Patents Assigned to Basell Poliolefine Italia s.r.I.
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Patent number: 10174137Abstract: Butene-1 terpolymers having a content of propylene derived units of 0.5-13% mol, and a content of ethylene derived units of 1-3% mol, a ratio C3/C2 of the content of propylene and ethylene derived units is of from 1 to 10, said butene-1 terpolymers having a melt flow rate MIE, measured at 190° C./2.16 Kg of from 0.3 to 3 g/10 min, and a molecular weight distribution curve determined by GPC with a ratio Mw/Mn of from 4 to 10, and the portion of molecular weights of 1×105 or lower, accounting for 22% or larger of the total area.Type: GrantFiled: April 11, 2008Date of Patent: January 8, 2019Assignee: Basell Poliolefine Italia S.r.I.Inventors: Giampaolo Pellegatti, Stefano Spataro
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Publication number: 20150141594Abstract: A catalyst component for the polymerization of olefins comprising Mg, Ti and an electron donor compound of the following formula (I) in which the R groups equal to or different from each other, are C1-C15 hydrocarbon groups, the R1-R2 groups, equal to or different from each other, are hydrogen, halogen or C1-C15 hydrocarbon groups, optionally containing an heteroatom selected from halogen, P, S, N and Si, which can be fused together to form one or more cycles; n and m are integer from 0 to 3 with the proviso that at least one of them is different from 0 and that diisobutyl o-phenylenediacetate is excluded.Type: ApplicationFiled: June 5, 2013Publication date: May 21, 2015Applicant: Basell Poliolefine Italia S.r.I.Inventors: Alessandro Mignogna, Simona Guidotti, Igor Kashulin, Giampiero Morini, Ilya Nifant'ev, Joachim T.M. Pater
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Publication number: 20150051350Abstract: Extruded or molded profiles comprising a polyolefin composition consisting of 85% by weight or more of a copolymer of 1-butene with ethylene (A) having an ethylene copolymerized content up to 18% by mol, and having Mw/Mn lower than 3, hardness shore A (measured according to ISO 868) lower than 90, no melting point (TmII) detectable at the DSC after cancelling the thermal history, melting enthalpy (?Hf), measured by DSC after 10 days of aging at room temperature, comprised between 4 and 15 J/g; and up to 15% by weight of a propylene copolymer or a composition of copolymers of propylene (B) having a melting point from about 126° C. to 200° C., isotactic index greater than 90%.Type: ApplicationFiled: February 12, 2013Publication date: February 19, 2015Applicant: Basell Poliolefine Italia S.r.I.Inventors: Paolo Ferrari, Luca Lunghi, Roberta Marchini, Stefano Spataro, Giampaolo Pellegatti, Caroline Cathelin, Stefano Pasquali
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Publication number: 20150005438Abstract: Propylene polymer compositions comprising: A) from 70 wt % to 95 wt %, of a random copolymer of propylene with ethylene, containing from 1.5 wt % to 4.5 wt %, of ethylene derived units, having a content of fraction insoluble in xylene at 25° C. of not less than 93%; B) from 5 wt % to 35 wt %, of a copolymer of propylene with ethylene, containing from 7.0 wt % to 17.0 wt % of ethylene derived units; the sum A+B being 100; wherein the melt flow rate ,MFR. (Melt Flow Rate according to ASTM 1238, condition L, i.e. 230° C. and 2.16 kg load) ranges from 40 g/10 min and 130 g /10 min; and wherein the relation (I) is fulfilled: 10<XS*C2A-MFR/C2B<30 ??(I) wherein XS is the wt % of xylene soluble content at 25° C.Type: ApplicationFiled: October 5, 2012Publication date: January 1, 2015Applicant: Basell Poliolefine Italia S.r.I.Inventors: Gisella Biondini, Marco Ciarafoni, Paola Massari, Roberto Pantaleoni
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Publication number: 20140171592Abstract: A case for valve-regulated lead-acid battery comprising an olefin polymer composition comprising: A) From 60 wt % to 95 wt %, of a propylene homopolymer, or a copolymer of propylene containing 3% or less of ethylene, said homopolymer or copolymer having a Polydispersity Index (P.I.) value of from 4.6 to 10 and a fraction insoluble in xylene at 25° C., higher than 98 molar %; and B) from 5 wt % to 40 wt %, of a copolymer of propylene and ethylene containing from 30 wt % to 65 wt % of ethylene derived units; the sum A)+B) being 100.Type: ApplicationFiled: July 13, 2012Publication date: June 19, 2014Applicant: Basell Poliolefine Italia S.r.I.Inventors: Gisella Biondini, Marco Ciarafoni, Mara Destro, Paola Massari, Piorella Pradella
