced aerogel composition which comprises a reinforcement material and a monolithic aerogel framework, a first facing layer comprising a first facing material attached to the top surface of the base layer, and a second facing layer comprising a second facing material attached to the bottom surface of the base layer. At least a portion of the monolithic aerogel framework of the base layer extends into at least a portion of both the first facing layer and the second facing layer. The first facing material and the second facing material can each comprise or consist essentially of a non-fluoropolymeric material.

Abstract: The present invention provides a fiber-reinforced aerogel material which can be used as insulation. The fiber-reinforced aerogel material is highly durable, flexible, and has a thermal performance that exceeds the insulation materials currently used. The fiber-reinforced aerogel insulation material can be as thin as 1 mm or less, and can have a thickness variation as low as 2% or less. Also provided is a method for improving the performance of a battery by incorporating a reinforced aerogel material into the battery. Further provided is a casting method for producing thin fiber-reinforced aerogel materials.

Abstract: The present disclosure is directed to methods of forming polyamic acid and polyimide gels in water. The resulting polyamic acid and polyimide gels may be converted to aerogels, which may further be converted to carbon aerogels. Such carbon aerogels have the same physical properties as carbon aerogels prepared from polyimide aerogels obtained according to conventional methods, i.e., organic solvent-based. The disclosed methods are advantageous in reducing or avoiding costs associated with use and disposal of potentially toxic solvents and byproducts. Gel materials prepared according to the disclosed methods are suitable for use in environments involving electrochemical reactions, for example as an electrode material within a lithium-ion battery.

Abstract: Embodiments of the present invention describe secured fiber-reinforced aerogels and laminate structures formed therefrom. In one embodiment a laminate comprises at least one fiber-reinforced aerogel layer adjacent to at least one layer of fiber containing material wherein fibers from said at least one fiber-reinforced aerogel layer are interlaced with fibers of said at least one fiber-containing material. In another embodiment a laminate comprises at least two adjacent fiber-reinforced aerogel layers wherein fibers from at least one fiber-reinforced aerogel layer are interlaced with fibers of an adjacent fiber-reinforced aerogel layer.

Abstract: Silicon nanoparticles and methods for preparation of silicon nanoparticles are provided. Embodiments include a method for grinding silicon. Methods include providing silicon material, providing a grinding liquid including a polar solvent, and grinding the silicon material in the presence of the grinding liquid to yield silicon nanoparticles. Grinding the silicon in the presence of the grinding liquid can chemically functionalize the silicon material as the nanoparticles are formed to provide stable chemically functionalized nanoparticles.