Abstract: The preparation of chlorinated hydrocarbons, such as pentachloropropanes, such as 1,1,1,2,3-pentachloropropane, from tetrachloropropanes, such as 1,1,1,3-tetrachloropropane, in the presence of a polyvalent antimony compound that includes a pentavalent antimony compound, such as antimony pentachloride, is described. Also described are methods for preparing optionally chlorinated alkenes, such as, tetrachloropropenes, from chlorinated alkanes, such as pentachloropropanes, in the presence of polyvalent antimony compound that includes a pentavalent antimony compound, as well as methods for recovering polyvalent antimony compounds from such processes.

Abstract: The present invention relates to a chemical feeder that includes a housing having a housing chamber, a sieve plate residing within the housing chamber, and a funnel residing on an upper surface of the sieve plate. The funnel includes upper and lower openings, an interior funnel space, and at least one funnel sidewall aperture. The sieve plate includes a plurality of sieve plate apertures at least a portion of which are in fluid communication with the interior funnel space via the lower funnel opening. During operation, a feed liquid passes up through at least a portion of the sieve plate apertures and into the interior funnel space where it contacts a solid chemical material, so as to form a treated liquid that includes dissolved chemical material, at least a portion of which passes out through the funnel sidewall aperture(s) and exits the chemical feed through an outlet.

Abstract: The preparation of chlorinated hydrocarbons, such as pentachloropropanes, such as 1,1,1,2,3-pentachloropropane, from tetrachloropropanes, such as 1,1,1,3-tetrachloropropane, in the presence of a polyvalent antimony compound that includes a pentavalent antimony compound, such as antimony pentachloride, is described. Also described are methods for preparing optionally chlorinated alkenes, such as, tetrachloropropenes, from chlorinated alkanes, such as pentachloropropanes, in the presence of polyvalent antimony compound that includes a pentavalent antimony compound, as well as methods for recovering polyvalent antimony compounds from such processes.

Abstract: The present invention relates to a chemical feeder that includes a housing (11) having a housing chamber (20) therein, a support plate (35) within the housing chamber that includes a plurality of support plate apertures (44), and a plurality of nozzles (69, 72) that each have a distributor head (78) that extends up through the support plate. Each distributor head distributes a feed liquid horizontally above the upper surface (38) of the support plate. The chemical feeder, with some embodiments, further includes a diverter plate (122) that extends upward from the support plate at an angle (125) of less than 90°. The diverter plate divides an upper housing chamber (146) into a first upper housing chamber (152) that includes solid chemical material, and a second upper housing chamber (155) that is free of solid chemical material.

Abstract: A chemical feeder includes a support plate that is positioned within the housing chamber of the chemical feeder is described. The support plate includes a base plate having an upper surface that has one or more extensions that extend upward from the upper surface. The extensions can, with some embodiments, be in the form of arcuate extensions that can together define an impeller pattern or a spiral extension that defines a spiral channel. The upper surface of the base plate and/or the one or more extensions are adapted to support a solid chemical material thereon. The support plate further includes a plurality of arcuate channel apertures or spiral channel apertures that extend through the base plate. A feed liquid introduced into the housing chamber flows through at least one of the plurality of arcuate/spiral channel apertures and contacts the solid chemical material to form a treated liquid.

Abstract: The present invention relates to a chemical feeder that includes a support plate that is positioned within the housing chamber of the chemical feeder, in which one or more extensions extend upward from an upper surface of the base plate of the support plate. The extensions can, with some embodiments, be in the form of peg extensions, arcuate extensions that can together define an impeller pattern, or a spiral extension. A distributor head having a plurality of distributor head apertures and at least one dome hole extends up through a support plate aperture in the base plate of the support plate, and distributes liquid horizontally and vertically relative to the base plate. The horizontally and vertically distributed liquid contacts a solid chemical material that is supported above the support plate, so as to form a treated liquid that includes dissolved chemical material.

