Abstract: The invention relates to blends of sulfo-modified copolyester and polyalkylene furanoate such as polyethylene-, polybutylene-, or polytrimethylene-furanoate, or a mixture thereof. The sulfo-modified copolyester comprises at least about 75 mole % of polyethylene terephthalate or polyethylene naphthalate or a mixture thereof; and at least about 0.1 mole % to about 5 mole % of units of the Formula (I) wherein n is an integer from 3 to 10 and wherein M+ is an alkali metal ion, earth alkali metal ion, phosphonium ion or ammonium ion. Articles requiring high gas barrier are bottles for beer, juices, carbonated soft drinks, and the like.
Abstract: A method of making a non-solid state polyester that includes: a) reacting terephthalic acid and ethylene glycol; b) removing the water continuously; c) polymerizing the monomers and oligomers in vacuum conditions at a temperature to form molten polyester having an IV (intrinsic viscosity) of about 0.7 to 0.
Abstract: The present invention relates to bio-copolyester of polyethylene terephthalate composition prepared from raw materials which are derived from biomass. The bio-composition comprises: 1) about 92 to about 99 mole % of bioPET, prepared from bioMEG and bioPTA, 2) about 1 to about 8 mole % bio-based acids, bio-based diols and/or bio-based branching agents. Bio-based acids include bio-aliphatic diacids or bio-aromatic diacids, or their corresponding bio-esters, or a mixture thereof. Bio-based diols include bio-aliphatic diol comprising 3 to 20 carbon atoms, bio-cycloaliphatic diol of 6 to 20 carbon atoms, or bio-aromatic diol comprising 6 to 14 carbon atoms, or a mixture thereof. Bio-based branching agents include bio-aliphatic compounds having more than two functionalities such as bio-trimellitic anhydride, bio-trimethylol propane, or bio-pentaerythritol, or a blend thereof.
Abstract: The present invention relates to a polyester resin for extrusion blow molded containers comprising a branched copolymer and fumed silica to improve the aged drop performance said branched copolyester is made from the reaction of purified terephthalic acid or its dimethyl ester, ethylene glycol, bifunctional diacid other than terephthalic acid, diol other than ethylene glycol, and multifunctional compound having a least 3 carboxyl groups, hydroxyl groups and/or ester forming groups thereof, said fumed silica has a particle size of 0.1 to 5 microns and is present at about 100 ppm to about 2,500 ppm based on the weight of said copolyester.
Type:
Grant
Filed:
October 28, 2014
Date of Patent:
November 14, 2017
Assignee:
Auriga Polymers, Inc.
Inventors:
K. Prasanna U. Perera, Geoffrey R. Scantlebury