Abstract: Some aspects of the present disclosure relate to systems and processes for the conversion of lithium phosphate into a low-phosphate solution containing lithium which may be suitable as feedstock for the production of saleable lithium products.

Abstract: A modularized system for processing, storing and/or disposing of a hazardous waste material is described. In one exemplary embodiment, the modularized system includes a container configured to sealingly contain hazardous waste material; a first cell, the first cell comprising a first area for manipulating the container; and a second cell, the second cell comprising a second area for manipulating the container. The second cell is isolated from the first cell. The first cell is held at a first pressure and the second cell held at a second pressure, the first pressure being less than the second pressure. An interlock couples the first cell to the second cell. The first cell, second cell and interlock are configured to allow the container to be transferred from the first cell to the second cell while maintaining at least one seal between the first cell and the second cell.

Abstract: A process is provided for releasably encapsulating a biological entity. The process comprises combining a solution of a surfactant in a non-polar solvent with a precursor material and the biological entity to form an emulsion. The emulsion comprises a polar phase dispersed in a non-polar phase, wherein the polar phase comprises the biological entity. The particles comprising the biological entity are then formed from the polar phase.

Abstract: A sorbent for sorbing radioactive ions is described. The sorbent comprises a porous crystalline powder of a metal oxide or mixed metal oxide. A process for making the sorbent comprises the steps of reacting a metal halide or a mixture of metal halides and an alcohol to form a gel; heating the gel to form a particulate material; exposing the particulate material to an oxidant to form a powder; and heating the powder to a temperature sufficient to at least partially melt or sinter particles of the powder so as to form the sorbent.

Abstract: A process for preparing particles having a hydrophobic material therein is disclosed. The process comprises providing a multiple emulsion comprising a first emulsion dispersed in a hydrophobic medium, said first emulsion comprising a hydrophobic phase dispersed in a hydrophilic phase, wherein the hydrophobic phase comprises the hydrophobic material and the hydrophilic phase comprises a precursor which is capable of reacting to form a non-fluid matrix and reacting the precursor in the multiple emulsion to form the matrix in the form of the particles having the hydrophobic material therein wherein the precursor is added prior to formation of the multiple emulsion. Also disclosed are particles having a hydrophobic material therein, which may be releasable, as well as particles having a hydrophobic material therein, which may be releasable, made by the process and methods of using the particles.

Abstract: The invention provides a process for forming a layered nanoparticle, comprising providing a suspension comprising a core particle in a first liquid, adding a second liquid to the suspension, and adding a reagent, or a precursor for the reagent, to the suspension. The second liquid is immiscible with the first liquid. If the reagent is added to the suspension, the reagent reacts to form a layer on the core particle to form the layered nanoparticle. If a precursor for the reagent is added to the suspension, the precursor is converted to the reagent, and the reagent reacts to form a layer on the core particle to form the layered nanoparticle.

Abstract: A method is described for delivering a species to a liquid, whereby porous particles are exposed to a condition such that the species is rapidly released into the liquid. Each of the porous particles comprises an agglomeration of primary particles so that outer surfaces of said primary particles define pores of said porous particles. The primary particles comprise silica and the species is disposed in the pores of the porous particles.

Abstract: A process for making particles comprising a hydrophobic dopant for subsequent release therefrom is disclosed. The process comprises providing an emulsion comprising a hydrophilic phase and a hydrophobic phase dispersed in the hydrophilic phase, and reacting the precursor material to form the particles comprising the dopant therein. The hydrophobic phase comprises a precursor material and the dopant.

Abstract: A method is described for obtaining purified 68Ga. The method comprises eluting 68Ga from a sorbent in and/or on which are sorbed 68Ga and 68Ge, so as to generate a crude 68Ga solution. The sorbent should have a higher affinity for 68Ge than for 68Ga. The crude 68Ga solution is then applied to a medium cation exchange resin, and the resin is eluted with an aqueous alcohol so as to retain the 68Ga on the resin and remove unwanted species from the resin. The resin is then eluted with an eluent, which may be an acidic solution, an alkaline solution or a solution of a species capable of complexing 68Ga ions, so as to obtain an eluate comprising purified 68Ga ions.

Abstract: A process for making particles comprising a hydrophobic dopant for subsequent release therefrom is disclosed. The process comprises providing an emulsion comprising a hydrophilic phase and a hydrophobic phase dispersed in the hydrophilic phase, and reacting the precursor material to form the particles comprising the dopant therein. The hydrophobic phase comprises a precursor material and the dopant.

Abstract: A process is provided for releasably encapsulating a biological entity. The process comprise combining a solution of a surfactant in a non-polar solvent with a precursor material and the biological entity to form an emulsion. The emulsion comprises a polar phase dispersed in a non-polar phase, wherein the polar phase comprises the biological entity. The particles comprising the biological entity are then formed from the polar phase.

