Abstract: Disclosed are coating compositions including (A) at least one member selected from hydroxyl-containing polyacrylate, polymethacrylate, polyurethane, polyester, polysiloxane, and combinations of two or more of the foregoing, (B) at least one compound having blocked isocyanate groups and having alkoxysilane groups, wherein (i) the hydroxyl groups of component (A) are blocked with at least one acyclic orthoester, (ii) the compound (B) has at least one structural unit (II) —N(X—SiR?x(OR)3-x)n(X?—SiR?y(OR)3-y)m??(II), where R=hydrogen, cycloalkyl radical or alkyl radical, X,X?=linear and/or branched alkylene or cycloalkylene radical having 1 to 20 carbon atoms, R?=alkyl, cycloalkyl, aryl or aralkyl, n, m, x, y=0 to 2, and also m+n=2, and (i) at least 90 mol % of the alkoxysilane groups are ethoxysilane groups. Also disclosed are multistage coating processes, use of the compositions as clearcoat materials and application of the processes for automotive OEM finishing.

Abstract: A carbamate-functional material is prepared by reacting a carbamate compound with a hydroxy-functional material using zirconium acetylacetonate as catalyst.

Abstract: Compositions comprising (B1) at least one polyisocyanate-group-containing compound (B1) having free or blocked isocyanate groups and a cycloaliphatic polyisocyanate parent structure, and/or a polyisocyanate derived therefrom, and (B2) at least one polyisocyanate-group-containing compound (B2) having free or blocked isocyanate groups and an acyclic, aliphatic polyisocyanate parent structure, and/or a polyisocyanate derived therefrom, where at least one of component (B1) and component (B2) comprise at least one structural unit selected from the group of structural unit (I) —NR—(X—SiR?x(OR?)3-x)??(I), structural unit (II) —N(X—SiR?x(OR?)3-x)n(X?—SiR?y(OR?)3-y)m??(II), and mixtures of two or more of the foregoing, wherein the compound (B1) is in an amount such that the binder fraction of the compound (B1) is between 5% and 45% by weight, based on the sum of the binder fraction of the compound (B1) and of the compound (B2), and the mixture of components (B1) and (B2) includes structural units (I) and structura

Abstract: Described is a high solids coating composition having exceptional rheological properties and appearances comprising (a) a thermosetting binder, (b) from about 0.1 to about 10 wt. % based on binder solids of solid polyurea particles prepared by the reaction of a mixture of a polyisocyanate and an amino reactant comprising a primary or secondary monoamine that optionally has a hydroxyl or ether group or both, and (c) from about 2 to about 25 wt. % on resin solids of an acrylic polymer having a number average molecular weight of from about 2000 to about 8000 and a glass transition temperature of from about 50 to about 120° C.

Abstract: Disclosed is a method for producing a multicoat color and/or effect paint system, comprising (1) applying a pigmented aqueous basecoat to a substrate, (2) forming a polymer film from the basecoat applied in stage (1), (3) applying a clearcoat to the polymer film, and then (4) curing the polymer film together with the applied clearcoat to form a clearcoat film. The pigmented aqueous basecoat comprises at least one ester characterized by the following structure: where R1 is selected from the group of ethyl and isopropyl and R2 is a C2 to C8 radical. The at least one ester is used here in an amount of 0.1% to 5% by weight, based on the total weight of the aqueous basecoat applied in stage (1). The invention further provides the corresponding coating materials and the use of the esters in pigmented aqueous coating materials.

Abstract: Water-free composition comprising at least one saturated or unsaturated, epoxy-modified polyester as binder, at least one acrylate polymer or polyurethane polymer as further binder, polymer microparticles, at least one polymer which comprises functional groups consisting of blocked isocyanates and amino resins, as crosslinking agent, at least one pigment, at least one organic solvent, and at least one auxiliary or additive, the solids of the composition being at least 50% by weight.

