Patents Assigned to ATOFINA Research
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Publication number: 20120053304Abstract: A method for the copolymerization of ethylene and a C3+ olefin copolymer in a loop reactor system and polymers formed therefrom are described herein.Type: ApplicationFiled: August 24, 2010Publication date: March 1, 2012Applicant: ATOFINA Research S.A.Inventors: Louis Fouarge, Eric Damme, Olivier Miserque, Daniel Siraux, Philippe Bodart, André Lewalle, Marc Van der Auwera, Frans Van den Brande, Giacomo Conti, Hugo Vandaele, Mark Verleysen, Carl Van Camp, Etienne Laurent, Philippe Marechal, Marc Moers, Leopold D'Hooghe, Marjan Sillis, Kai Hortman, Pascal Folie, Renaud Oreins
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Publication number: 20090143546Abstract: A method for controlling the injection of catalyst slurry in a polymerization reactor is described herein. The method includes the preparation of polyethylene with a solid catalyst and a hydrocarbon diluents. The method includes providing solid catalyst and a hydrocarbon diluent in one or more storage vessels such that a catalyst slurry is obtained in said vessel, transferring said catalyst slurry from said storage vessel to a mixing vessel wherein said catalyst slurry is diluted for obtaining a suitable concentration for use in a polymerization reaction, pumping said diluted catalyst slurry at a controlled flow rate from said mixing vessel to said polymerization reactor through one or more conduits, by means of a membrane pump provided in each of said conduits, and the membrane pump is controllable as a function of reactant concentration within the polymerization reactor.Type: ApplicationFiled: October 1, 2008Publication date: June 4, 2009Applicant: ATOFINA RESEARCH S.A.Inventors: Louis Fouarge, Eric Damme, Olivier Miserque, Daniel Siraux, Philippe Bodart, Andre Lewalle, Marc Van der Auwera, Frans Van den Brande, Giacomo Conti, Hugo Vandaele, Mark Verleysen, Carl Van Camp, Etienne Laurent, Philippe Marechal, Marc Moers, Leopold D'Hooghe, Marjan Sillis, Kai Hortman, Pascal Folie, Renaud Oreins
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Publication number: 20070178303Abstract: The present invention provides monofilaments or stretched tapes, unwoven or woven into raffia, prepared with metallocene-produced polyethylene having long chain branches.Type: ApplicationFiled: April 7, 2004Publication date: August 2, 2007Applicant: ATOFINA RESEARCHInventors: Eric Maziers, Vincent Stephenne
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Patent number: 6992136Abstract: The invention relates to a novel transparent block copolymer and its process for the manufacture. The process comprises a first partial killing of at least the living copolymeric species R-S1-B1-M with a multi-functional deactivation agent where S1 is a monovinyl-substituted aromatic homopolymer, B1, is a conjugated diene homopolymer, M is an alkali metal and R is an alkyl (RM being an initiator) and further comprises a second total deactivation of at least the living tapered block copolymeric species R-S1-B1-B2/S2-M (obtained by adding a feed B2/S2 to the reaction medium) by a mono-functional deactivation agent (the terminating agent).Type: GrantFiled: October 9, 2003Date of Patent: January 31, 2006Assignee: Atofina ResearchInventors: Thierry Coupin, Jean Philippe Hallet
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Publication number: 20050272891Abstract: The present invention relates to an apparatus and process for polymerizing olefins. One embodiment comprises polymerizing at least one monomer in a first loop reactor in the presence of a catalyst to produce a first polyolefin fraction. A portion of the first polyolefin fraction is transferred to a second loop reactor, connected in series with the first loop reactor. The process further comprises polymerizing in the second loop reactor at least one monomer in the presence of a catalyst to produce a second polyolefin fraction in addition to the first polyolefin fraction. The combination of the first and second polyolefin fractions can produce a polymer resin fluff having bimodal molecular weight distribution.Type: ApplicationFiled: February 14, 2005Publication date: December 8, 2005Applicant: ATOFINA Research S.A.Inventors: Louis Fouarge, Eric Damme, Olivier Miserque, Daniel Siraux, Philippe Bodart, Andre Lewalle, Marc Auwera, Frans Brande, Giacomo Conti, Hugo Vandaele, Mark Verleysen, Carl Camp, Etienne Laurent, Philippe Marechal, Marc Moers, Leopold D'Hooghe, Marjan Sillis, Kai Hortman, Pascal Folie, Renaud Oreins