Abstract: The present invention relates to a chemical feeder that includes a support plate that is positioned within the housing chamber of the chemical feeder. The support plate includes a base plate that has one or more extensions that extend upward from an upper surface of the base plate. The extensions can, with some embodiments, be in the form of peg extensions, arcuate extensions that can together define an impeller pattern, or a spiral extension. The support plate also includes a deflection plate that is positioned vertically above at least one support plate aperture that extends through the base plate. The deflection plate also includes at least one deflection plate hole therethrough. A first portion of liquid passing up through the support plate aperture is horizontally deflected by the deflection plate and interacts with the extensions. A second portion of liquid passing up through the support plate aperture passes vertically up through the deflection plate hole(s).

Abstract: The preparation of chlorinated hydrocarbons, such as pentachloropropanes, such as 1,1,1,2,3-pentachloropropane, from tetrachloropropanes, such as 1,1,1,3-tetrachloropropane, in the presence of a polyvalent antimony compound that includes a pentavalent antimony compound, such as antimony pentachloride, is described. Also described are methods for preparing optionally chlorinated alkenes, such as, tetrachloropropenes, from chlorinated alkanes, such as pentachloropropanes, in the presence of ferric chloride and a polyvalent antimony compound that includes a pentavalent antimony compound.

Abstract: The preparation of chlorinated hydrocarbons by reacting a chlorinated alkane substrate, such as 1,1,1,3-tetrachloropropane, with a source of chlorine, such as chlorine (Cl2), in the presence of a polyvalent bismuth compound, such as triphenyl bismuth and/or triphenyl bismuth dichloride, is described. With the method of the present invention, the chlorinated alkane product has covalently bonded thereto at least one more chlorine group than the chlorinated alkane substrate, and the chlorinated alkane substrate and the chlorinated alkane product each have a carbon backbone structure that is in each case the same.

Abstract: The preparation of chlorinated hydrocarbons, such as pentachloropropanes, such as 1,1,1,2,3-pentachloropropane, from tetrachloropropanes, such as 1,1,1,3-tetrachloropropane, in the presence of a polyvalent antimony compound that includes a pentavalent antimony compound, such as antimony pentachloride, is described. Also described are methods for preparing optionally chlorinated alkenes, such as, tetrachloropropenes, from chlorinated alkanes, such as pentachloropropanes, in the presence of ferric chloride and a polyvalent antimony compound that includes a pentavalent antimony compound.

Abstract: A composition is described that includes: (a) at least one alkali metal hydrogen sulfate anhydrous, such as sodium hydrogen sulfate anhydrous; (b) at least one salt, that is different than the alkali metal hydrogen sulfate anhydrous, which is selected from alkali metal salt and/or alkaline earth metal salt, such as sodium chloride and/or magnesium sulfate; and (c) optionally a colorant, in which the composition is in the form of a tablet. There is also described a method of forming a treated aqueous stream using the tablet composition. There is further described a method of forming a treated sanitizing aqueous stream that involves combining the treated aqueous stream with a feed sanitizing aqueous stream. In addition, there is described a method of sanitizing a surface that involves applying the treated sanitizing aqueous stream to a surface to be treated, such as animal carcass surfaces.

Abstract: The preparation of chlorinated hydrocarbons, such as pentachloropropanes, such as 1,1,1,2,3-pentachloropropane, from tetrachloropropanes, such as 1,1,1,3-tetrachloropropane, in the presence of a polyvalent antimony compound that includes a pentavalent antimony compound, such as antimony pentachloride, is described. Also described are methods for preparing optionally chlorinated alkenes, such as, tetrachloropropenes, from chlorinated alkanes, such as pentachloropropanes, in the presence of ferric chloride and a polyvalent antimony compound that includes a pentavalent antimony compound.

Abstract: Described is a method for improving the operation of an electrolytic cell having an anolyte compartment, a catholyte compartment and a synthetic diaphragm separating the compartments, wherein liquid anolyte is introduced into the anolyte compartment and flows through the diaphragm into the catholyte compartment, which method involves introducing particulate material comprising halocarbon polymer short fiber, e.g., fluorocarbon polymer short fiber, into the anolyte compartment in amounts sufficient to lower the flow of liquid anolyte through the diaphragm into the catholyte compartment. In the case of an electrolytic cell wherein aqueous alkali metal chloride, e.g.