Abstract: A gas stream containing nitrous oxide and ammonia is contacted with a catalyst composition containing a zeolite. N2O is reduced to N2 and H2O at low temperatures in a highly efficient manner. Ammonia-mediated reduction of nitrous oxide can be effectuated from gas streams having N2O concentrations as low as 1%. The gas stream may also contact a catalytic composition selective for the reduction of NOx. In this way, N2O and NOx treatment may be effectuated in a single process stream.
Type:
Grant
Filed:
September 11, 2008
Date of Patent:
May 31, 2011
Assignee:
BASF Corporation
Inventors:
James Chen, Pascaline Tran, Michael Durilla, Stanley Mack
Abstract: Polymer emulsion compositions for use in printing inks and printing inks made from the compositions are provided. The emulsion compositions include an aqueous continuous phase containing water and a dissolved carboxylic acid-functional support polymer. The dispersed phase of the emulsion composition contains crosslinked, dispersed polymer particles. The emulsion compositions also include at least one multivalent metal crosslinker and at least one stabilizing agent. The polymer emulsion compositions display superior printability properties in inks and other coatings formulated with them, yet are stable at elevated temperatures for long periods of time.
Type:
Grant
Filed:
September 19, 2005
Date of Patent:
May 24, 2011
Assignee:
BASF Corporation
Inventors:
Rein J. Janmaat, James W. Taylor, Mark van den Brink, Andre van Meer
Abstract: An oxidation catalyst for the treatment of exhaust gas emissions, such as the oxidation of unburned hydrocarbons (HC), and carbon monoxide (CO) and the reduction of nitrogen oxides (NOx) from a diesel engine and methods of exhaust gas treatment are disclosed. More particularly, a washcoat composition is disclosed comprising at least two washcoat layers, a first washcoat comprising palladium supported on ceria-zirconia and ceria-zirconia-alumina and a second washcoat containing one or more of platinum and palladium and one or more hydrocarbon storage components. An undercoat may also be included in the catalyst. Also disclosed are method of exhaust gas treatment and diesel exhaust gas treatment systems that include the oxidation catalyst and a downstream soot filter.
Abstract: Provided are selective catalytic reduction catalytic articles, emission treatment systems and methods for simultaneously remediating the nitrogen oxides (NOx), particulate matter, and gaseous hydrocarbons present in diesel engine exhaust streams. The catalytic articles have a Selective Catalytic Reduction (SCR) catalyst uniformly coated over the outlet portion of wall flow filter walls resulting in reduction of NO2 and combustion of the soot without substantially increasing the system backpressure.
Abstract: Catalysts, systems and methods are described to reduce NOx emissions of an internal combustion engine. In one embodiment, an emissions treatment system for an exhaust stream is provided having a catalyst comprising silver and a platinum group metal on a particulate alumina support, the atomic fraction of the platinum group metal being less than or equal to about 0.25. Methods of manufacturing catalysts are described in which silver is impregnated on alumina particles.
Type:
Grant
Filed:
September 20, 2006
Date of Patent:
May 17, 2011
Assignee:
BASF Corporation
Inventors:
Christopher R. Castellano, Ahmad Moini, Gerald S. Koermer, Howard Furbeck, Steven J. Schmieg, Richard J. Blint
Abstract: Catalyst articles comprising substantially only a palladium precious metal component in a first catalytic layer and a rhodium component in a second catalytic layer and related methods of preparation and use are disclosed. Also disclosed is a catalyst article comprising a first layer formed on a carrier substrate, wherein the first layer comprises a refractory metal oxide and has a surface that is substantially uniform; a second layer formed on the first layer, wherein the second layer comprises i) an oxygen storage component that is about 50-90% by weight of the second layer and ii) a palladium component in an amount of about 2-5% by weight of the second layer, wherein the palladium component is substantially the only platinum group metal component, and a palladium-free third layer comprising a rhodium component supported on a thermostable oxygen storage component which is about 80-99% by weight of the second layer. One or more improved properties are exhibited by the catalyst article.