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Patent number: 6946521Abstract: A polyethylene resin comprising from 35 to 49 wt. % of a first polyethylene fraction of high molecular weight and from 51 to 65 wt. % of a second polyethylene fraction of low molecular weight, the first polyethylene having a density of up to 0.930 g/cm3, and an HLMI of less than 0.6 g/10 min and the second polyethylene fraction comprising a high density polyethylene having a density of at least 0.969 g/cm3 and an MI2 of greater than 10 g/10 min, and the polyethylene resin, having a density of great 0.946 g/cm3, an HLMI of from 1 to 100 g/10 min, a dynamical viscosity, measured at 0.01 radians/second, greater than 200,000 Pa.s and a ratio of the dynamical viscosities measured at, respectively 0.01 and 1 radians/second greater than 8.Type: GrantFiled: October 25, 2001Date of Patent: September 20, 2005Assignees: ATOFINA Research S.A., Solvay Polyolefins Europe-Belgium S.A.Inventors: Olivier Miserque, Jacques Michel, Marc Dupire, Fabian Siberdt, Jean-Louis Costa, Serge Bettonville, Virgil Rouyer, Eric Damme
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Patent number: 6894132Abstract: Provided is a catalyst for the polymerization of olefins of general formula: R?(C4R?mC5C4R?n)XMeQ wherein X is an hetero-atom ligand with one or two lone pair electrons selected from the elements of Group VA or VIA which can be substituted or non-substituted: (C4Rm?C5C4Rn?) is a symmetrically substituted, 3,6-substituted fluorenyl; R? is hydrogen or hydrocarbyl radical having from 1-20 carbon atoms, a halogen, an alkoxy, an alkoxy alkyl or an alkylamino or alkylsilylo radical, each R? may be the same or different and m and n independently are 1, 2 3 or 4, with the proviso that the bilateral symmetry is maintained; R? is a structural bridge between X and the (C4R?mC5C4R?n) ring to impart stereorigidity; Q is a hydrocarbyl radical having 1-20 carbon atoms or is a halogen; Me is a Group IIIB, IVB, VB, or VIB metal as positioned in the Periodic Table of Elements; and Me can be in any of its theoretically possible oxidation states.Type: GrantFiled: June 26, 2003Date of Patent: May 17, 2005Assignee: Atofina Research S.A.Inventor: Abbas Razavi
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Patent number: 6881493Abstract: Uses of syndiotactic/atactic block polypropylene are provided in which the molecular weight thereof is preferably at least 120kD. The syndiotactic/atactic block polypropylene may be used as a polypropylene modifier, a component in an adhesive composition, a shock absorber component, a waterproof membrane component, a packaging film or component thereof, a shapable composition component, and an acoustic absorbent material component, a composition for moulding into a footwear component, a bitumen modifier, a compatibiliser, an emulgator or an emulsifier, as a viscosity improver, and as a spilled oil absorber.Type: GrantFiled: October 9, 2001Date of Patent: April 19, 2005Assignee: ATOFINA Research S.A.Inventors: Bernard Haveaux, Thierry Coupin
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Patent number: 6872763Abstract: Provided is a vulcanizing agent for vulcanizing bitumen, which vulcanizing agent comprises a sulphur agent and a binder, wherein the vulcanizing agent is in the form of pellets. Further provided is a process for producing a surfacing composition, which process comprises contacting bitumen with an elastomer and the vulcanizing agent of the present invention.Type: GrantFiled: October 24, 2001Date of Patent: March 29, 2005Assignee: ATOFINA Research, S.A.Inventor: Patrizio Andriolo
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Patent number: 6863941Abstract: An automobile fuel tank comprising at least two components which have been joined together to form a tank having a wall defining a fuel chamber, at least one of the components being injection moulded and defining a part of the wall and composed of a polyethylene having a density of from 0.930 to 0.955 g/cm3, a dispersion index D of from 2 to 3 and a melt index MI2 of from 0.2 to 2 g/10 min.Type: GrantFiled: January 24, 2003Date of Patent: March 8, 2005Assignee: ATOFINA Research S.A.Inventor: Patrick Detounay
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Patent number: 6858133Abstract: A process for desulfurising an olefin-containing hydrocarbon feedstock including sulfur-containing hydrocarbon compounds as impurities, the process comprising passing a hydrocarbon feedstock containing one or more olefins through a reactor containing a crystalline silicate selected from the group consisting of an MFI-type crystalline silicate having a silicon/aluminum atomic ratio of at least 180 and an MEL-type crystalline silicate having a silicon/aluminum atomic ratio of from 150 to 800 which has been subjected to a steaming step to produce an effluent with an olefin content of lower molecular weight than that of the feedstock and removing hydrogen sulphide from the effluent.Type: GrantFiled: April 23, 2002Date of Patent: February 22, 2005Assignee: Atofina Research S.A.Inventors: Jean-Pierre Dath, Walter Vermeiren, Koen Herrebout
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Patent number: 6858170Abstract: The present invention relates to a process for preparing silica-alumina carriers preferably under the form of extrudates. Further, the present invention also provides hydrogenation catalysts prepared thereof. These catalysts are used in an improved process for the reduction of the aromatic hydrocarbons content present in hydrocarbon streams.Type: GrantFiled: May 29, 2002Date of Patent: February 22, 2005Assignee: ATOFINA ResearchInventors: Hugo Van Thillo, Philippe Bodart, Christian Lamotte, Jacques Grootjans
