Abstract: A radiation polymerizable composition comprising: (A) a donor/acceptor component for forming a charge transfer complex said component being selected from the group consisting of: (iii) a bifunctional compound having an electron donor group and an electron withdrawing group and a polymerizable unsaturated group; (iv) a mixture of (a) at least one unsaturated compound having an electron donor group and a polymerizable unsaturated moiety; and (b) at least one unsaturated compound having an electron acceptor group and a polymerizable unsaturated group; and (B) a binder polymer composition.

Abstract: A method of preparing a coated substrate comprising: providing a radiation curable composition comprising a resin component including an unsaturated monomer and an unsaturated oligomer, binder or mixture of oligomer and binder; applying the radiation curable composition at a temperature in the range of from 35 to 150.degree. C. to the substrate; and subjecting the applied coating to radiation to thereby cure the coating. The invention also provides a composition for application of pigmented finishes and a method of coating in which a radiation curable composition is applied to a wet substrate.