Type:
Application
Filed:
November 1, 2010
Publication date:
May 12, 2011
Applicant:
BASF Corporation
Inventors:
Michael P. Galligan, Pascaline H. Tran, Keshavaraja Alive, Ye Liu
Abstract: A plastic container used to hold a dispersion-based paint colorant and capable of dispensing the colorant into paint dispensing machines, comprising an open top capable of holding and securing a cap, and having a wide mouth with a diameter of at least 50 mm. The plastic container has a cylindrical body extending below the open top, and a plurality of vertical ribs spaced around the body to strengthen the container.
Type:
Application
Filed:
January 10, 2011
Publication date:
May 5, 2011
Applicant:
BASF Corporation
Inventors:
Joseph M. Galownia, Dennis Futo, Dale Panascewicz
Abstract: The shelf life of fresh harvest produce is extended by coating the exterior surface of freshly harvested produce with a coating composition comprising an aqueous emulsion of polyvinylidene chloride copolymers containing from about 0.25 to 25% by weight of copolymer solids to water and between 0.001 and 20% plasticizer preferably a polyethylene oxide based additive such as Triton-X to weight of copolymer solids in the emulsion. The coating may also contain biocides as well to control bacteria and fungal growth on the post harvest produce during storage, shipping, distribution, and sale of the product. The coating composition is effective in extending the shelf life of produce.
Abstract: Provided is an emissions treatment system for an exhaust stream, having a NOx storage reduction (NSR) catalyst with a NOx sorbent at a concentration of at least 0.1 g/in3 and a platinum group metal component dispersed on a refractory metal oxide support; and, an SCR catalyst disposed downstream of the NSR catalyst. The emissions treatment system is advantageously used for the treatment of exhaust streams from diesel engines and lean burn gasoline engines.
Type:
Grant
Filed:
May 15, 2007
Date of Patent:
April 5, 2011
Assignee:
BASF Corporation
Inventors:
Yuejin Li, Michel Deeba, Joseph C. Dettling, Joseph A. Patchett, Stanley A. Roth
Abstract: Stable water-borne polymer compositions are disclosed. The compositions comprise a water-borne polymer, a metal cross-linking agent and a stabilizing agent comprising from 2 to 10 carbon atoms and at least two functional groups independently selected from hydroxy and carboxy. The stabilizing agent is present a 1.4 mole percent or more of the amount of metal cross-linking agent. Inventive compositions are particularly suitable for use in water-based inks and coatings. Methods of making and using the coating compositions are also described.
Type:
Grant
Filed:
November 20, 2008
Date of Patent:
March 22, 2011
Assignee:
BASF Corporation
Inventors:
James W. Taylor, Mark Van den Brink, Andre Van Meer
Abstract: Provided is an emission treatment system and method for simultaneously remediating the nitrogen oxides (NOx), particulate matter, and gaseous hydrocarbons present in diesel engine exhaust streams. The emission treatment system has an oxidation catalyst upstream of a soot filter coated with a material effective in the Selective Catalytic Reduction (SCR) of NOx by a reductant, e.g., ammonia. Also provided is a method for disposing an SCR catalyst composition on a wall flow monolith that provides adequate catalyst loading, but does not result in unsuitable back pressures in the exhaust.
Type:
Grant
Filed:
February 8, 2008
Date of Patent:
March 8, 2011
Assignee:
BASF Corporation
Inventors:
Joseph A. Patchett, Joseph C. Dettling, Elizabeth A. Przybylski
Abstract: A method of reforming a sulfur containing hydrocarbon involves contacting the sulfur containing hydrocarbon with a sulfur tolerant catalyst containing a sulfur tolerant precious metal and a non-sulfating carrier so that the sulfur tolerant catalyst adsorbs at least a portion of sulfur in the sulfur containing hydrocarbon and a low sulfur reformate is collected, and contacting the sulfur tolerant catalyst with an oxygen containing gas to convert at least a portion of adsorbed sulfur to a sulfur oxide that is desorbed from the sulfur tolerant catalyst.
Type:
Grant
Filed:
July 11, 2006
Date of Patent:
March 8, 2011
Assignee:
BASF Corporation
Inventors:
Thomas Giroux, Earl Waterman, Robert Joseph Farrauto
Abstract: A method is provided for measuring the concentration of a catalytic clement in a fuel cell powder. The method includes depositing on a porous substrate at least one layer of a powder mixture comprising the fuel cell powder and an internal standard material, ablating a sample of the powder mixture using a laser, and vaporizing the sample using an inductively coupled plasma. A normalized concentration of catalytic element in the sample is determined by quantifying the intensity of a first signal correlated to the amount of catalytic element in the sample, quantifying the intensity of a second signal correlated to the amount of internal standard material in the sample, and using a ratio of the first signal intensity to the second signal intensity to cancel out the effects of sample size.