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Patent number: 6852764Abstract: Provided is a blend comprising: a) from 20 to 60 wt % of a thermoplastic elastomer; b) from 8 to 30 wt % of a vinylaromatic polymer; c) from 10 to 30 wt % of one or more processing aid; d) from 0 to 20 wt % of one or more additives.Type: GrantFiled: December 7, 2000Date of Patent: February 8, 2005Assignee: Atofina Research S.A.Inventor: Jean-Marie Mlinaric
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Publication number: 20040249094Abstract: Use of isotactic polypropylene homopolymers or copolymers in processes in which the polypropylene solidifies from a melt, wherein for enhanced speed of solidification of the polypropylene the polypropylene has a melt temperature and a crystallisation temperature not more than 50° less than the melt temperature resulting from the polypropylene having been produced using a metallocene catalyst component having the general formula as described herein:Type: ApplicationFiled: March 3, 2004Publication date: December 9, 2004Applicant: ATOFINA Research, S.A.Inventor: Axel Demain
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Patent number: 6824886Abstract: Use of a homogeneous blend of a metallocene-catalysed medium density polyethylene (mMDPE) with low density polyethylene (LDPE), to produce blown films, this composition essentially consisting of from 0.5 to 99.5 % by weight of mMDPE and from 99.5 to 0.5 % by weight of LDPE, based on the total weight of the blend. The blend is optionally coextruded between layers of LDPE. The compositions of this invention have good processability and are used to make blown films which have the good optical properties of LDPE and the good mechancial and processing properties of MDPE.Type: GrantFiled: September 23, 2002Date of Patent: November 30, 2004Assignee: ATOFINA Research S.A.Inventor: Marc Tavernier
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Patent number: 6817114Abstract: Use of compositions prepared with organic coupling agents carrying epoxy groups for preparing applications requiring simultaneously improved mechanical properties and low viscosity.Type: GrantFiled: September 30, 2002Date of Patent: November 16, 2004Assignee: Atofina Research S.A.Inventor: Pierre Bredael
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Patent number: 6774156Abstract: A process for producing a propylene copolymer having increased melt strength, the process comprising irradiating a copolymer of propylene and ethylene which has been polymerised using a Ziegler-Natta catalyst with an electron beam having an energy of at least 5 MeV and a radiation dose of at least 10 kGray and melting and mechanically processing the melt of the irradiated ethylene propylene copolymer to form long chain branches on the ethylene propylene copolymer molecules.Type: GrantFiled: September 2, 2003Date of Patent: August 10, 2004Assignee: ATOFINA Research S.A.Inventors: Guy Debras, Marc Dupire, Jacques Michel
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Patent number: 6730742Abstract: A polypropylene fiber including greater than 50% by weight of a first isotactic polypropylene produced by a Ziegler-Natta catalyst, from 5 to less than 50% by weight of a second isotactic polypropylene produced by a metallocene catalyst and up to 15% by weight of a syndiotactic polypropylene (sPP).Type: GrantFiled: October 30, 2002Date of Patent: May 4, 2004Assignee: Atofina Research S.A.Inventor: Axel Demain
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Patent number: 6727332Abstract: Use of isotactic polypropylene homopolymers or copolymers in processes in which the polypropylene solidifies from a melt, wherein for enhanced speed of solidification of the polypropylene the polypropylene has a melt temperature and a crystallisation temperature not more than 50° C. less than the melt temperature resulting from the polypropylene having been produced using a metallocene catalyst component having the general formula: R″(CpR1R2R3)(Cp′Rn′)MQ2. Cp and Cp′ are a substituted cyclopentadienyl ring, and a sybstituted or unsubstituted fluorenyl ring, respectively. R″ is a structural bridge; R1 is a substituent on the cyclopentadienyl ring distal to the bridge. The distal substituent comprises a bulky group of the formula XR*a; X is chosen from Group IVA. M is a Group IVB transition metal or vanadium and each Q is hydrocarbyl having 1 to 20 carbon atoms or is a halogen.Type: GrantFiled: August 24, 2001Date of Patent: April 27, 2004Assignee: Atofina Research S.A.Inventor: Axel Demain
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Patent number: 6723795Abstract: Use of a multimodal polypropylene blend in melt processing wherein for enhancing a compromise between melt strength and drawability the blend has a dispersion index of at least 8 and a ratio Mz/Mn of at least 10.Type: GrantFiled: March 29, 2002Date of Patent: April 20, 2004Assignee: ATOFINA Research S.A.Inventors: Marc Dupire, Jacques Michel