Abstract: An aqueous dispersion comprising at least one copolymer, the copolymer being preparable by initially charging an aqueous dispersion of at least one polyurethane, and then polymerizing a mixture of olefinically unsaturated monomers in the presence of the polyurethane, where a water-soluble initiator is used, the metered addition of the olefinically unsaturated monomers is effected in such a way that a concentration of 6.0% by weight, based on the total amount of olefinically unsaturated monomers, in the reaction solution is not exceeded over the entire duration of the reaction, and the mixture of the olefinically unsaturated monomers comprises at least one polyolefinically unsaturated monomer. The invention further relates to the use of the aqueous dispersion for production of coating materials, to a process for producing the aqueous dispersion, to a basecoat comprising the aqueous dispersion, and to the use of the basecoat for coating of automobile bodies and/or parts for installation on automobile bodies.

Abstract: Disclosed are coating compositions comprising at least one hydroxyl-containing compound (A) and at least one isocyanato-containing compound (B), wherein one or more of the constituents of the coating composition comprise between 2.5 and 97.5 mol %, based on the entirety of structural units (I) and (II), of at least one structural unit of the formula (I) —N(X—SiR?x(OR?)3-x)n(X?—SiR?y(OR?)3-y)m??(I) and between 2.5 and 97.5 mol %, based on the entirety of structural units (I) and (II), of at least one structural unit of the formula (II) —Z—(X—SiR?x(OR?)3-x)??(II).

Abstract: The present invention relates to coating material compositions comprising at least one polyhydroxyl group-containing compound (A), at least one polyisocyanate group-containing compound (B) having free and/or blocked isocyanate groups, and at least one catalyst (D) based on a zinc-amidine complex which is preparable by reaction of 1.0 moles of at least one zinc(II) biscarboxylate with 2.0 moles of at least one amidine where R5=hydrogen and R1, R2, R3, and R4 are each identical or different radicals, R1 and R3 being hydrogen or an alkyl radical or an aryl radical, and R2 and R4 being an alkyl radical or an aryl radical, characterized in that the coating material composition further comprises at least one monomeric aromatic, optionally substituted carboxylic acid (S) whose carboxyl group is in conjugation with a ?-electron system.

Abstract: The present invention relates to coating material compositions comprising at least one polyhydroxyl group-containing compound (A), at least one polyisocyanate group-containing compound (B) having free and/or blocked isocyanate groups, and at least one catalyst (D) based on a zinc-amidine complex which is prepared by reaction of 1.0 moles of at least one zinc(II) biscarboxylate with less than 2.0 moles of at least one amidine where R5=hydrogen and R1, R2, R3, and R4 are each identical or different radicals, R1 and R3 being hydrogen or an alkyl radical or an aryl radical, and R2 and R4 being an alkyl radical or an aryl radical.

Abstract: Disclosed is a hyperbranched, dendritic, hydroxyl-functional polyester comprising an OH number greater than or equal to 180 mg KOH/g as measured via DIN 53240 and to clearcoat compositions comprising said polyesters. Also disclosed are processes for preparing the disclosed polyester, methods of making coated automotive substrates by applying the disclosed clearcoat compositions to automotive substrates, and to coated substrates made therefrom.

Abstract: A carbamate-functional material is prepared by reacting a carbamate compound with a hydroxy-functional material using titanium (IV) alkoxide as catalyst.

Abstract: The present invention provides nonaqueous coating material compositions, multistage coating processes and also the use of the coating material compositions, comprising (A) at least one polyhydroxyl-group-containing compound, (B1) at least one polyisocyanate-group-containing compound (B1) having free or blocked isocyanate groups and having a cycloaliphatic polyisocyanate parent structure, and/or a polyisocyanate derived therefrom, (B2) at least one polyisocyanate-group-containing compound (B2) having free or blocked isocyanate groups and having an acyclic, aliphatic polyisocyanate parent structure, and/or a polyisocyanate derived therefrom, (D) at least one catalyst for the crosslinking of silane groups, and (R) at least one rheological assistant (R) based on fumed silica, where component (B1) and/or component (B2) comprise at least one structural unit —NR—(X—SiR?x(OR?)3-x)??(I), and/or at least one structural unit —N(X—SiR?x(OR?)3-x)n(X?—SiR?y(OR?)3-y)m??(II).