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Publication number: 20140142262Abstract: Catalyst component for the polymerization of olefins comprising Mg, Ti and an electron donor compound of the following formula (I) In which R1 to R4 groups, equal to or different from each other, are hydrogen, C1-C15 hydrocarbon groups, optionally containing an heteroatom selected from halogen, P, S, N and Si, R6 group is selected from C1-C15 hydrocarbon groups optionally containing an heteroatom selected from halogen, P, S, N and Si, and R5 is selected from phenyl groups mono or poly substituted with halogens, said groups R1-R4 being also optionally linked to form a saturated or unsaturated mono or poly cycle.Type: ApplicationFiled: June 15, 2012Publication date: May 22, 2014Applicant: Basell Poliolefine Italia S.r.I.Inventors: Alessandro Mignogna, Davide Balboni, Antonio Cristofori, Simona Guidotti, Giampiero Morini, Joachim T.M Peter
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Publication number: 20140121340Abstract: Films or sheets of polypropylene, particularly biaxially oriented polypropylene (BOPP) films, exhibiting excellent physical and mechanical properties combined with good processing characteristics can be prepared from propylene polymers prepared in the presence of Ziegler-Natta catalysts comprising a succinate and a diether compound.Type: ApplicationFiled: June 21, 2012Publication date: May 1, 2014Applicant: Basell Poliolefine Italia S.r.IInventors: Monica Galvan, Roberto Pantaleoni, Ofelia Fusco, Benedetta Gaddi, Andreas Neumann, Antonio Mazzucco, Gianni Collina
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Publication number: 20140046010Abstract: A porous solid catalyst component comprising a magnesium halide, a titanium compound having at least a Ti-halogen bond and at least two electron donor compounds one of which being selected from 1,3-diethers and the other being selected from succinates, characterized by the fact that the molar ratio ID/Ti is from 0.30 to 0.90, where ID is the total molar amount of succinate and 1,3-diether, the molar ratio of the 1,3-diether donor to the succinate donor is higher than, or equal to, 0.60.Type: ApplicationFiled: March 29, 2012Publication date: February 13, 2014Applicant: Basell Poliolefine Italia S.r.I.Inventors: Simona Guidotti, Giampiero Morini, Simona Esposito, Alessandro Mignogna, Joachim T.M. Pater, Fabrizio Piemontesi, Diego Brita
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Publication number: 20140046011Abstract: Process for the preparation of solid particles of a magnesium-chloride alcohol adduct comprising (a) forming an emulsion between a MgCl2 alcohol adduct in molten form and a liquid phase which is immiscible with the said adduct in the presence of a polyalkyl-methacrylate used as a solution having viscosity ranging from 100 to 5000 mm2/s and (b) rapidly cooling the emulsion to solidify the disperse phase and collecting the solid adduct particles.Type: ApplicationFiled: April 13, 2012Publication date: February 13, 2014Applicant: Basell Poliolefine Italia S. r. I.Inventors: Benedetta Gaddi, Daniele Evangelisti, Gianni Collina
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Publication number: 20130344267Abstract: A container comprising a polyolefin composition comprising: A) from 59 wt % to 84 wt %, of a propylene homopolymer having isotactic pentads (mmmm) measured with by 13C-NMR higher than 96%, B) from 16 wt % to 41 wt %, of a copolymer of propylene and ethylene with from 30 wt % to 44 wt %, of ethylene derived units; the sum A) +B) being 100; the composition having an MFR L (Melt Flow Rate according to ISO 1133, condition L, i.e. 230° C. and 2.16 kg load) comprised from 72 to 100 g/10 min.Type: ApplicationFiled: March 8, 2012Publication date: December 26, 2013Applicant: Basell Poliolefine Italia S.r.I.Inventors: Thomas A. Frederick, Claudio Cavalieri, Jeanine A. Smith, Gilles Jobin, Timothy C. Brasel, Roberto Pantaleoni, Marco Ciarafoni, Paola Massari
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Publication number: 20130202836Abstract: Pressure sensitive adhesive composition and multilayer easy peel re-closable structures thereof, comprising a butene-1 (co)polymer (A) having a content of butene-1 derived units of 80 wt % or more; a flexural modulus (MEF) of 80 MPa or less; a melting temperature DSC (TmI) lower than 110° C., and optionally a tackifier (B).Type: ApplicationFiled: October 18, 2011Publication date: August 8, 2013Applicant: Basell Poliolefine Italia S.r.I.Inventors: Gianluca Musacchi, Inge Elisabeth Roucourt, Giampaolo Pellegatti, Johan De Clippeleir, Stefano Spataro
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Publication number: 20130165605Abstract: A gas-phase polymerization reactor having interconnected polymerization zones comprising:—a riser through which the polymer particles flow upwards under fast fluidization conditions or transport conditions—a dowcomer through which the polymer particles flow downward in a densified form under the action of gravity, the bottom of said downcomer being connected to the lower region of said riser by means of a transport section, said transport section being designed as a bend descending from the downcomer to the riser.Type: ApplicationFiled: September 2, 2011Publication date: June 27, 2013Applicant: Basell Poliolefine Italia S.r.I.Inventors: Silvia Soffritti, Riccardo Rinaldi, Maurizio Dorini, Giuseppe Penzo
