Abstract: A cation-exchange membrane using a polyolefin-based substrate with reduced swelling of an ion-exchange resin and a low electrical resistance is provided. The cation-exchange membrane of the present invention includes a substrate made of polyolefin-based woven fabric, and a sulfonic acid group-containing cation-exchange resin. A portion of the cation-exchange membrane other than the substrate has 23 mass % or more to 35 mass % or less of polyvinyl chloride.

Abstract: An anion-exchange membrane of the present invention includes a substrate made of polyolefin-based woven fabric and an anion-exchange resin, and has an electrical resistance measured using 0.5 M NaCl solution at 25° C. of 1.0 ?•cm2 or more to 2.5 ?•cm2 or less, a bursting strength of 0.7 MPa or more to 1.2 MPa or less, a water permeation rate measured using pressured water at 0.1 MPa of 300 ml/(m2•hr) or less, a thickness of the substrate of 90 µm or more to 160 µm or less, and an open area ratio of the substrate of 35% or more to 55% or less.

Abstract: A bipolar membrane in which a cation-exchange membrane and an anion-exchange membrane are joined to each other, wherein a leakage ratio of gluconic acid at 60° C. is not more than 1.0%, and the cation-exchange membrane is supported by a polyolefin reinforcing member and, further, contains a polyvinyl chloride.

Abstract: A polymerizable composition for forming an ion-exchange resin precursor, the polymerizable composition containing a monomer component and polyethylene particles in an amount of 50 to 120 parts by mass per 100 parts by mass of the monomer component, wherein the monomer component contains an aromatic monomer for introducing ion-exchange groups and a nitrogen-containing aliphatic monomer, the nitrogen-containing aliphatic monomer being present in an amount of 10 to 35% by mass in said monomer component. An ion-exchange membrane is produced by applying the polymerizable composition onto a polyolefin type filament base material and polymerizing the polymerizable composition to form an ion-exchange resin precursor and, thereafter, introducing ion-exchange groups into the precursor.

Abstract: A polymerizable composition for forming an ion-exchange resin precursor, the polymerizable composition containing a monomer component and polyethylene particles in an amount of 50 to 120 parts by mass per 100 parts by mass of the monomer component, wherein the monomer component contains an aromatic monomer for introducing ion-exchange groups and a nitrogen-containing aliphatic monomer, the nitrogen-containing aliphatic monomer being present in an amount of 10 to 35% by mass in said monomer component. An ion-exchange membrane is produced by applying the polymerizable composition onto a polyolefin type filament base material and polymerizing the polymerizable composition to form an ion-exchange resin precursor and, thereafter, introducing ion-exchange groups into the precursor.

Abstract: A polymerizable composition for forming an ion-exchange resin precursor, the polymerizable composition containing a monomer component and polyethylene particles in an amount of 50 to 120 parts by mass per 100 parts by mass of the monomer component, wherein the monomer component contains an aromatic monomer for introducing ion-exchange groups and a nitrogen-containing aliphatic monomer, the nitrogen-containing aliphatic monomer being present in an amount of 10 to 35% by mass in said monomer component. An ion-exchange membrane is produced by applying the polymerizable composition onto a polyolefin type filament base material and polymerizing the polymerizable composition to form an ion-exchange resin precursor and, thereafter, introducing ion-exchange groups into the precursor.

Abstract: A bipolar membrane BP characterized in that particles 5 of a basic metal chloride are distributed in the interface between a cation-exchange membrane 1 and an anion-exchange membrane 3.

Abstract: An ion exchange membrane having a structure that an ion exchange resin is filled in spaces of a porous base film, the porous base film has a structure that at least two porous olefin resin layers are laminated with a bonding strength of 100 gf/cm or more to less than 700 gf/cm and a Gurley air permeance of 500 sec/100 ml or less in terms of a 100 ?m thick film. In this ion exchange membrane, base film has high air permeability though it has a multi-layer structure that a plurality of porous resin films are bonded together, and therefore a rise in electric resistance caused by the lamination of the base sheets is effectively suppressed.