Abstract: Provided is a coating composition comprising at least one hydroxyl-containing compound (A), at least one compound (B1) having at least one silane group of the formula (I) —X—Si—R?xG3-x??(I) with G=identical or different hydrolyzable groups, X=organic radical, more particularly linear and/or branched alkylene or cycloalkylene radical having 1 to 20 carbon atoms, R?=alkyl, cycloalkyl, aryl or aralkyl, it being possible for the carbon chain to be interrupted by nonadjacent oxygen, sulfur or NRa groups, with Ra=alkyl, cycloalkyl, aryl or aralkyl, x=0 to 2, and at least one compound (B2) different from the component (B1) and which is prepared from a linear aliphatic diisocyanate (DI), (B2) comprising uretidone groups and at least 2 isocyanate groups per molecule.

Abstract: A coating system comprises a substrate and a cured film disposed on the substrate and formed from a coating composition. The coating composition comprises a solvent component and a resin. The resin comprises a reaction product of a polyolefin and an oligomer or polymer. The polyolefin, different from the oligomer or polymer, has a functional group that is reactive with the oligomer or polymer and the functional group is selected from acrylate, methacrylate, carboxyl, hydroxyl, epoxide, anhydride and isocyanate functional groups. The oligomer or polymer and the polyolefin are at least partially immiscible in solution at ambient temperature. The oligomer or polymer is grafted with the polyolefin to form the resin.

Abstract: Scratch resistance and/or reflow of a refinish topcoat is improved by preparing the topcoat from a refinish topcoat coating composition comprising an unsaturated fatty acid ester polyol that does not undergo oxidative cure when the applied refinish topcoat coating composition is cured.

Abstract: The present invention relates to electrodeposition primer compositions comprising catalytically active core/shell particles CS. The electrodeposition primer compositions can be used more particularly for cathodic dip coating for the coating of automobile bodies or parts thereof.

Abstract: The present invention relates to a process for the coating of polycarbonate substrates, in particular of transparent polycarbonate substrates, by applying a transparent coating composition encompassing at least one radiation-curing binder resin (A) and/or reactive diluent (C), nanoparticles (B), optionally solvent and at least one light stabilizer (L), to a polycarbonate substrate, wherein the coating composition comprises at least one light stabilizer (L) which comprises, per molecule, an average of at least one ethylenically unsaturated group bonded by way of a urethane group. The present invention also relates to the coating compositions used in said process, and to the coated polycarbonate substrates obtainable via the process, and to their use.

Abstract: Described is a solvent-containing clearcoat coating composition comprising (A) an OH-functional (meth)acrylate (co)polymer component composed of (A1) at least one OH-functional (meth)acrylate (co)polymer having an OH number of 60-200 mg KOH/g and a glass transition temperature Tg of 15° C. to 100° C., and (A2) at least one OH-functional (meth)acrylate (co)polymer having an OH number of 60-200 mg KOH/g and a glass transition temperature Tg of ?100° C. to ?20° C.; (B) a crosslinker component comprising at least one crosslinking agent having functional groups that are reactive toward OH groups; and also (C) at least one polyamide; and (D) at least one urea compound, which is an adduct of a polyisocyanate and methoxypropylamine. Also described is a process for preparing the solvent-containing clearcoat coating composition, to the use of the solvent-containing clearcoat coating composition and a clearcoat which has been produced using the clearcoat coating composition.

Abstract: Binder mixture comprising a hydroxyl-containing compound (A), and at least 1.0% by weight, based on the nonvolatile constituents of the binder mixture, of a phosphorus- and nitrogen-containing catalyst (D) for the crosslinking of silane groups, wherein the hydroxyl-containing compound (A) comprises a hydroxyl-functional polyester having on average at least one hydroxyl function of the polyester esterified with a C8 to C9 monocarboxylic acid, and the catalyst (D) is blocked with at least one tertiary amine of the formula (I) where R1 is an acyclic aliphatic or araliphatic hydrocarbon radical having at least 3 C atoms, R2 is an acyclic aliphatic or araliphatic hydrocarbon radical which is the same or different from R1 and/or R3, and R3 is hydrogen or an acyclic aliphatic or araliphatic hydrocarbon radical which is the same or different from R1 and/or R2.