Abstract: A method of reforming a sulfur containing hydrocarbon involves contacting the sulfur containing hydrocarbon with a sulfur tolerant catalyst containing a non-sulfating carrier and one or more of a sulfur tolerant precious metal and a non-precious metal compound so that the sulfur tolerant catalyst adsorbs at least a portion of sulfur in the sulfur containing hydrocarbon and a low sulfur reformate is collected, and contacting the sulfur tolerant catalyst with an oxygen containing gas to convert at least a portion of adsorbed sulfur to a sulfur oxide that is desorbed from the sulfur tolerant catalyst.
Type:
Grant
Filed:
July 11, 2007
Date of Patent:
March 8, 2011
Assignee:
BASF Corporation
Inventors:
Thomas Giroux, Earl Waterman, Robert Joseph Farrauto
Abstract: A rodent management station includes a housing having a base and a lid that together at least in part define an interior space of the housing. The lid is positionable relative to the base between a closed configuration of the station in which the interior space is substantially enclosed, and an opened configuration of the station in which the interior space is accessible for servicing. The housing has an entry opening through which rodents enter the interior space of the housing. The rodent management station also includes at least one of a trap and a bait positionable within the interior space of the housing. The base includes a floor panel and an inner surface on which rodents move within the interior space. An upstanding rear wall extends upward relative to the floor panel about substantially less than the circumference of the floor panel.
Type:
Application
Filed:
September 21, 2009
Publication date:
February 24, 2011
Applicant:
BASF CORPORATION
Inventors:
James H. Cink, Jonathan D. Berger, Brian James Mann, Edward Francis Marshall, Henry Wayne Moran, James David Poling
Abstract: This invention is directed to novel pigments, pigment systems (including components not classified as pigments) and formulations for use in an aqueous coating system applied onto cellulosic (paper and/or paperboard) and non-cellulosic substrates (polyethylene (PE), polylactic acid (PLA), polyvinyl acetate (PVAc), etc.) to impart barrier properties.
Type:
Application
Filed:
August 23, 2010
Publication date:
February 24, 2011
Applicant:
BASF Corporation
Inventors:
Richard Berube, Kenneth W. Folmar, Sharad Mathur, John D. Serafano, Ashok Khokhani, Jennifer Rigney, James Royce Godfrey
Abstract: Methods and apparatus for destroying ozone in an air stream are provided. Specific embodiments comprise passing air through a particulate filter comprising a filter media folded into a plurality pleats and a plurality of separators, where the separators and/or the filter media is coated with an ozone destruction catalyst.
Abstract: The present invention provides aqueous dispersions of highly-branched polymers for coating applications and methods for making the polymers. The polymers may have high molecular weights and desirably take the form of microgels. The polymers and dispersions may be formulated with functionalities, viscosities, and solids contents that make them well-suited for use in a variety of coatings including, but not limited to, 2-pack coatings, ultraviolet (UV) curable coatings, inks, and air-dry coatings.
Abstract: The present invention relates to a process for preparing a catalyst, at least comprising the steps of adding a protecting agent to an aqueous solution of a metal precursor to give a mixture (M1), adding a reducing agent to mixture (M1) to give a mixture (M2), adding a support material to mixture (M2) to give a mixture (M3), adjusting the pH of mixture (M3), and separating the solid and liquid phase of mixture (M3). Furthermore, the present invention relates to the catalyst as such and its use as diesel oxidation catalyst.
Abstract: The present invention relates to a catalyst comprising particles of a cobalt and zinc co-precipitate, having a volume average particle size of less than 150 ?m. Another aspect of the invention is the use of such a catalyst in a Fischer-Tropsch process. The present invention further relates to a method for preparing a catalyst comprising cobalt and zinc oxide, wherein an acidic solution comprising zinc ions and cobalt ions and a alkaline solution are contacted and the precipitate is isolated.