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Publication number: 20120172533Abstract: A polymer composition comprising (per cent by weight): a) 57%-74%, of a crystalline propylene polymer having an amount of isotactic pentads (mmmm), measured by 13C-MNR on the fraction insoluble in xylene at 25° C., higher than 97.5 molar % and a polydispersity index ranging from 5 to 10; b) 8 to 15%, of an elastomeric copolymer of ethylene and propylene, the copolymer having an amount of recurring units deriving from ethylene ranging from 30 to 50%, and being partially soluble in xylene at ambient temperature; the polymer fraction soluble in xylene at ambient temperature having an intrinsic viscosity value ranging from 2.5 to 3.5 dl/g; and c) 18-28%, of ethylene homopolymer having an intrinsic viscosity value ranging from 1.5 to 4 dl/g; said composition having a value of melt flow rate ranging from 35 to 60 g/10 min, and the amount of hexane extractables lower than 4.0 wt %.Type: ApplicationFiled: July 20, 2010Publication date: July 5, 2012Applicant: BASELL POLIOLEFINE ITALIA S.R.I.Inventors: Marco Ciarafoni, Paola Massari, Gisella Biondini, Roberto Pantaleoni
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Publication number: 20120130031Abstract: Process for the preparation of ethylene polymers having narrow MWD characterized by a F/E ratio lower than 35 carried out in the presence of a catalyst system comprising (a) a solid catalyst component comprising Ti atoms that are substantially in the +4 oxidation state, Mg, Cl, and optionally OR groups and internal donors in which R is a C1-C20 hydrocarbon group, in which the OR/Ti molar ratio is equal to or lower than 0.35 and the internal donor/Ti ratio is lower than 1, (b) an aluminum alkyl compound and (c) a compound selected from alkoxybenzenes of specified formula.Type: ApplicationFiled: August 2, 2010Publication date: May 24, 2012Applicant: BASELL POLIOLEFINE ITALIA S.R.IInventors: Masaki Fushimi, Dario Liguori, Tiziano Dall'Occo, Giampiero Morini, Joachim T.M. Pater, Gianni Vitale
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Publication number: 20090306316Abstract: A catalyst component comprising Ti, Mg, Al, Cl, and optionally OR1 groups in which R1 is a C1-C20 hydrocarbon group, optionally containing heteroatoms, up to an amount such as to give a molar OR1/Ti ratio lower than 0.5, characterized by the fact that substantially all the titanium atoms are in valence state of 4, that the porosity (PF), measured by the mercury method and due to pores with radius equal to or lower than 1 ?m, is at least 0.3 cm3/g, and by the fact that the Cl/Ti molar ratio is lower than 29. The said catalysts are characterized by high morphological stability under the low molecular weight ethylene polymerization conditions while at the same time maintaining characteristics of high activity.Type: ApplicationFiled: December 11, 2007Publication date: December 10, 2009Applicant: Basell Poliolefine Italia s.r.IInventors: Giampiero Morini, Tiziano Dall'Occo, Dario Liguori, Joachim T.M. Pater, Gianni Vitale
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Publication number: 20090203816Abstract: A polypropylene resin composition comprising (A) 99.8 to 80 weight parts of a polypropylene resin having a melt flow rate of 0.1 to 50 g/10 min and (B) 0.2 to 20 weight parts of an olefin copolymer rubber having an intrinsic viscosity [?] of 0.5 to 4.0 dl/g and/or a polyethylene resin having a density of 0.895 to 0.945 g/cc and a melt flow rate of 0.05 to 15 g/10 min, which have undergone an ionization ray-irradiation treatment and/or a treatment of adding 0.05 to 5 weight parts of an organic peroxide to 100 weight parts of the aforesaid polypropylene resin composition comprising (A) and (B) and then melting.Type: ApplicationFiled: November 12, 2008Publication date: August 13, 2009Applicant: Basell Poliolefine Italia s.r.I.Inventor: Toshiyuki Iwashita
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Publication number: 20080064836Abstract: Process for the preparation of ethylene copolymers comprising the copolymerization of ethylene with olefins CH2?CHR, in which R is a hydrocarbyl radical with 1-12 carbon atoms carried out in the presence of a catalyst comprising (i) a solid catalyst component comprising Mg, Ti, halogen and specific 1,3-diethers of formula (I) in which R is a C1-C10 hydrocarbon group, R1 is methyl or ethyl, optionally containing a heteroatom, and R2 is a C4-C12 linear alkyl optionally containing a heteroatom, and (ii) an organo-Al compound. The obtained copolymers are endowed with good comonomer distribution.Type: ApplicationFiled: November 1, 2007Publication date: March 13, 2008Applicant: Basell Poliolefine Italia s.r.I.Inventors: Angelo Ferraro, Tiziano Dall'Occo, Giuliano Cecchin