Abstract: A process for forming a layered nanoparticle includes providing a suspension including a core particle in a first liquid, adding a second liquid to the suspension, and adding a reagent or a precursor for the reagent, to the suspension. The second liquid is immiscible with the first liquid. If the reagent is added to the suspension, the reagent reacts to form a layer on the core particle to form the layered nanoparticle. If a precursor for the reagent is added to the suspension, the precursor is converted to the reagent, and the reagent reacts to form a layer on the core particle to form the layered nanoparticle.

Abstract: The present invention provides systems, methods and devices for storing and/or disposing of hazardous waste material such as calcined material. In certain embodiments, the system comprises a filling nozzle having a valve body having a distal end and an outer surface, the outer surface proximate the distal end being configured to sealingly and removeably couple to an inner surface of a filling port of the container. In certain embodiments, the method comprises (a) coupling an outer surface of a filling nozzle with an inner surface of a filling port of a container to form a first seal (b) adding hazardous waste material into the container (c) decoupling the filling port from the filling nozzle and (d) inserting a fill plug into the filling port, the fill plug forming a second seal with the inner surface of the filling port, the second seal being distally spaced from at least a portion of the first seal with respect to the container.

Abstract: The present invention provides systems, methods and devices for storing and/or disposing of hazardous waste material. In some embodiments, the waste material includes nuclear waste such as calcined material. In certain embodiments, the device includes a container having a container body, a filling port configured to couple with a filling nozzle and a filling plug, and an evacuation port having a filter. The evacuation port is configured to couple with an evacuation nozzle and an evacuation plug. In certain embodiments, the method includes (a) adding hazardous waste material via a filling nozzle coupled to a filling port of a container, the container including an evacuation port, (b) evacuating the container during adding of the hazardous waste material via an evacuation nozzle coupled to an evacuation port of the container, (c) sealing the filling port, (d) heating the container, and (e) sealing the evacuation port.

Abstract: Disclosed herein is a method for coupling a first compound having the formula (I) with a second compound that contains a carbonyl group. Also disclosed herein are compounds that can be formed by this method, and uses for such compounds.

Abstract: Described herein is a method for determining the presence or absence of anomalous radioactive materials in a target in a detection zone. In the method, a target gamma ray spectrum is obtained from the target and a target data set is prepared from the target gamma ray spectrum. This data set comprise a plurality of intensity values, each intensity value being associated with an energy bin representing a gamma ray energy or range of gamma ray energies in the target gamma ray spectrum. The target data set is then pre-processed and projected into a principal component space which contains a pre-processed data library projected into the principal component space. A distance is then determined between the projected pre-processed target data set and one or more clusters of the projected pre-processed data library in the principal component space and this distance is compared with a predetermined threshold distance so as to determine if an anomalous radioactive material is present in the target.

Abstract: A modularized system for processing, storing and/or disposing of a hazardous waste material is described. In one exemplary embodiment, the modularized system includes a container configured to sealingly contain hazardous waste material; a first cell, the first cell comprising a first area for manipulating the container; and a second cell, the second cell comprising a second area for manipulating the container, the second cell being isolated from the first cell, the first cell held at a first pressure and the second cell held at a second pressure, the first pressure being less than the second pressure. The first cell can include a filling station and the filling station can include (a) a blender configured to mix the hazardous waste material with additives; (b) a hopper coupled to the blender; and (c) a fill nozzle coupled to the hopper and configured to transfer the hazardous waste material and additive mixture into the container.

Abstract: A container to be received in a processing apparatus to subject the container to heat and/or pressure. The container is adapted to receive and contain a substance that includes nuclear material. The container includes a hollow body having an interior within which the substance is to be located. The body includes an opening through which the substance can be moved with respect to the interior. A lid is removably attached to the body to close the opening. At least one filter allows fluid flow into and from the interior. The body and lid hermetically seal the interior except for the at least one filter.

Abstract: A method is described for obtaining purified 68Ga. The method comprises eluting 68Ga from a sorbent in and/or on which are sorbed 68Ga and 68Ge, so as to generate a crude 68Ga solution. The sorbent should have a higher affinity for 68Ge than for 68Ga. The crude 68Ga solution is then applied to a medium cation exchange resin, and the resin is eluted with an aqueous alcohol so as to retain the 68Ga on the resin and remove unwanted species from the resin. The resin is then eluted with an eluent, which may be an acidic solution, an alkaline solution or a solution of a species capable of complexing 68Ga ions, so as to obtain an eluate comprising purified 68Ga ions.

Abstract: A sorbent for sorbing radioactive ions is described. The sorbent comprises a porous crystalline powder of a metal oxide or mixed metal oxide. A process for making the sorbent comprises the steps of reacting a metal halide or a mixture of metal halides and an alcohol to form a gel; heating the gel to form a particulate material; exposing the particulate material to an oxidant to form a powder; and heating the powder to a temperature sufficient to at least partially melt or sinter particles of the powder so as to form the sorbent.