Abstract: A polymerizable composition for forming an ion-exchange resin precursor, the polymerizable composition containing a monomer component and polyethylene particles in an amount of 50 to 120 parts by mass per 100 parts by mass of the monomer component, wherein the monomer component contains an aromatic monomer for introducing ion-exchange groups and a nitrogen-containing aliphatic monomer, the nitrogen-containing aliphatic monomer being present in an amount of 10 to 35% by mass in said monomer component. An ion-exchange membrane is produced by applying the polymerizable composition onto a polyolefin type filament base material and polymerizing the polymerizable composition to form an ion-exchange resin precursor and, thereafter, introducing ion-exchange groups into the precursor.

Abstract: A bipolar membrane in which a cation-exchange membrane and an anion-exchange membrane are joined to each other, wherein a leakage ratio of gluconic acid at 60° C. is not more than 1.0%, and the cation-exchange membrane is supported by a polyolefin reinforcing member and, further, contains a polyvinyl chloride.

Abstract: An ion exchange membrane having a structure that an ion exchange resin is filled in spaces of a porous base film, the porous base film has a structure that at least two porous olefin resin layers are laminated with a bonding strength of 100 gf/cm or more to less than 700 gf/cm and a Gurley air permeance of 500 sec/100 ml or less in terms of a 100 ?m thick film. In this ion exchange membrane, base film has high air permeability though it has a multi-layer structure that a plurality of porous resin films are bonded together, and therefore a rise in electric resistance caused by the lamination of the base sheets is effectively suppressed.

Abstract: An ion-exchange membrane including a porous unstretched polyethylene sheet in which fine pores are piercing, the pores being filled with an ion-exchange resin. The ion-exchange membrane exhibits excellent concentration property.

Abstract: To provide a bipolar membrane featuring improved adhesion between an anion-exchange membrane and a cation-exchange membrane without accompanied by an increase in the membrane voltage. [Means for Solution] A bipolar membrane comprising a cation-exchange membrane and an anion-exchange membrane joined together facing each other, wherein at least one of the ion exchange membranes contains a chlorinated polyolefin.

Abstract: An ion-exchange membrane including a porous unstretched polyethylene sheet in which fine pores are piercing, the pores being filled with an ion-exchange resin. The ion-exchange membrane exhibits excellent concentration property.

Abstract: [Problems] To provide an ion exchanger having excellent electric properties, a low electric resistance, excellent mechanical strength and, at the same time, having excellent contamination resistance. [Means for Solution] An ion exchanger comprises a melt-extrusion-formed body of a resin composition containing a granular ion-exchange resin and a low-melting polyolefin resin having a melting point of not higher than 170° C., the melt-extrusion-formed body: (a) containing the granular ion-exchange resin at a ratio of not less than 30% by weight but less than 50% by weight, and the low-melting polyolefin resin in an amount of more than 100 parts by weight but not more than 150 parts by weight per 100 parts by weight of the granular ion-exchange resin; (b) having a melt index in a range of 1 to 5 g/10 min. as measured at 190° C.; and (c) having a water content of not less than 30%.

Abstract: [Problems] To provide an ion-exchange membrane using an inexpensive nonwoven fabric sheet as a base sheet, featuring excellent properties such as strength, dimensional stability and shape stability, effectively suppressing undulation when it is brought into contact with the electrolyte, and having a low membrane resistance and stable properties. [Means for Solution] An ion-exchange membrane comprising a nonwoven fabric sheet 1 and an ion-exchange resin coating 3 formed on one surface of the nonwoven fabric sheet 1, the nonwoven fabric sheet 1 having a fiber layer structure that includes long filament layers 5 of a fiber diameter of 8 to 30 ?m on both surfaces thereof and an extra-fine filament layer 7 of a fiber diameter of not more than 5 ?m as an intermediate layer formed by melt-adhesion of fibers between the long filament layers 5.